Organic electroluminescent materials and devices

ABSTRACT

A compound having the formula:Formula I is disclosed. The compound is useful as emitters in OLEDs.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application claims priority under 35 U.S.C. § 119(e) to U.S.Provisional Application No. 62/479,730, filed Mar. 31, 2017 and U.S.Provisional Application No. 62/478,072, filed Mar. 29, 2017, the entirecontents of which are incorporated herein by reference.

FIELD

The present invention relates to compounds for use as emitters, anddevices, such as organic light emitting diodes, including the same.

BACKGROUND

Opto-electronic devices that make use of organic materials are becomingincreasingly desirable for a number of reasons. Many of the materialsused to make such devices are relatively inexpensive, so organicopto-electronic devices have the potential for cost advantages overinorganic devices. In addition, the inherent properties of organicmaterials, such as their flexibility, may make them well suited forparticular applications such as fabrication on a flexible substrate.Examples of organic opto-electronic devices include organic lightemitting diodes/devices (OLEDs), organic phototransistors, organicphotovoltaic cells, and organic photodetectors. For OLEDs, the organicmaterials may have performance advantages over conventional materials.For example, the wavelength at which an organic emissive layer emitslight may generally be readily tuned with appropriate dopants.

OLEDs make use of thin organic films that emit light when voltage isapplied across the device. OLEDs are becoming an increasinglyinteresting technology for use in applications such as flat paneldisplays, illumination, and backlighting. Several OLED materials andconfigurations are described in U.S. Pat. Nos. 5,844,363, 6,303,238, and5,707,745, which are incorporated herein by reference in their entirety.

One application for phosphorescent emissive molecules is a full colordisplay. Industry standards for such a display call for pixels adaptedto emit particular colors, referred to as “saturated” colors. Inparticular, these standards call for saturated red, green, and bluepixels. Alternatively the OLED can be designed to emit white light. Inconventional liquid crystal displays emission from a white backlight isfiltered using absorption filters to produce red, green and blueemission. The same technique can also be used with OLEDs. The white OLEDcan be either a single EML device or a stack structure. Color may bemeasured using CIE coordinates, which are well known to the art.

One example of a green emissive molecule is tris(2-phenylpyridine)iridium, denoted Ir(ppy)₃, which has the following structure:

In this, and later figures herein, we depict the dative bond fromnitrogen to metal (here, Ir) as a straight line.

As used herein, the term “organic” includes polymeric materials as wellas small molecule organic materials that may be used to fabricateorganic opto-electronic devices. “Small molecule” refers to any organicmaterial that is not a polymer, and “small molecules” may actually bequite large Small molecules may include repeat units in somecircumstances. For example, using a long chain alkyl group as asubstituent does not remove a molecule from the “small molecule” class.Small molecules may also be incorporated into polymers, for example as apendent group on a polymer backbone or as a part of the backbone Smallmolecules may also serve as the core moiety of a dendrimer, whichconsists of a series of chemical shells built on the core moiety. Thecore moiety of a dendrimer may be a fluorescent or phosphorescent smallmolecule emitter. A dendrimer may be a “small molecule,” and it isbelieved that all dendrimers currently used in the field of OLEDs aresmall molecules.

As used herein, “top” means furthest away from the substrate, while“bottom” means closest to the substrate. Where a first layer isdescribed as “disposed over” a second layer, the first layer is disposedfurther away from substrate. There may be other layers between the firstand second layer, unless it is specified that the first layer is “incontact with” the second layer. For example, a cathode may be describedas “disposed over” an anode, even though there are various organiclayers in between.

As used herein, “solution processible” means capable of being dissolved,dispersed, or transported in and/or deposited from a liquid medium,either in solution or suspension form.

A ligand may be referred to as “photoactive” when it is believed thatthe ligand directly contributes to the photoactive properties of anemissive material. A ligand may be referred to as “ancillary” when it isbelieved that the ligand does not contribute to the photoactiveproperties of an emissive material, although an ancillary ligand mayalter the properties of a photoactive ligand.

As used herein, and as would be generally understood by one skilled inthe art, a first “Highest Occupied Molecular Orbital” (HOMO) or “LowestUnoccupied Molecular Orbital” (LUMO) energy level is “greater than” or“higher than” a second HOMO or LUMO energy level if the first energylevel is closer to the vacuum energy level. Since ionization potentials(IP) are measured as a negative energy relative to a vacuum level, ahigher HOMO energy level corresponds to an IP having a smaller absolutevalue (an IP that is less negative) Similarly, a higher LUMO energylevel corresponds to an electron affinity (EA) having a smaller absolutevalue (an EA that is less negative). On a conventional energy leveldiagram, with the vacuum level at the top, the LUMO energy level of amaterial is higher than the HOMO energy level of the same material. A“higher” HOMO or LUMO energy level appears closer to the top of such adiagram than a “lower” HOMO or LUMO energy level.

As used herein, and as would be generally understood by one skilled inthe art, a first work function is “greater than” or “higher than” asecond work function if the first work function has a higher absolutevalue. Because work functions are generally measured as negative numbersrelative to vacuum level, this means that a “higher” work function ismore negative. On a conventional energy level diagram, with the vacuumlevel at the top, a “higher” work function is illustrated as furtheraway from the vacuum level in the downward direction. Thus, thedefinitions of HOMO and LUMO energy levels follow a different conventionthan work functions.

More details on OLEDs, and the definitions described above, can be foundin U.S. Pat. No. 7,279,704, which is incorporated herein by reference inits entirety.

SUMMARY

A compound having the formula:

Formula I is disclosed. In Formula I, R¹, R², R³, R⁴, and R⁵ eachindependently represents mono, to a maximum possible number ofsubstitutions, or no substitution. X is selected from the groupconsisting of BR′, NR′, PR′, O, S, Se, C═O, S═O, SO₂, CR′R″, SiR′R″, andGeR′R″. R′, R″, R¹, R², R³, R⁴, and R⁵ are independently selected fromthe group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl,heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl,cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl,carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl,sulfonyl, phosphino, and combinations thereof. Any substitutions areoptionally joined or fused into a ring. n is 1 or 2. R is selected fromthe group consisting of alkyl, cycloalkyl, heteroalkyl,heterocycloalkyl, partially or fully fluorinated variants thereof,partially or fully deuterated variants thereof, and combination thereof.R has at least five carbon atoms.

An OLED is also disclosed, where the OLED comprises: an anode; acathode; and an organic layer, disposed between the anode and thecathode, comprising a compound having the formula:

In Formula I, R¹, R², R³, R⁴, and R⁵ each independently represents mono,to a maximum possible number of substitutions, or no substitution. X isselected from the group consisting of BR′, NR′, PR′, O, S, Se, C═O, S═O,SO₂, CR′R″, SiR′R″, and GeR′R″. R′, R″, R¹, R², R³, R⁴, and R⁵ areindependently selected from the group consisting of hydrogen, deuterium,halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy,amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl,heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile,isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinationsthereof. Any substitutions are optionally joined or fused into a ring. nis 1 or 2. R is selected from the group consisting of alkyl, cycloalkyl,heteroalkyl, heterocycloalkyl, partially or fully fluorinated variantsthereof, partially or fully deuterated variants thereof, and combinationthereof. R has at least five carbon atoms.

A consumer product comprising the OLED is also disclosed.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 shows an organic light emitting device.

FIG. 2 shows an inverted organic light emitting device that does nothave a separate electron transport layer.

FIG. 3 is a diagram showing how the substituent R group in the inventivecompound aligns with the transition dipolar moment of the metallatedcomplex.

DETAILED DESCRIPTION

Generally, an OLED comprises at least one organic layer disposed betweenand electrically connected to an anode and a cathode. When a current isapplied, the anode injects holes and the cathode injects electrons intothe organic layer(s). The injected holes and electrons each migratetoward the oppositely charged electrode. When an electron and holelocalize on the same molecule, an “exciton,” which is a localizedelectron-hole pair having an excited energy state, is formed. Light isemitted when the exciton relaxes via a photoemissive mechanism. In somecases, the exciton may be localized on an excimer or an exciplex.Non-radiative mechanisms, such as thermal relaxation, may also occur,but are generally considered undesirable.

The initial OLEDs used emissive molecules that emitted light from theirsinglet states (“fluorescence”) as disclosed, for example, in U.S. Pat.No. 4,769,292, which is incorporated by reference in its entirety.Fluorescent emission generally occurs in a time frame of less than 10nanoseconds.

More recently, OLEDs having emissive materials that emit light fromtriplet states (“phosphorescence”) have been demonstrated. Baldo et al.,“Highly Efficient Phosphorescent Emission from OrganicElectroluminescent Devices,” Nature, vol. 395, 151-154, 1998;(“Baldo-I”) and Baldo et al., “Very high-efficiency green organiclight-emitting devices based on electrophosphorescence,” Appl. Phys.Lett., vol. 75, No. 3, 4-6 (1999) (“Baldo-II”), are incorporated byreference in their entireties. Phosphorescence is described in moredetail in U.S. Pat. No. 7,279,704 at cols. 5-6, which are incorporatedby reference.

FIG. 1 shows an organic light emitting device 100. The figures are notnecessarily drawn to scale. Device 100 may include a substrate 110, ananode 115, a hole injection layer 120, a hole transport layer 125, anelectron blocking layer 130, an emissive layer 135, a hole blockinglayer 140, an electron transport layer 145, an electron injection layer150, a protective layer 155, a cathode 160, and a barrier layer 170.Cathode 160 is a compound cathode having a first conductive layer 162and a second conductive layer 164. Device 100 may be fabricated bydepositing the layers described, in order. The properties and functionsof these various layers, as well as example materials, are described inmore detail in U.S. Pat. No. 7,279,704 at cols. 6-10, which areincorporated by reference.

More examples for each of these layers are available. For example, aflexible and transparent substrate-anode combination is disclosed inU.S. Pat. No. 5,844,363, which is incorporated by reference in itsentirety. An example of a p-doped hole transport layer is m-MTDATA dopedwith F₄-TCNQ at a molar ratio of 50:1, as disclosed in U.S. PatentApplication Publication No. 2003/0230980, which is incorporated byreference in its entirety. Examples of emissive and host materials aredisclosed in U.S. Pat. No. 6,303,238 to Thompson et al., which isincorporated by reference in its entirety. An example of an n-dopedelectron transport layer is BPhen doped with Li at a molar ratio of 1:1,as disclosed in U.S. Patent Application Publication No. 2003/0230980,which is incorporated by reference in its entirety. U.S. Pat. Nos.5,703,436 and 5,707,745, which are incorporated by reference in theirentireties, disclose examples of cathodes including compound cathodeshaving a thin layer of metal such as Mg:Ag with an overlyingtransparent, electrically-conductive, sputter-deposited ITO layer. Thetheory and use of blocking layers is described in more detail in U.S.Pat. No. 6,097,147 and U.S. Patent Application Publication No.2003/0230980, which are incorporated by reference in their entireties.Examples of injection layers are provided in U.S. Patent ApplicationPublication No. 2004/0174116, which is incorporated by reference in itsentirety. A description of protective layers may be found in U.S. PatentApplication Publication No. 2004/0174116, which is incorporated byreference in its entirety.

FIG. 2 shows an inverted OLED 200. The device includes a substrate 210,a cathode 215, an emissive layer 220, a hole transport layer 225, and ananode 230. Device 200 may be fabricated by depositing the layersdescribed, in order. Because the most common OLED configuration has acathode disposed over the anode, and device 200 has cathode 215 disposedunder anode 230, device 200 may be referred to as an “inverted” OLED.Materials similar to those described with respect to device 100 may beused in the corresponding layers of device 200. FIG. 2 provides oneexample of how some layers may be omitted from the structure of device100.

The simple layered structure illustrated in FIGS. 1 and 2 is provided byway of non-limiting example, and it is understood that embodiments ofthe invention may be used in connection with a wide variety of otherstructures. The specific materials and structures described areexemplary in nature, and other materials and structures may be used.Functional OLEDs may be achieved by combining the various layersdescribed in different ways, or layers may be omitted entirely, based ondesign, performance, and cost factors. Other layers not specificallydescribed may also be included. Materials other than those specificallydescribed may be used. Although many of the examples provided hereindescribe various layers as comprising a single material, it isunderstood that combinations of materials, such as a mixture of host anddopant, or more generally a mixture, may be used. Also, the layers mayhave various sublayers. The names given to the various layers herein arenot intended to be strictly limiting. For example, in device 200, holetransport layer 225 transports holes and injects holes into emissivelayer 220, and may be described as a hole transport layer or a holeinjection layer. In one embodiment, an OLED may be described as havingan “organic layer” disposed between a cathode and an anode. This organiclayer may comprise a single layer, or may further comprise multiplelayers of different organic materials as described, for example, withrespect to FIGS. 1 and 2.

Structures and materials not specifically described may also be used,such as OLEDs comprised of polymeric materials (PLEDs) such as disclosedin U.S. Pat. No. 5,247,190 to Friend et al., which is incorporated byreference in its entirety. By way of further example, OLEDs having asingle organic layer may be used. OLEDs may be stacked, for example asdescribed in U.S. Pat. No. 5,707,745 to Forrest et al, which isincorporated by reference in its entirety. The OLED structure maydeviate from the simple layered structure illustrated in FIGS. 1 and 2.For example, the substrate may include an angled reflective surface toimprove out-coupling, such as a mesa structure as described in U.S. Pat.No. 6,091,195 to Forrest et al., and/or a pit structure as described inU.S. Pat. No. 5,834,893 to Bulovic et al., which are incorporated byreference in their entireties.

Unless otherwise specified, any of the layers of the various embodimentsmay be deposited by any suitable method. For the organic layers,preferred methods include thermal evaporation, ink-jet, such asdescribed in U.S. Pat. Nos. 6,013,982 and 6,087,196, which areincorporated by reference in their entireties, organic vapor phasedeposition (OVPD), such as described in U.S. Pat. No. 6,337,102 toForrest et al., which is incorporated by reference in its entirety, anddeposition by organic vapor jet printing (OVJP), such as described inU.S. Pat. No. 7,431,968, which is incorporated by reference in itsentirety. Other suitable deposition methods include spin coating andother solution based processes. Solution based processes are preferablycarried out in nitrogen or an inert atmosphere. For the other layers,preferred methods include thermal evaporation. Preferred patterningmethods include deposition through a mask, cold welding such asdescribed in U.S. Pat. Nos. 6,294,398 and 6,468,819, which areincorporated by reference in their entireties, and patterning associatedwith some of the deposition methods such as ink jet and OVJD. Othermethods may also be used. The materials to be deposited may be modifiedto make them compatible with a particular deposition method. Forexample, substituents such as alkyl and aryl groups, branched orunbranched, and preferably containing at least 3 carbons, may be used insmall molecules to enhance their ability to undergo solution processing.Substituents having 20 carbons or more may be used, and 3-20 carbons isa preferred range. Materials with asymmetric structures may have bettersolution processibility than those having symmetric structures, becauseasymmetric materials may have a lower tendency to recrystallize.Dendrimer substituents may be used to enhance the ability of smallmolecules to undergo solution processing.

Devices fabricated in accordance with embodiments of the presentinvention may further optionally comprise a barrier layer. One purposeof the barrier layer is to protect the electrodes and organic layersfrom damaging exposure to harmful species in the environment includingmoisture, vapor and/or gases, etc. The barrier layer may be depositedover, under or next to a substrate, an electrode, or over any otherparts of a device including an edge. The barrier layer may comprise asingle layer, or multiple layers. The barrier layer may be formed byvarious known chemical vapor deposition techniques and may includecompositions having a single phase as well as compositions havingmultiple phases. Any suitable material or combination of materials maybe used for the barrier layer. The barrier layer may incorporate aninorganic or an organic compound or both. The preferred barrier layercomprises a mixture of a polymeric material and a non-polymeric materialas described in U.S. Pat. No. 7,968,146, PCT Pat. Application Nos.PCT/US2007/023098 and PCT/US2009/042829, which are herein incorporatedby reference in their entireties. To be considered a “mixture”, theaforesaid polymeric and non-polymeric materials comprising the barrierlayer should be deposited under the same reaction conditions and/or atthe same time. The weight ratio of polymeric to non-polymeric materialmay be in the range of 95:5 to 5:95. The polymeric material and thenon-polymeric material may be created from the same precursor material.In one example, the mixture of a polymeric material and a non-polymericmaterial consists essentially of polymeric silicon and inorganicsilicon.

Devices fabricated in accordance with embodiments of the invention canbe incorporated into a wide variety of electronic component modules (orunits) that can be incorporated into a variety of electronic products orintermediate components. Examples of such electronic products orintermediate components include display screens, lighting devices suchas discrete light source devices or lighting panels, etc. that can beutilized by the end-user product manufacturers. Such electroniccomponent modules can optionally include the driving electronics and/orpower source(s). Devices fabricated in accordance with embodiments ofthe invention can be incorporated into a wide variety of consumerproducts that have one or more of the electronic component modules (orunits) incorporated therein. A consumer product comprising an OLED thatincludes the compound of the present disclosure in the organic layer inthe OLED is disclosed. Such consumer products would include any kind ofproducts that include one or more light source(s) and/or one or more ofsome type of visual displays. Some examples of such consumer productsinclude flat panel displays, computer monitors, medical monitors,televisions, billboards, lights for interior or exterior illuminationand/or signaling, heads-up displays, fully or partially transparentdisplays, flexible displays, laser printers, telephones, mobile phones,tablets, phablets, personal digital assistants (PDAs), wearable devices,laptop computers, digital cameras, camcorders, viewfinders,micro-displays (displays that are less than 2 inches diagonal), 3-Ddisplays, virtual reality or augmented reality displays, vehicles, videowalls comprising multiple displays tiled together, theater or stadiumscreen, and a sign. Various control mechanisms may be used to controldevices fabricated in accordance with the present invention, includingpassive matrix and active matrix. Many of the devices are intended foruse in a temperature range comfortable to humans, such as 18 degrees C.to 30 degrees C., and more preferably at room temperature (20-25 degreesC.), but could be used outside this temperature range, for example, from−40 degree C. to +80 degree C.

The materials and structures described herein may have applications indevices other than OLEDs. For example, other optoelectronic devices suchas organic solar cells and organic photodetectors may employ thematerials and structures. More generally, organic devices, such asorganic transistors, may employ the materials and structures.

The term “halo,” “halogen,” or “halide” as used herein includesfluorine, chlorine, bromine, and iodine.

The term “alkyl” as used herein contemplates both straight and branchedchain alkyl radicals. Preferred alkyl groups are those containing fromone to fifteen carbon atoms and includes methyl, ethyl, propyl,1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl, pentyl,1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl,1,2-dimethylpropyl, 2,2-dimethylpropyl, and the like. Additionally, thealkyl group may be optionally substituted.

The term “cycloalkyl” as used herein contemplates cyclic alkyl radicals.Preferred cycloalkyl groups are those containing 3 to 10 ring carbonatoms and includes cyclopropyl, cyclopentyl, cyclohexyl, adamantyl, andthe like. Additionally, the cycloalkyl group may be optionallysubstituted.

The term “alkenyl” as used herein contemplates both straight andbranched chain alkene radicals. Preferred alkenyl groups are thosecontaining two to fifteen carbon atoms. Additionally, the alkenyl groupmay be optionally substituted.

The term “alkynyl” as used herein contemplates both straight andbranched chain alkyne radicals. Preferred alkynyl groups are thosecontaining two to fifteen carbon atoms. Additionally, the alkynyl groupmay be optionally substituted.

The terms “aralkyl” or “arylalkyl” as used herein are usedinterchangeably and contemplate an alkyl group that has as a substituentan aromatic group. Additionally, the aralkyl group may be optionallysubstituted.

The term “heterocyclic group” as used herein contemplates aromatic andnon-aromatic cyclic radicals. Hetero-aromatic cyclic radicals also meansheteroaryl. Preferred hetero-non-aromatic cyclic groups are thosecontaining 3 to 7 ring atoms which includes at least one hetero atom,and includes cyclic amines such as morpholino, piperidino, pyrrolidino,and the like, and cyclic ethers, such as tetrahydrofuran,tetrahydropyran, and the like. Additionally, the heterocyclic group maybe optionally substituted.

The term “aryl” or “aromatic group” as used herein contemplatessingle-ring groups and polycyclic ring systems. The polycyclic rings mayhave two or more rings in which two carbons are common to two adjoiningrings (the rings are “fused”) wherein at least one of the rings isaromatic, e.g., the other rings can be cycloalkyls, cycloalkenyls, aryl,heterocycles, and/or heteroaryls. Preferred aryl groups are thosecontaining six to thirty carbon atoms, preferably six to twenty carbonatoms, more preferably six to twelve carbon atoms. Especially preferredis an aryl group having six carbons, ten carbons or twelve carbons.Suitable aryl groups include phenyl, biphenyl, triphenyl, triphenylene,tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene,fluorene, pyrene, chrysene, perylene, and azulene, preferably phenyl,biphenyl, triphenyl, triphenylene, fluorene, and naphthalene.Additionally, the aryl group may be optionally substituted.

The term “heteroaryl” as used herein contemplates single-ringhetero-aromatic groups that may include from one to five heteroatoms.The term heteroaryl also includes polycyclic hetero-aromatic systemshaving two or more rings in which two atoms are common to two adjoiningrings (the rings are “fused”) wherein at least one of the rings is aheteroaryl, e.g., the other rings can be cycloalkyls, cycloalkenyls,aryl, heterocycles, and/or heteroaryls. Preferred heteroaryl groups arethose containing three to thirty carbon atoms, preferably three totwenty carbon atoms, more preferably three to twelve carbon atoms.Suitable heteroaryl groups include dibenzothiophene, dibenzofuran,dibenzoselenophene, furan, thiophene, benzofuran, benzothiophene,benzoselenophene, carbazole, indolocarbazole, pyridylindole,pyrrolodipyridine, pyrazole, imidazole, triazole, oxazole, thiazole,oxadiazole, oxatriazole, dioxazole, thiadiazole, pyridine, pyridazine,pyrimidine, pyrazine, triazine, oxazine, oxathiazine, oxadiazine,indole, benzimidazole, indazole, indoxazine, benzoxazole, benzisoxazole,benzothiazole, quinoline, isoquinoline, cinnoline, quinazoline,quinoxaline, naphthyridine, phthalazine, pteridine, xanthene, acridine,phenazine, phenothiazine, phenoxazine, benzofuropyridine,furodipyridine, benzothienopyridine, thienodipyridine,benzoselenophenopyridine, and selenophenodipyridine, preferablydibenzothiophene, dibenzofuran, dibenzoselenophene, carbazole,indolocarbazole, imidazole, pyridine, triazine, benzimidazole,1,2-azaborine, 1,3-azaborine, 1,4-azaborine, borazine, and aza-analogsthereof. Additionally, the heteroaryl group may be optionallysubstituted.

The alkyl, cycloalkyl, alkenyl, alkynyl, aralkyl, heterocyclic group,aryl, and heteroaryl may be unsubstituted or may be substituted with oneor more substituents selected from the group consisting of deuterium,halogen, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy,amino, cyclic amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl,alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acid, ether,ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, andcombinations thereof.

As used herein, “substituted” indicates that a substituent other than His bonded to the relevant position, such as carbon. Thus, for example,where R¹ is mono-substituted, then one R¹ must be other than H.Similarly, where R¹ is di-substituted, then two of R¹ must be other thanH. Similarly, where R¹ is unsubstituted, R¹ is hydrogen for allavailable positions. The maximum number of substitutions possible in astructure will depend on the number of atoms with available valencies.

The “aza” designation in the fragments described herein, i.e.aza-dibenzofuran, aza-dibenzothiophene, etc. means that one or more ofthe C—H groups in the respective fragment can be replaced by a nitrogenatom, for example, and without any limitation, azatriphenyleneencompasses both dibenzo[f,h]quinoxaline and dibenzo[f,h]quinoline. Oneof ordinary skill in the art can readily envision other nitrogen analogsof the aza-derivatives described above, and all such analogs areintended to be encompassed by the terms as set forth herein.

It is to be understood that when a molecular fragment is described asbeing a substituent or otherwise attached to another moiety, its namemay be written as if it were a fragment (e.g. phenyl, phenylene,naphthyl, dibenzofuryl) or as if it were the whole molecule (e.g.benzene, naphthalene, dibenzofuran). As used herein, these differentways of designating a substituent or attached fragment are considered tobe equivalent.

Disclosed herein are novel polycyclic substituents. Phosphorescentemitters with these substituents show higher external quantum efficiency(EQE) in devices. In the field of organic chemistry, a polycycliccompound is an organic chemical featuring several closed rings of atoms,primarily carbon. These ring substructures comprise cycloalkanes,aromatics, and other ring types. They come in sizes of three atoms andupward, and in combinations of linkages that include tethering (such asin biaryls), fusing (edge-to-edge, such as in anthracene and steroids),links via a single atom (such as in spiro compounds), and bridgedcyclics such as adamantane. The term “polycyclic” is used in thisdisclosure to include rings including many rings as well as structuressuch as bicyclic, tricyclic, and tetracyclic.

According to an aspect of the present disclosure, heteroleptictris-cyclometalated Iridium (III) complexes that has a high efficiencyin OLED device are disclosed.

A compound is disclosed having the formula [L_(A)]_(3-n)Ir[L_(B)]_(n),having the structure:

In Formula I, R¹, R², R³, R⁴, and R⁵ each independently represents mono,to a maximum possible number of substitutions, or no substitution. X isselected from the group consisting of BR′, NR′, PR′, O, S, Se, C═O, S═O,SO₂, CR′R″, SiR′R″, and GeR′R″. Each of R′, R″, R¹, R², R³, R⁴, and R⁵is independently selected from the group consisting of hydrogen,deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy,aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl,aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile,isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinationsthereof. Any substitutions are optionally joined or fused into a ring. nis 1 or 2. R is selected from the group consisting of alkyl, cycloalkyl,heteroalkyl, heterocycloalkyl, partially or fully fluorinated variantsthereof, partially or fully deuterated variants thereof, and combinationthereof. R has at least five carbon atoms.

In some embodiments, each of R′, R″, R¹, R², R³, R⁴, and R⁵ isindependently selected from the group consisting of hydrogen, deuterium,fluorine, alkyl, cycloalkyl, heteroalkyl, alkoxy, aryloxy, amino, silyl,alkenyl, cycloalkenyl, heteroalkenyl, aryl, heteroaryl, nitrile,isonitrile, and combinations thereof.

In some embodiments, R has at least six carbon atoms. In someembodiments, R has at least seven carbon atoms.

In some embodiments, n is 2. In some embodiments, X is O.

In some embodiments, R comprises a cycloalkyl or heterocycloalkyl. Insome embodiments, R¹, R², R³, R⁴, and R⁵ are each independently selectedfrom the group consisting of hydrogen, deuterium, alkyl, cycloalkyl,aryl, and combinations thereof.

In some embodiments, R is selected from the group consisting of:

In some embodiments of the compound, the compound is selected from thegroup consisting of:

wherein R⁶ is selected from the group consisting of hydrogen, deuterium,halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy,amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl,heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile,isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinationsthereof.In some embodiments of the compound, L_(A) is selected from the groupconsisting of L_(A1) to L_(A371)

having a structure according to in which R, R¹, R^(A), R^(B), R^(c),R^(D), and R^(E) are defined as provided below:

L_(Ai), where i is R¹ R R^(A) R^(B) R^(C) R^(D) R^(E) 1. H R^(A1 ) H H HH H 2. H R^(A2 ) H H H H H 3. H R^(A3 ) H H H H H 4. H R^(A4 ) H H H H H5. H R^(A5 ) H H H H H 6. H R^(A6 ) H H H H H 7. H R^(A7 ) H H H H H 8.H R^(A8 ) H H H H H 9. H R^(A9 ) H H H H H 10. H R^(A10) H H H H H 11. HR^(A11) H H H H H 12. H R^(A12) H H H H H 13. H R^(A13) H H H H H 14. HR^(A14) H H H H H 15. H R^(A15) H H H H H 16. H R^(A16) H H H H H 17. HR^(A17) H H H H H 18. H R^(A18) H H H H H 19. H R^(A19) H H H H H 20. HR^(A20) H H H H H 21. H R^(A21) H H H H H 22. H R^(A22) H H H H H 23. HR^(A23) H H H H H 24. H R^(A24) H H H H H 25. H R^(A25) H H H H H 26. HR^(A26) H H H H H 27. H R^(A27) H H H H H 28. H R^(A28) H H H H H 29. HR^(A29) H H H H H 30. H R^(A30) H H H H H 31. H R^(A31) H H H H H 32. HR^(A32) H H H H H 33. H R^(A33) H H H H H 34. H R^(A34) H H H H H 35. HR^(A35) H H H H H 36. H R^(A36) H H H H H 37. H R^(A37) H H H H H 38. HR^(A38) H H H H H 39. H R^(A39) H H H H H 40. H R^(A40) H H H H H 41. HR^(A41) H H H H H 42. H R^(A42) H H H H H 43. H R^(A43) H H H H H 44. HR^(A44) H H H H H 45. H R^(A45) H H H H H 46. H R^(A46) H H H H H 47. HR^(A47) H H H H H 48. H R^(A48) H H H H H 49. H R^(A49) H H H H H 50. HR^(A50) H H H H H 51. H R^(A51) H H H H H 52. H R^(A52) H H H H H 53. HR^(A53) H H H H H 54. H R^(A54) H H H H H 55. H R^(A55) H H H H H 56. HR^(A56) H H H H H 57. H R^(A57) H H H H H 58. H R^(A58) H H H H H 59. HR^(A59) H H H H H 60. H R^(A60) H H H H H 61. H R^(A61) H H H H H 62. HR^(A62) H H H H H 63. H R^(A63) H H H H H 64. H R^(A64) H H H H H 65. HR^(A65) H H H H H 66. H R^(A66) H H H H H 67. H R^(A67) H H H H H 68. HR^(A68) H H H H H 69. H R^(A69) H H H H H 70. H R^(A70) H H H H H 71. HR^(A71) H H H H H 72. H R^(A72) H H H H H 73. H R^(A73) H H H H H 74. HR^(A74) H H H H H 75. H R^(A75) H H H H H 76. H R^(A76) H H H H H 77. HR^(A77) H H H H H 78. H R^(A78) H H H H H 79. H R^(A79) H H H H H 80. HR^(A80) H H H H H 81. H R^(A81) H H H H H 82. H R^(A82) H H H H H 83. HR^(A83) H H H H H 84. H R^(A84) H H H H H 85. H R^(A85) H H H H H 86. HR^(A86) H H H H H 87. H R^(A87) H H H H H 88. H R^(A88) H H H H H 89. HR^(A89) H H H H H 90. H R^(A90) H H H H H 91. H R^(A91) H H H H H 92. HR^(A92) H H H H H 93. H R^(A93) H H H H H 94. CD₃ R^(A1 ) H H H H H 95.CD₃ R^(A2 ) H H H H H 96. CD₃ R^(A3 ) H H H H H 97. CD₃ R^(A4 ) H H H HH 98. CD₃ R^(A5 ) H H H H H 99. CD₃ R^(A6 ) H H H H H 100. CD₃ R^(A7 ) HH H H H 101. CD₃ R^(A8 ) H H H H H 102. CD₃ R^(A9 ) H H H H H 103. CD₃R^(A10) H H H H H 104. CD₃ R^(A11) H H H H H 105. CD₃ R^(A12) H H H H H106. CD₃ R^(A13) H H H H H 107. CD₃ R^(A14) H H H H H 108. CD₃ R^(A15) HH H H H 109. CD₃ R^(A16) H H H H H 110. CD₃ R^(A17) H H H H H 111. CD₃R^(A18) H H H H H 112. CD₃ R^(A19) H H H H H 113. CD₃ R^(A20) H H H H H114. CD₃ R^(A21) H H H H H 115. CD₃ R^(A22) H H H H H 116. CD₃ R^(A23) HH H H H 117. CD₃ R^(A24) H H H H H 118. CD₃ R^(A25) H H H H H 119. CD₃R^(A26) H H H H H 120. CD₃ R^(A27) H H H H H 121. CD₃ R^(A28) H H H H H122. CD₃ R^(A29) H H H H H 123. CD₃ R^(A30) H H H H H 124. CD₃ R^(A31) HH H H H 125. CD₃ R^(A32) H H H H H 126. CD₃ R^(A33) H H H H H 127. CD₃R^(A34) H H H H H 128. CD₃ R^(A35) H H H H H 129. CD₃ R^(A36) H H H H H130. CD₃ R^(A37) H H H H H 131. CD₃ R^(A38) H H H H H 132. CD₃ R^(A39) HH H H H 133. CD₃ R^(A40) H H H H H 134. CD₃ R^(A41) H H H H H 135. CD₃R^(A42) H H H H H 136. CD₃ R^(A43) H H H H H 137. CD₃ R^(A44) H H H H H138. CD₃ R^(A45) H H H H H 139. CD₃ R^(A46) H H H H H 140. CD₃ R^(A47) HH H H H 141. CD₃ R^(A48) H H H H H 142. CD₃ R^(A49) H H H H H 143. CD₃R^(A50) H H H H H 144. CD₃ R^(A51) H H H H H 145. CD₃ R^(A52) H H H H H146. CD₃ R^(A53) H H H H H 147. CD₃ R^(A54) H H H H H 148. CD₃ R^(A55) HH H H H 149. CD₃ R^(A56) H H H H H 150. CD₃ R^(A57) H H H H H 151. CD₃R^(A58) H H H H H 152. CD₃ R^(A59) H H H H H 153. CD₃ R^(A60) H H H H H154. CD₃ R^(A61) H H H H H 155. CD₃ R^(A62) H H H H H 156. CD₃ R^(A63) HH H H H 157. CD₃ R^(A64) H H H H H 158. CD₃ R^(A65) H H H H H 159. CD₃R^(A66) H H H H H 160. CD₃ R^(A67) H H H H H 161. CD₃ R^(A68) H H H H H162. CD₃ R^(A69) H H H H H 163. CD₃ R^(A70) H H H H H 164. CD₃ R^(A71) HH H H H 165. CD₃ R^(A72) H H H H H 166. CD₃ R^(A73) H H H H H 167. CD₃R^(A74) H H H H H 168. CD₃ R^(A75) H H H H H 169. CD₃ R^(A76) H H H H H170. CD₃ R^(A77) H H H H H 171. CD₃ R^(A78) H H H H H 172. CD₃ R^(A79) HH H H H 173. CD₃ R^(A80) H H H H H 174. CD₃ R^(A81) H H H H H 175. CD₃R^(A82) H H H H H 176. CD₃ R^(A83) H H H H H 177. CD₃ R^(A84) H H H H H178. CD₃ R^(A85) H H H H H 179. CD₃ R^(A86) H H H H H 180. CD₃ R^(A87) HH H H H 181. CD₃ R^(A88) H H H H H 182. CD₃ R^(A89) H H H H H 183. CD₃R^(A90) H H H H H 184. CD₃ R^(A91) H H H H H 185. CD₃ R^(A92) H H H H H186. CD₃ R^(A93) H H H H H 187. H R^(A1 ) H CD₃ H H H 188. H R^(A2 ) HCD₃ H H H 189. H R^(A3 ) H CD₃ H H H 190. H R^(A4 ) H CD₃ H H H 191. HR^(A5 ) H CD₃ H H H 192. H R^(A6 ) H CD₃ H H H 193. H R^(A7 ) H CD₃ H HH 194. H R^(A8 ) H CD₃ H H H 195. H R^(A10) H CD₃ H H H 196. H R^(A11) HCD₃ H H H 197. H R^(A12) H CD₃ H H H 198. H R^(A13) H CD₃ H H H 199. HR^(A14) H CD₃ H H H 200. H R^(A15) H CD₃ H H H 201. H R^(A16) H CD₃ H HH 202. H R^(A17) H CD₃ H H H 203. H R^(A18) H CD₃ H H H 204. H R^(A19) HCD₃ H H H 205. H R^(A20) H CD₃ H H H 206. H R^(A21) H CD₃ H H H 207. HR^(A22) H CD₃ H H H 208. H R^(A23) H CD₃ H H H 209. H R^(A24) H CD₃ H HH 210. H R^(A25) H CD₃ H H H 211. H R^(A26) H CD₃ H H H 212. H R^(A27) HCD₃ H H H 213. H R^(A28) H CD₃ H H H 214. H R^(A29) H CD₃ H H H 215. HR^(A30) H CD₃ H H H 216. H R^(A31) H CD₃ H H H 217. H R^(A32) H CD₃ H HH 218. H R^(A33) H CD₃ H H H 219. H R^(A34) H CD₃ H H H 220. H R^(A35) HCD₃ H H H 221. H R^(A36) H CD₃ H H H 222. H R^(A37) H CD₃ H H H 223. HR^(A38) H CD₃ H H H 224. H R^(A39) H CD₃ H H H 225. H R^(A40) H CD₃ H HH 226. H R^(A41) H CD₃ H H H 227. H R^(A42) H CD₃ H H H 228. H R^(A43) HCD₃ H H H 229. H R^(A44) H CD₃ H H H 230. H R^(A45) H CD₃ H H H 231. HR^(A46) H CD₃ H H H 232. H R^(A47) H CD₃ H H H 233. H R^(A48) H CD₃ H HH 234. H R^(A49) H CD₃ H H H 235. H R^(A50) H CD₃ H H H 236. H R^(A51) HCD₃ H H H 237. H R^(A52) H CD₃ H H H 238. H R^(A53) H CD₃ H H H 239. HR^(A54) H CD₃ H H H 240. H R^(A55) H CD₃ H H H 241. H R^(A56) H CD₃ H HH 242. H R^(A57) H CD₃ H H H 243. H R^(A58) H CD₃ H H H 244. H R^(A59) HCD₃ H H H 245. H R^(A60) H CD₃ H H H 246. H R^(A61) H CD₃ H H H 247. HR^(A62) H CD₃ H H H 248. H R^(A63) H CD₃ H H H 249. H R^(A64) H CD₃ H HH 250. H R^(A65) H CD₃ H H H 251. H R^(A66) H CD₃ H H H 252. H R^(A67) HCD₃ H H H 253. H R^(A68) H CD₃ H H H 254. H R^(A69) H CD₃ H H H 255. HR^(A70) H CD₃ H H H 256. H R^(A71) H CD₃ H H H 257. H R^(A72) H CD₃ H HH 258. H R^(A73) H CD₃ H H H 259. H R^(A74) H CD₃ H H H 260. H R^(A75) HCD₃ H H H 261. H R^(A76) H CD₃ H H H 262. H R^(A77) H CD₃ H H H 263. HR^(A78) H CD₃ H H H 264. H R^(A79) H CD₃ H H H 265. H R^(A80) H CD₃ H HH 266. H R^(A81) H CD₃ H H H 267. H R^(A82) H CD₃ H H H 268. H R^(A83) HCD₃ H H H 269. H R^(A84) H CD₃ H H H 270. H R^(A85) H CD₃ H H H 271. HR^(A86) H CD₃ H H H 272. H R^(A87) H CD₃ H H H 273. H R^(A88) H CD₃ H HH 274. H R^(A89) H CD₃ H H H 275. H R^(A90) H CD₃ H H H 276. H R^(A91) HCD₃ H H H 277. H R^(A92) H CD₃ H H H 278. H R^(A93) H CD₃ H H H 279. CD₃R^(A1 ) H CD₃ H H H 280. CD₃ R^(A2 ) H CD₃ H H H 281. CD₃ R^(A3 ) H CD₃H H H 282. CD₃ R^(A4 ) H CD₃ H H H 283. CD₃ R^(A5 ) H CD₃ H H H 284. CD₃R^(A6 ) H CD₃ H H H 285. CD₃ R^(A7 ) H CD₃ H H H 286. CD₃ R^(A8 ) H CD₃H H H 287. CD₃ R^(A9 ) H CD₃ H H H 288. CD₃ R^(A10) H CD₃ H H H 289. CD₃R^(A11) H CD₃ H H H 290. CD₃ R^(A12) H CD₃ H H H 291. CD₃ R^(A13) H CD₃H H H 292. CD₃ R^(A14) H CD₃ H H H 293. CD₃ R^(A15) H CD₃ H H H 294. CD₃R^(A16) H CD₃ H H H 295. CD₃ R^(A17) H CD₃ H H H 296. CD₃ R^(A18) H CD₃H H H 297. CD₃ R^(A19) H CD₃ H H H 298. CD₃ R^(A20) H CD₃ H H H 299. CD₃R^(A21) H CD₃ H H H 300. CD₃ R^(A22) H CD₃ H H H 301. CD₃ R^(A23) H CD₃H H H 302. CD₃ R^(A24) H CD₃ H H H 303. CD₃ R^(A25) H CD₃ H H H 304. CD₃R^(A26) H CD₃ H H H 305. CD₃ R^(A27) H CD₃ H H H 306. CD₃ R^(A28) H CD₃H H H 307. CD₃ R^(A29) H CD₃ H H H 308. CD₃ R^(A30) H CD₃ H H H 309. CD₃R^(A31) H CD₃ H H H 310. CD₃ R^(A32) H CD₃ H H H 311. CD₃ R^(A33) H CD₃H H H 312. CD₃ R^(A34) H CD₃ H H H 313. CD₃ R^(A35) H CD₃ H H H 314. CD₃R^(A36) H CD₃ H H H 315. CD₃ R^(A37) H CD₃ H H H 316. CD₃ R^(A38) H CD₃H H H 317. CD₃ R^(A39) H CD₃ H H H 318. CD₃ R^(A40) H CD₃ H H H 319. CD₃R^(A41) H CD₃ H H H 320. CD₃ R^(A42) H CD₃ H H H 321. CD₃ R^(A43) H CD₃H H H 322. CD₃ R^(A44) H CD₃ H H H 323. CD₃ R^(A45) H CD₃ H H H 324. CD₃R^(A46) H CD₃ H H H 325. CD₃ R^(A47) H CD₃ H H H 326. CD₃ R^(A48) H CD₃H H H 327. CD₃ R^(A49) H CD₃ H H H 328. CD₃ R^(A50) H CD₃ H H H 329. CD₃R^(A51) H CD₃ H H H 330. CD₃ R^(A52) H CD₃ H H H 331. CD₃ R^(A53) H CD₃H H H 332. CD₃ R^(A54) H CD₃ H H H 333. CD₃ R^(A55) H CD₃ H H H 334. CD₃R^(A56) H CD₃ H H H 335. CD₃ R^(A57) H CD₃ H H H 336. CD₃ R^(A58) H CD₃H H H 337. CD₃ R^(A59) H CD₃ H H H 338. CD₃ R^(A60) H CD₃ H H H 339. CD₃R^(A61) H CD₃ H H H 340. CD₃ R^(A62) H CD₃ H H H 341. CD₃ R^(A63) H CD₃H H H 342. CD₃ R^(A64) H CD₃ H H H 343. CD₃ R^(A65) H CD₃ H H H 344. CD₃R^(A66) H CD₃ H H H 345. CD₃ R^(A67) H CD₃ H H H 346. CD₃ R^(A68) H CD₃H H H 347. CD₃ R^(A69) H CD₃ H H H 348. CD₃ R^(A70) H CD₃ H H H 349. CD₃R^(A71) H CD₃ H H H 350. CD₃ R^(A72) H CD₃ H H H 351. CD₃ R^(A73) H CD₃H H H 352. CD₃ R^(A74) H CD₃ H H H 353. CD₃ R^(A75) H CD₃ H H H 354. CD₃R^(A76) H CD₃ H H H 355. CD₃ R^(A77) H CD₃ H H H 356. CD₃ R^(A78) H CD₃H H H 357. CD₃ R^(A79) H CD₃ H H H 358. CD₃ R^(A80) H CD₃ H H H 359. CD₃R^(A81) H CD₃ H H H 360. CD₃ R^(A82) H CD₃ H H H 361. CD₃ R^(A83) H CD₃H H H 362. CD₃ R^(A84) H CD₃ H H H 363. CD₃ R^(A85) H CD₃ H H H 364. CD₃R^(A86) H CD₃ H H H 365. CD₃ R^(A87) H CD₃ H H H 366. CD₃ R^(A88) H CD₃H H H 367. CD₃ R^(A89) H CD₃ H H H 368. CD₃ R^(A90) H CD₃ H H H 369. CD₃R^(A91) H CD₃ H H H 370. CD₃ R^(A92) H CD₃ H H H 371. CD₃ R^(A93) H CD₃H H H

In some embodiments of the compound, L_(B) is selected from the groupconsisting of L_(B1) to L_(B1471) having a structure according to

wherein R^(B1), R^(B2), R^(B3), and R^(B4) are defined as providedbelow:

L_(Bi), where i is R^(B1) R^(B2) R^(B3) R^(B4) 1. H H H H 2. CH₃ H H H3. H CH₃ H H 4. H H CH₃ H 5. CH₃ CH₃ H CH₃ 6. CH₃ H CH₃ H 7. CH₃ H H CH₃8. H CH₃ CH₃ H 9. H CH₃ H CH₃ 10. H H CH₃ CH₃ 11. CH₃ CH₃ CH₃ H 12. CH₃CH₃ H CH₃ 13. CH₃ H CH₃ CH₃ 14. H CH₃ CH₃ CH₃ 15. CH₃ CH₃ CH₃ CH₃ 16.CH₂CH₃ H H H 17. CH₂CH₃ CH₃ H CH₃ 18. CH₂CH₃ H CH₃ H 19. CH₂CH₃ H H CH₃20. CH₂CH₃ CH₃ CH₃ H 21. CH₂CH₃ CH₃ H CH₃ 22. CH₂CH₃ H CH₃ CH₃ 23.CH₂CH₃ CH₃ CH₃ CH₃ 24. H CH₂CH₃ H H 25. CH₃ CH₂CH₃ H CH₃ 26. H CH₂CH₃CH₃ H 27. H CH₂CH₃ H CH₃ 28. CH₃ CH₂CH₃ CH₃ H 29. CH₃ CH₂CH₃ H CH₃ 30. HCH₂CH₃ CH₃ CH₃ 31. CH₃ CH₂CH₃ CH₃ CH₃ 32. H H CH₂CH₃ H 33. CH₃ H CH₂CH₃H 34. H CH₃ CH₂CH₃ H 35. H H CH₂CH₃ CH₃ 36. CH₃ CH₃ CH₂CH₃ H 37. CH₃ HCH₂CH₃ CH₃ 38. H CH₃ CH₂CH₃ CH₃ 39. CH₃ CH₃ CH₂CH₃ CH₃ 40. CH(CH₃)₂ H HH 41. CH(CH₃)₂ CH₃ H CH₃ 42. CH(CH₃)₂ H CH₃ H 43. CH(CH₃)₂ H H CH₃ 44.CH(CH₃)₂ CH₃ CH₃ H 45. CH(CH₃)₂ CH₃ H CH₃ 46. CH(CH₃)₂ H CH₃ CH₃ 47.CH(CH₃)₂ CH₃ CH₃ CH₃ 48. H CH(CH₃)₂ H H 49. CH₃ CH(CH₃)₂ H CH₃ 50. HCH(CH₃)₂ CH₃ H 51. H CH(CH₃)₂ H CH₃ 52. CH₃ CH(CH₃)₂ CH₃ H 53. CH₃CH(CH₃)₂ H CH₃ 54. H CH(CH₃)₂ CH₃ CH₃ 55. CH₃ CH(CH₃)₂ CH₃ CH₃ 56. H HCH(CH₃)₂ H 57. CH₃ H CH(CH₃)₂ H 58. H CH₃ CH(CH₃)₂ H 59. H H CH(CH₃)₂CH₃ 60. CH₃ CH₃ CH(CH₃)₂ H 61. CH₃ H CH(CH₃)₂ CH₃ 62. H CH₃ CH(CH₃)₂ CH₃63. CH₃ CH₃ CH(CH₃)₂ CH₃ 64. CH₂CH(CH₃)₂ H H H 65. CH₂CH(CH₃)₂ CH₃ H CH₃66. CH₂CH(CH₃)₂ H CH₃ H 67. CH₂CH(CH₃)₂ H H CH₃ 68. CH₂CH(CH₃)₂ CH₃ CH₃H 69. CH₂CH(CH₃)₂ CH₃ H CH₃ 70. CH₂CH(CH₃)₂ H CH₃ CH₃ 71. CH₂CH(CH₃)₂CH₃ CH₃ CH₃ 72. H CH₂CH(CH₃)₂ H H 73. CH₃ CH₂CH(CH₃)₂ H CH₃ 74. HCH₂CH(CH₃)₂ CH₃ H 75. H CH₂CH(CH₃)₂ H CH₃ 76. CH₃ CH₂CH(CH₃)₂ CH₃ H 77.CH₃ CH₂CH(CH₃)₂ H CH₃ 78. H CH₂CH(CH₃)₂ CH₃ CH₃ 79. CH₃ CH₂CH(CH₃)₂ CH₃CH₃ 80. H H CH₂CH(CH₃)₂ H 81. CH₃ H CH₂CH(CH₃)₂ H 82. H CH₃ CH₂CH(CH₃)₂H 83. H H CH₂CH(CH₃)₂ CH₃ 84. CH₃ CH₃ CH₂CH(CH₃)₂ H 85. CH₃ HCH₂CH(CH₃)₂ CH₃ 86. H CH₃ CH₂CH(CH₃)₂ CH₃ 87. CH₃ CH₃ CH₂CH(CH₃)₂ CH₃88. C(CH₃)₃ H H H 89. C(CH₃)₃ CH₃ H CH₃ 90. C(CH₃)₃ H CH₃ H 91. C(CH₃)₃H H CH₃ 92. C(CH₃)₃ CH₃ CH₃ H 93. C(CH₃)₃ CH₃ H CH₃ 94. C(CH₃)₃ H CH₃CH₃ 95. C(CH₃)₃ CH₃ CH₃ CH₃ 96. H C(CH₃)₃ H H 97. CH₃ C(CH₃)₃ H CH₃ 98.H C(CH₃)₃ CH₃ H 99. H C(CH₃)₃ H CH₃ 100. CH₃ C(CH₃)₃ CH₃ H 101. CH₃C(CH₃)₃ H CH₃ 102. H C(CH₃)₃ CH₃ CH₃ 103. CH₃ C(CH₃)₃ CH₃ CH₃ 104. H HC(CH₃)₃ H 105. CH₃ H C(CH₃)₃ H 106. H CH₃ C(CH₃)₃ H 107. H H C(CH₃)₃ CH₃108. CH₃ CH₃ C(CH₃)₃ H 109. CH₃ H C(CH₃)₃ CH₃ 110. H CH₃ C(CH₃)₃ CH₃111. CH₃ CH₃ C(CH₃)₃ CH₃ 112. CH₂C(CH₃)₃ H H H 113. CH₂C(CH₃)₃ CH₃ H CH₃114. CH₂C(CH₃)₃ H CH₃ H 115. CH₂C(CH₃)₃ H H CH₃ 116. CH₂C(CH₃)₃ CH₃ CH₃H 117. CH₂C(CH₃)₃ CH₃ H CH₃ 118. CH₂C(CH₃)₃ H CH₃ CH₃ 119. CH₂C(CH₃)₃CH₃ CH₃ CH₃ 120. H CH₂C(CH₃)₃ H H 121. CH₃ CH₂C(CH₃)₃ H CH₃ 122. HCH₂C(CH₃)₃ CH₃ H 123. H CH₂C(CH₃)₃ H CH₃ 124. CH₃ CH₂C(CH₃)₃ CH₃ H 125.CH₃ CH₂C(CH₃)₃ H CH₃ 126. H CH₂C(CH₃)₃ CH₃ CH₃ 127. CH₃ CH₂C(CH₃)₃ CH₃CH₃ 128. H H CH₂C(CH₃)₃ H 129. CH₃ H CH₂C(CH₃)₃ H 130. H CH₃ CH₂C(CH₃)₃H 131. H H CH₂C(CH₃)₃ CH₃ 132. CH₃ CH₃ CH₂C(CH₃)₃ H 133. CH₃ HCH₂C(CH₃)₃ CH₃ 134. H CH₃ CH₂C(CH₃)₃ CH₃ 135. CH₃ CH₃ CH₂C(CH₃)₃ CH₃136.

H H H 137.

CH₃ H CH₃ 138.

H CH₃ H 139.

H H CH₃ 140.

CH₃ CH₃ H 141.

CH₃ H CH₃ 142.

H CH₃ CH₃ 143.

CH₃ CH₃ CH₃ 144. H

H H 145. CH₃

H CH₃ 146. H

CH₃ H 147. H

H CH₃ 148. CH₃

CH₃ H 149. CH₃

H CH₃ 150. H

CH₃ CH₃ 151. CH₃

CH₃ CH₃ 152. H H

H 153. CH₃ H

H 154. H CH₃

H 155. H H

CH₃ 156. CH₃ CH₃

H 157. CH₃ H

CH₃ 158. H CH₃

CH₃ 159. CH₃ CH₃

CH₃ 160.

H H H 161.

CH₃ H CH₃ 162.

H CH₃ H 163.

H H CH₃ 164.

CH₃ CH₃ H 165.

CH₃ H CH₃ 166.

H CH₃ CH₃ 167.

CH₃ CH₃ CH₃ 168. H

H H 169. CH₃

H CH₃ 170. H

CH₃ H 171. H

H CH₃ 172. CH₃

CH₃ H 173. CH₃

H CH₃ 174. H

CH₃ CH₃ 175. CH₃

CH₃ CH₃ 176. H H

H 177. CH₃ H

H 178. H CH₃

H 179. H H

CH₃ 180. CH₃ CH₃

H 181. CH₃ H

CH₃ 182. H CH₃

CH₃ 183. CH₃ CH₃

CH₃ 184.

H H H 185.

CH₃ H CH₃ 186.

H CH₃ H 187.

H H CH₃ 188.

CH₃ CH₃ H 189.

CH₃ H CH₃ 190.

H CH₃ CH₃ 191.

CH₃ CH₃ CH₃ 192. H

H H 193. CH₃

H CH₃ 194. H

CH₃ H 195. H

H CH₃ 196. CH₃

CH₃ H 197. CH₃

H CH₃ 198. H

CH₃ CH₃ 199. CH₃

CH₃ CH₃ 200. H H

H 201. CH₃ H

H 202. H CH₃

H 203. H H

CH₃ 204. CH₃ CH₃

H 205. CH₃ H

CH₃ 206. H CH₃

CH₃ 207. CH₃ CH₃

CH₃ 208.

H H H 209.

CH₃ H CH₃ 210.

H CH₃ H 211.

H H CH₃ 212.

CH₃ CH₃ H 213.

CH₃ H CH₃ 214.

H CH₃ CH₃ 215.

CH₃ CH₃ CH₃ 216. H

H H 217. CH₃

H CH₃ 218. H

CH₃ H 219. H

H CH₃ 220. CH₃

CH₃ H 221. CH₃

H CH₃ 222. H

CH₃ CH₃ 223. CH₃

CH₃ CH₃ 224. H H

H 225. CH₃ H

H 226. H CH₃

H 227. H H

CH₃ 228. CH₃ CH₃

H 229. CH₃ H

CH₃ 230. H CH₃

CH₃ 231. CH₃ CH₃

CH₃ 232.

H H H 233.

CH₃ H CH₃ 234.

H CH₃ H 235.

H H CH₃ 236.

CH₃ CH₃ H 237.

CH₃ H CH₃ 238.

H CH₃ CH₃ 239.

CH₃ CH₃ CH₃ 240. H

H H 241. CH₃

H CH₃ 242. H

CH₃ H 243. H

H CH₃ 244. CH₃

CH₃ H 245. CH₃

H CH₃ 246. H

CH₃ CH₃ 247. CH₃

CH₃ CH₃ 248. H H

H 249. CH₃ H

H 250. H CH₃

H 251. H H

CH₃ 252. CH₃ CH₃

H 253. CH₃ H

CH₃ 254. H CH₃

CH₃ 255. CH₃ CH₃

CH₃ 256.

H H H 257.

CH₃ H CH₃ 258.

H CH₃ H 259.

H H CH₃ 260.

CH₃ CH₃ H 261.

CH₃ H CH₃ 262.

H CH₃ CH₃ 263.

CH₃ CH₃ CH₃ 264. H

H H 265. CH₃

H CH₃ 266. H

CH₃ H 267. H

H CH₃ 268. CH₃

CH₃ H 269. CH₃

H CH₃ 270. H

CH₃ CH₃ 271. CH₃

CH₃ CH₃ 272. H H

H 273. CH₃ H

H 274. H CH₃

H 275. H H

CH₃ 276. CH₃ CH₃

H 277. CH₃ H

CH₃ 278. H CH₃

CH₃ 279. CH₃ CH₃

CH₃ 280. CH(CH₃)₂ H CH₂CH₃ H 281. CH(CH₃)₂ H CH(CH₃)₂ H 282. CH(CH₃)₂ HCH₂CH(CH₃)₂ H 283. CH(CH₃)₂ H C(CH₃)₃ H 284. CH(CH₃)₂ H CH₂C(CH₃)₃ H285. CH(CH₃)₂ H

H 286. CH(CH₃)₂ H

H 287. CH(CH₃)₂ H

H 288. CH(CH₃)₂ H

H 289. CH(CH₃)₂ H

H 290. CH(CH₃)₂ H

H 291. C(CH₃)₃ H CH₂CH₃ H 292. C(CH₃)₃ H CH(CH₃)₂ H 293. C(HC₃)₃ HCH₂CH(CH₃)₂ H 294. C(CH₃)₃ H C(CH₃)₃ H 295. C(CH₃)₃ H CH₂C(CH₃)₃ H 296.C(CH₃)₃ H

H 297. C(CH₃)₃ H

H 298. C(CH₃)₃ H

H 299. C(CH₃)₃ H

H 300. C(CH₃)₃ H

H 301. C(CH₃)₃ H

H 302. CH₂C(CH₃)₃ H CH₂CH₃ H 303. CH₂C(CH₃)₃ H CH(CH₃)₂ H 304.CH₂C(CH₃)₃ H CH₂CH(CH₃)₂ H 305. CH₂C(CH₃)₃ H C(CH₃)₃ H 306. CH₂C(CH₃)₃ HCH₂C(CH₃)₃ H 307. CH₂C(CH₃)₃ H

H 308. CH₂C(CH₃)₃ H

H 309. CH₂C(CH₃)₃ H

H 310. CH₂C(CH₃)₃ H

H 311. CH₂C(CH₃)₃ H

H 312. CH₂C(CH₃)₃ H

H 313.

H CH₂CH₃ H 314.

H CH(CH₃)₂ H 315.

H CH₂CH(CH₃)₂ H 316.

H C(CH₃)₃ H 317.

H CH₂C(CH₃)₃ H 318.

H

H 319.

H

H 320.

H

H 321.

H

H 322.

H

H 323.

H

H 324.

H CH₂CH₃ H 325.

H CH(CH₃)₂ H 326.

H CH₂CH(CH₃)₂ H 327.

H C(CH₃)₃ H 328.

H CH₂C(CH₃)₃ H 329.

H

H 330.

H

H 331.

H

H 332.

H

H 333.

H

H 334.

H

H 335.

H CH₂CH(CH₃)₂ H 336.

H C(CH₃)₃ H 337.

H CH₂C(CH₃)₃ H 338.

H CH₂CH₂CF₃ H 339.

H CH₂C(CH₃)₂CF₃ H 340.

H

H 341.

H

H 342.

H

H 343.

H

H 344.

H

H 345.

H

H 346.

H CH₂CH(CH₃)₂ H 347.

H C(CH₃)₃ H 348.

H CH₂C(CH₃)₃ H 349.

H

H 350.

H

H 351.

H

H 352.

H

H 353.

H

H 354.

H

H 355.

H CH₂CH(CH₃)₂ H 356.

H C(CH₃)₃ H 357.

H CH₂C(CH₃)₃ H 358.

H

H 359.

H

H 360.

H

H 361.

H

H 362.

H

H 363.

H

H 364. H H H H 365. CD₃ H H H 366. H CD₃ H H 367. H H CD₃ H 368. CD₃ CD₃H CD₃ 369. CD₃ H CD₃ H 370. CD₃ H H CD₃ 371. H CD₃ CH₃ H 372. H CD₃ HCD₃ 373. H H CD₃ CD₃ 374. CD₃ CD₃ CD₃ H 375. CD₃ CD₃ H CD₃ 376. CD₃ HCD₃ CD₃ 377. H CD₃ CD₃ CD₃ 378. CD₃ CD₃ CD₃ CD₃ 379. CD₂CH₃ H H H 380.CD₂CH₃ CD₃ H CD₃ 381. CD₂CH₃ H CD₃ H 382. CD₂CH₃ H H CD₃ 383. CD₂CH₃ CD₃CD₃ H 384. CD₂CH₃ CD₃ H CD₃ 385. CD₂CH₃ H CD₃ CD₃ 386. CD₂CH₃ CD₃ CD₃CD₃ 387. H CDCH₃ H H 388. CH₃ CD₂CH₃ H CD₃ 389. H CD₂CH₃ CD₃ H 390. HCD₂CH₃ H CD₃ 391. CD₃ CD₂CH₃ CD₃ H 392. CD₃ CD₂CH₃ H CD₃ 393. H CD₂CH₃CD₃ CD₃ 394. CD₃ CD₂CH₃ CD₃ CD₃ 395. H H CD₂CH₃ H 396. CD₃ H CD₂CH₃ H397. H CD₃ CD₂CH₃ H 398. H H CD₂CH₃ CD₃ 399. CD₃ CD₃ CD₂CH₃ H 400. CD₃ HCD₂CH₃ CD₃ 401. H CD₃ CD₂CH₃ CD₃ 402. CD₃ CD₃ CD₂CH₃ CD₃ 403. CD(CH₃)₂ HH H 404. CD(CH₃)₂ CD₃ H CD₃ 405. CD(CH₃)₂ H CD₃ H 406. CD(CH₃)₂ H H CD₃407. CD(CH₃)₂ CD₃ CD₃ H 408. CD(CH₃)₂ CD₃ H CD₃ 409. CD(CH₃)₂ H CD₃ CD₃410. CD(CH₃)₂ CD₃ CD₃ CD₃ 411. H CD(CH₃)₂ H H 412. CD₃ CD(CH₃)₂ H CD₃413. H CD(CH₃)₂ CD₃ H 414. H CD(CH₃)₂ H CD₃ 415. CD₃ CD(CH₃)₂ CD₃ H 416.CD₃ CD(CH₃)₂ H CD₃ 417. H CD(CH₃)₂ CD₃ CD₃ 418. CD₃ CD(CH₃)₂ CD₃ CD₃419. H H CD(CH₃)₂ H 420. CD₃ H CD(CH₃)₂ H 421. H CD₃ CD(CH₃)₂ H 422. H HCD(CH₃)₂ CD₃ 423. CD₃ CD₃ CD(CH₃)₂ H 424. CD₃ H CD(CH₃)₂ CD₃ 425. H CD₃CD(CH₃)₂ CD₃ 426. CD₃ CD₃ CD(CH₃)₂ CD₃ 427. CD(CD₃)₂ H H H 428. CD(CD₃)₂CD₃ H CD₃ 429. CD(CD₃)₂ H CD₃ H 430. CD(CD₃)₂ H H CD₃ 431. CD(CD₃)₂ CD₃CD₃ H 432. CD(CD₃)₂ CD₃ H CD₃ 433. CD(CD₃)₂ H CD₃ CD₃ 434. CD(CD₃)₂ CD₃CD₃ CD₃ 435. H CD(CD₃)₂ H H 436. CH₃ CD(CD₃)₂ H CD₃ 437. H CD(CD₃)₂ CD₃H 438. H CD(CD₃)₂ H CD₃ 439. CD₃ CD(CD₃)₂ CD₃ H 440. CD₃ CD(CD₃)₂ H CD₃441. H CD(CD₃)₂ CD₃ CD₃ 442. CD₃ CD(CD₃)₂ CD₃ CD₃ 443. H H CD(CD₃)₂ H444. CD₃ H CD(CD₃)₂ H 445. H CD₃ CD(CD₃)₂ H 446. H H CD(CD₃)₂ CD₃ 447.CD₃ CD₃ CD(CD₃)2 H 448. CD₃ H CD(CD₃)2 CD₃ 449. H CD₃ CD(CD₃)₂ CD₃ 450.CD₃ CD₃ CD(CD₃)₂ CD₃ 451. CD₂CH(CH₃)₂ H H H 452. CD₂CH(CH₃)₂ CD₃ H CD₃453. CD₂CH(CH₃)₂ H CD₃ H 454. CD₂CH(CH₃)₂ H H CD₃ 455. CD₂CH(CH₃)₂ CD₃CD₃ H 456. CD₂CH(CH₃)₂ CD₃ H CD₃ 457. CD₂CH(CH₃)₂ H CD₃ CD₃ 458.CD₂CH(CH₃)₂ CD₃ CD₃ CD₃ 459. H CD₂CH(CH₃)₂ H H 460. CD₃ CD₂CH(CH₃)₂ HCD₃ 461. H CD₂CH(CH₃)₂ CD₃ H 462. H CD₂CH(CH₃)₂ H CD₃ 463. CD₃CD₂CH(CH₃)₂ CD₃ H 464. CD₃ CD₂CH(CH₃)₂ H CD₃ 465. H CD₂CH(CH₃)₂ CD₃ CD₃466. CD₃ CD₂CH(CH₃)₂ CD₃ CD₃ 467. H H CD₂CH(CH₃)₂ H 468. CD₃ HCD₂CH(CH₃)₂ H 469. H CD₃ CD₂CH(CH₃)₂ H 470. H H CD₂CH(CH₃)₂ CD₃ 471. CD₃CD₃ CD₂CH(CH₃)₂ H 472. CD₃ H CD₂CH(CH₃)₂ CD₃ 473. H CD₃ CD₂CH(CH₃)₂ CD₃474. CD₃ CD₃ CD₂CH(CH₃)₂ CD₃ 475. CD₂C(CH₃)₃ H H H 476. CD₂C(CH₃)₃ CD₃ HCD₃ 477. CD₂C(CH₃)₃ H CD₃ H 478. CD₂C(CH₃)₃ H H CD₃ 479. CD₂C(CH₃)₃ CD₃CD₃ H 480. CD₂C(CH₃)₃ CD₃ H CD₃ 481. CD₂C(CH₃)₃ H CD₃ CD₃ 482.CD₂C(CH₃)₃ CH₃ CD₃ CD₃ 483. H CD₂C(CH₃)₃ H H 484. CD₃ CD₂C(CH₃)₃ H CD₃485. H CD₂C(CH₃)₃ CD₃ H 486. H CD₂C(CH₃)₃ H CD₃ 487. CD₃ CD₂C(CH₃)₃ CD₃H 488. CD₃ CD₂C(CH₃)₃ H CD₃ 489. H CD₂C(CH₃)₃ CD₃ CD₃ 490. CD₃CD₂C(CH₃)₃ CD₃ CD₃ 491. H H CD₂C(CH₃)₃ H 492. CD₃ H CD₂C(CH₃)₃ H 493. HCD₃ CD₂C(CH₃)₃ H 494. H H CD₂C(CH₃)₃ CD₃ 495. CD₃ CD₃ CD₂C(CH₃)₃ H 496.CD₃ H CD₂C(CH₃)₃ CD₃ 497. H CD₃ CD₂C(CH₃)₃ CD₃ 498. CD₃ CD₃ CD₂C(CH₃)₃CD₃ 499.

H H H 500.

CD₃ H CD₃ 501.

H CD₃ H 502.

H H CD₃ 503.

CD₃ CD₃ H 504.

CD₃ H CD₃ 505.

H CD₃ CD₃ 506.

CD₃ CD₃ CD₃ 507. H

H H 508. CD₃

H CD₃ 509. H

CD₃ H 510. H

H CD₃ 511. CD₃

CD₃ H 512. CD₃

H CD₃ 513. H

CD₃ CD₃ 514. CD₃

CD₃ CD₃ 515. H H

H 516. CD₃ H

H 517. H CD₃

H 518. H H

CD₃ 519. CD₃ CD₃

H 520. CD₃ H

CD₃ 521. H CD₃

CD₃ 522. CD₃ CD₃

CD₃ 523.

H H H 524.

CD₃ H CD₃ 525.

H CD₃ H 526.

H H CD₃ 527.

CD₃ CD₃ H 528.

CD₃ H CD₃ 529.

H CD₃ CD₃ 530.

CD₃ CD₃ CD₃ 531. H

H H 532. CH₃

H CD₃ 533. H

CD₃ H 534. H

H CD₃ 535. CD₃

CD₃ H 536. CD₃

H CD₃ 537. H

CD₃ CD₃ 538. CH₃

CD₃ CD₃ 539. H H

H 540. CD₃ H

H 541. H CD₃

H 542. H H

CD₃ 543. CD₃ CD₃

H 544. CD₃ H

CD₃ 545. H CD₃

CD₃ 546. CD₃ CD₃

CD₃ 547.

H H H 548.

CD₃ H CD₃ 549.

H CD₃ H 550.

H H CD₃ 551.

CD₃ CD₃ H 552.

CD₃ H CD₃ 553.

H CD₃ CD₃ 554.

CD₃ CD₃ CD₃ 555. H

H H 556. CD₃

H CD₃ 557. H

CD₃ H 558. H

H CD₃ 559. CD

CD₃ H 560. CD₃

H CD₃ 561. H

CD₃ CD₃ 562. CD₃

CD₃ CD₃ 563. H H

H 564. CD₃ H

H 565. H CD₃

H 566. H H

CD₃ 567. CD₃ CD₃

H 568. CD₃ H

CD₃ 569. H CD₃

CD₃ 570. CD₃ CD₃

CD₃ 571.

H H H 572.

CD₃ H CD₃ 573.

H CD₃ H 574.

H H CD₃ 575.

CD₃ CD₃ H 576.

CD₃ H CD₃ 577.

H CD₃ CD₃ 578.

CD₃ CD₃ CD₃ 579. H

H H 580. CD₃

H CD₃ 581. H

CD₃ H 582. H

H CD₃ 583. CD₃

CD₃ H 584. CD₃

H CD₃ 585. H

CD₃ CD₃ 586. CD₃

CD₃ CD₃ 587. H H

H 588. CD₃ H

H 589. H CD₃

H 590. H H

CD₃ 591. CD₃ CD₃

H 592. CD₃ H

CD₃ 593. H CD₃

CD₃ 594. CD₃ CD₃

CD₃ 595.

H H H 596.

CD₃ H CD₃ 597.

H CD₃ H 598.

H H CD₃ 599.

CD₃ CD₃ H 600.

CD₃ H CD₃ 601.

H CD₃ CD₃ 602.

CD₃ CD₃ CD₃ 603. H

H H 604. CD₃

H CD₃ 605. H

CD₃ H 606. H

H CD₃ 607. CD₃

CD₃ H 608. CD₃

H CD₃ 609. H

CD₃ CD₃ 610. CD₃

CD₃ CD₃ 611. H H

H 612. CD₃ H

H 613. H CD₃

H 614. H H

CD₃ 615. CD₃ CD₃

H 616. CD₃ H

CD₃ 617. H CD₃

CD₃ 618. CD₃ CD₃

CD₃ 619.

H H H 620.

CD₃ H CD₃ 621.

H CD₃ H 622.

H H CD₃ 623.

CH₃ CH₃ H 624.

CD₃ H CD₃ 625.

H CD₃ CD₃ 626.

CD₃ CD₃ CD₃ 627. H

H H 628. CD₃

H CD₃ 629. H

CD₃ H 630. H

H CD₃ 631. CD₃

CD₃ H 632. CD₃

H CD₃ 633. H

CD₃ CD₃ 634. CD₃

CD₃ CD₃ 635. H H

H 636. CD₃ H

H 637. H CD₃

H 638. H H

CH₃ 639. CD₃ CD₃

H 640. CD₃ H

CD₃ 641. H CD₃

CD₃ 642. CD₃ CD₃

CD₃ 643. CD(CH₃)₂ H CD₂CH₃ H 644. CD(CH₃)₂ H CD(CH₃)₂ H 645. CD(CH₃)₂ HCD₂CH(CH₃)₂ H 646. CD(CH₃)₂ H C(CH₃)₃ H 647. CD(CH₃)₂ H CD₂C(CH₃)₃ H648. CD(CH₃)₂ H

H 649. CD(CH₃)₂ H

H 650. CD(CH₃)₂ H

H 651. CD(CH₃)₂ H

H 652. CD(CH₃)₂ H

H 653. CD(CH₃)₂ H

H 654. C(CH₃)₃ H CD₂CH₃ H 655. C(CH₃)₃ H CD(CH₃)₂ H 656. C(CH₃)₃ HCD₂CH(CH₃)₂ H 657. C(CH₃)₃ H C(CH₃)₃ H 658. C(CH₃)₃ H CD₂C(CH₃)₃ H 659.C(CH₃)₃ H

H 660. C(CH₃)₃ H

H 661. C(CH₃)₃ H

H 662. C(CH₃)₃ H

H 663. C(CH₃)₃ H

H 664. C(CH₃)₃ H

H 665. CD₂C(CH₃)₃ H CD₂CH₃ H 666. CD₂C(CH₃)₃ H CD(CH₃)₂ H 667.CD₂C(CH₃)₃ H CD₂CH(CH₃)₂ H 668. CD₂C(CH₃)₃ H C(CH₃)₃ H 669. CD₂C(CH₃)₃ HCD₂C(CH₃)₃ H 670. CD₂C(CH₃)₃ H

H 671. CD₂C(CH₃)₃ H

H 672. CD₂C(CH₃)₃ H

H 673. CD₂C(CH₃)₃ H

H 674. CD₂C(CH₃)₃ H

H 675. CD₂C(CH₃)₃ H

H 676.

H CD₂CH₃ H 677.

H CD(CH₃)₂ H 678.

H CD₂CH(CH₃)₂ H 679.

H C(CH₃)₃ H 680.

H CD₂C(CH₃)₃ H 681.

H

H 682.

H

H 683.

H

H 684.

H

H 685.

H

H 686.

H

H 687.

H CD₂CH₃ H 688.

H CD(CH₃)₂ H 689.

H CD₂CH(CH₃)₂ H 690.

H C(CH₃)₃ H 691.

H CD₂C(CH₃)₃ H 692.

H CD₂CH₂CF₃ H 693.

H CD₂C(CH₃)₂CF₃ H 694.

H

H 695.

H

H 696.

H

H 697.

H

H 698.

H

H 699.

H

H 700.

H CD₂CH₃ H 701.

H CD(CH₃)₂ H 702.

H CD₂CH(CH₃)₂ H 703.

H C(CH₃)₃ H 704.

H CD₂C(CH₃)₃ H 705.

H CD₂CH₂CF₃ H 706.

H CD₂C(CH₃)₂CF₃ H 707.

H

H 708.

H

H 709.

H

H 710.

H

H 711.

H

H 712.

H

H 713.

H CD₂CH₃ H 714.

H CD(CH₃)₂ H 715.

H CD₂CH(CH₃)₂ H 716.

H C(CH₃)₃ H 717.

H CD₂C(CH₃)₃ H 718.

H CD₂CH₂CF₃ H 719.

H CD₂C(CH₃)₂CF₃ H 720.

H

H 721.

H

H 722.

H

H 723.

H

H 724.

H

H 725.

H

H 726.

H CD₂CH₃ H 727.

H CD(CH₃)₂ H 728.

H CD₂CH(CH₃)₂ H 729.

H C(CH₃)3 H 730.

H CD₂C(CH₃)₃ H 731.

H CD₂CH₂CF₃ H 732.

H CD₂C(CH₃)₂CF₃ H 733.

H

H 734.

H

H 735.

H

H 736.

H

H 737.

H

H 738. H H H H 739. CH₃ Ph H H 740. H Ph H H 741. H Ph CH₃ H 742. CH₃ PhH CH₃ 743. CH₃ Ph CH₃ H 744. CH₃ Ph H CH₃ 745. H Ph CH₃ H 746. H Ph HCH₃ 747. H Ph CH₃ CH₃ 748. CH₃ Ph CH₃ H 749. CH₃ Ph H CH₃ 750. CH₃ PhCH₃ CH₃ 751. H Ph CH₃ CH₃ 752. CH₃ Ph CH₃ CH₃ 753. CH₂CH₃ Ph H H 754.CH₂CH₃ Ph H CH₃ 755. CH₂CH₃ Ph CH₃ H 756. CH₂CH₃ Ph H CH₃ 757. CH₂CH₃ PhCH₃ H 758. CH₂CH₃ Ph H CH₃ 759. CH₂CH₃ Ph CH₃ CH₃ 760. CH₂CH₃ Ph CH₃ CH₃761. H Ph H H 762. CH₃ Ph H CH₃ 763. H Ph CH₃ H 764. H Ph H CH₃ 765. CH₃Ph CH₃ H 766. CH₃ Ph H CH₃ 767. H Ph CH₃ CH₃ 768. CH₃ Ph CH₃ CH₃ 769. HPh CH₂CH₃ H 770. CH₃ Ph CH₂CH₃ H 771. H Ph CH₂CH₃ H 772. H Ph CH₂CH₃ CH₃773. CH₃ Ph CH₂CH₃ H 774. CH₃ Ph CH₂CH₃ CH₃ 775. H Ph CH₂CH₃ CH₃ 776.CH₃ Ph CH₂CH₃ CH₃ 777. CH(CH₃)₂ Ph H H 778. CH(CH₃)₂ Ph H CH₃ 779.CH(CH₃)₂ Ph CH₃ H 780. CH(CH₃)₂ Ph H CH₃ 781. CH(CH₃)₂ Ph CH₃ H 782.CH(CH₃)₂ Ph H CH₃ 783. CH(CH₃)₂ Ph CH₃ CH₃ 784. CH(CH₃)₂ Ph CH₃ CH₃ 785.H Ph H H 786. CH₃ Ph H CH₃ 787. H Ph CH₃ H 788. H Ph H CH₃ 789. CH₃ PhCH₃ H 790. CH₃ Ph H CH₃ 791. H Ph CH₃ CH₃ 792. CH₃ Ph CH₃ CH₃ 793. H PhCH(CH₃)₂ H 794. CH₃ Ph CH(CH₃)₂ H 795. H Ph CH(CH₃)₂ H 796. H PhCH(CH₃)₂ CH₃ 797. CH₃ Ph CH(CH₃)₂ H 798. CH₃ Ph CH(CH₃)₂ CH₃ 799. H PhCH(CH₃)₂ CH₃ 800. CH₃ Ph CH(CH₃)₂ CH₃ 801. CH₂CH(CH₃)₂ Ph H H 802.CH₂CH(CH₃)₂ Ph H CH₃ 803. CH₂CH(CH₃)₂ Ph CH₃ H 804. CH₂CH(CH₃)₂ Ph H CH₃805. CH₂CH(CH₃)₂ Ph CH₃ H 806. CH₂CH(CH₃)₂ Ph H CH₃ 807. CH₂CH(CH₃)₂ PhCH₃ CH₃ 808. CH₂CH(CH₃)₂ Ph CH₃ CH₃ 809. H Ph H H 810. CH₃ Ph H CH₃ 811.H Ph CH₃ H 812. H Ph H CH₃ 813. CH₃ Ph CH₃ H 814. CH₃ Ph H CH₃ 815. H PhCH₃ CH₃ 816. CH₃ Ph CH₃ CH₃ 817. H Ph CH₂CH(CH₃)₂ H 818. CH₃ PhCH₂CH(CH₃)₂ H 819. H Ph CH₂CH(CH₃)₂ H 820. H Ph CH₂CH(CH₃)₂ CH₃ 821. CH₃Ph CH₂CH(CH₃)₂ H 822. CH₃ Ph CH₂CH(CH₃)₂ CH₃ 823. H Ph CH₂CH(CH₃)₂ CH₃824. CH₃ Ph CH₂CH(CH₃)₂ CH₃ 825. C(CH₃)₃ Ph H H 826. C(CH₃)₃ Ph H CH₃827. C(CH₃)₃ Ph CH₃ H 828. C(CH₃)₃ Ph H CH₃ 829. C(CH₃)₃ Ph CH₃ H 830.C(CH₃)₃ Ph H CH₃ 831. C(CH₃)₃ Ph CH₃ CH₃ 832. C(CH₃)₃ Ph CH₃ CH₃ 833. HPh H H 834. CH₃ Ph H CH₃ 835. H Ph CH₃ H 836. H Ph H CH₃ 837. CH₃ Ph CH₃H 838. CH₃ Ph H CH₃ 839. H Ph CH₃ CH₃ 840. CH₃ Ph CH₃ CH₃ 841. H PhC(CH₃)₃ H 842. CH₃ Ph C(CH₃)₃ H 843. H Ph C(CH₃)₃ H 844. H Ph C(CH₃)₃CH₃ 845. CH₃ Ph C(CH₃)₃ H 846. CH₃ Ph C(CH₃)₃ CH₃ 847. H Ph C(CH₃)₃ CH₃848. CH₃ Ph C(CH₃)₃ CH₃ 849. CH₂C(CH₃)₃ Ph H H 850. CH₂C(CH₃)₃ Ph H CH₃851. CH₂C(CH₃)₃ Ph CH₃ H 852. CH₂C(CH₃)₃ Ph H CH₃ 853. CH₂C(CH₃)₃ Ph CH₃H 854. CH₂C(CH₃)₃ Ph H CH₃ 855. CH₂C(CH₃)₃ Ph CH₃ CH₃ 856. CH₂C(CH₃)₃ PhCH₃ CH₃ 857. H Ph H H 858. CH₃ Ph H CH₃ 859. H Ph CH₃ H 860. H Ph H CH₃861. CH₃ Ph CH₃ H 862. CH₃ Ph H CH₃ 863. H Ph CH₃ CH₃ 864. CH₃ Ph CH₃CH₃ 865. H Ph CH₂C(CH₃)₃ H 866. CH₃ Ph CH₂C(CH₃)₃ H 867. H Ph CH₂C(CH₃)₃H 868. H Ph CH₂C(CH₃)₃ CH₃ 869. CH₃ Ph CH₂C(CH₃)₃ H 870. CH₃ PhCH₂C(CH₃)₃ CH₃ 871. H Ph CH₂C(CH₃)₃ CH₃ 872. CH₃ Ph CH₂C(CH₃)₃ CH₃ 873.

Ph H H 874.

Ph H CH₃ 875.

Ph CH₃ H 876.

Ph H CH₃ 877.

Ph CH₃ H 878.

Ph H CH₃ 879.

Ph CH₃ CH₃ 880.

Ph CH₃ CH₃ 881. H Ph H H 882. CH₃ Ph H CH₃ 883. H Ph CH₃ H 884. H Ph HCH₃ 885. CH₃ Ph CH₃ H 886. CH₃ Ph H CH₃ 887. H Ph CH₃ CH₃ 888. CH₃ PhCH₃ CH₃ 889. H Ph

H 890. CH₃ Ph

H 891. H Ph

H 892. H Ph

CH₃ 893. CH₃ Ph

H 894. CH₃ Ph

CH₃ 895. H Ph

CH₃ 896. CH₃ Ph

CH₃ 897.

Ph H H 898.

Ph H CH₃ 899.

Ph CH₃ H 900.

Ph H CH₃ 901.

Ph CH₃ H 902.

Ph H CH₃ 903.

Ph CH₃ CH₃ 904.

Ph CH₃ CH₃ 905. H Ph H H 906. CH₃ Ph H CH₃ 907. H Ph CH₃ H 908. H Ph HCH₃ 909. CH₃ Ph CH₃ H 910. CH₃ Ph H CH₃ 911. H Ph CH₃ CH₃ 912. CH₃ PhCH₃ CH₃ 913. H Ph

H 914. CH₃ Ph

H 915. H Ph

H 916. H Ph

CH₃ 917. CH₃ Ph

H 918. CH₃ Ph

CH₃ 919. H Ph

CH₃ 920. CH₃ Ph

CH₃ 921.

Ph H H 922.

Ph H CH₃ 923.

Ph CH₃ H 924.

Ph H CH₃ 925.

Ph CH₃ H 926.

Ph H CH₃ 927.

Ph CH₃ CH₃ 928.

Ph CH₃ CH₃ 929. H Ph H H 930. CH₃ Ph H CH₃ 931. H Ph CH₃ H 932. H Ph HCH₃ 933. CH₃ Ph CH₃ H 934. CH₃ Ph H CH₃ 935. H Ph CH₃ CH₃ 936. CH₃ PhCH₃ CH₃ 937. H Ph

H 938. CH₃ Ph

H 939. H Ph

H 940. H Ph

CH₃ 941. CH₃ Ph

H 942. CH₃ Ph

CH₃ 943. H Ph

CH₃ 944. CH₃ Ph

CH₃ 945.

Ph H H 946.

Ph H CH₃ 947.

Ph CH₃ H 948.

Ph H CH₃ 949.

Ph CH₃ H 950.

Ph H CH₃ 951.

Ph CH₃ CH₃ 952.

Ph CH₃ CH₃ 953. H Ph H H 954. CH₃ Ph H CH₃ 955. H Ph CH₃ H 956. H Ph HCH₃ 957. CH₃ Ph CH₃ H 958. CH₃ Ph H CH₃ 959. H Ph CH₃ CH₃ 960. CH₃ PhCH₃ CH₃ 961. H Ph

H 962. CH₃ Ph

H 963. H Ph

H 964. H Ph

CH₃ 965. CH₃ Ph

H 966. CH₃ Ph

CH₃ 967. H Ph

CH₃ 968. CH₃ Ph

CH₃ 969.

Ph H H 970.

Ph H CH₃ 971.

Ph CH₃ H 972.

Ph H CH₃ 973.

Ph CH₃ H 974.

Ph H CH₃ 975.

Ph CH₃ CH₃ 976.

Ph CH₃ CH₃ 977. H Ph H H 978. CH₃ Ph H CH₃ 979. H Ph CH₃ H 980. H Ph HCH₃ 981. CH₃ Ph CH₃ H 982. CH₃ Ph H CH₃ 983. H Ph CH₃ CH₃ 984. CH₃ PhCH₃ CH₃ 985. H Ph

H 986. CH₃ Ph

H 987. H Ph

H 988. H Ph

CH₃ 989. CH₃ Ph

H 990. CH₃ Ph

CH₃ 991. H Ph

CH₃ 992. CH₃ Ph

CH₃ 993.

Ph H H 994.

Ph H CH₃ 995.

Ph CH₃ H 996.

Ph H CH₃ 997.

Ph CH₃ H 998.

Ph H CH₃ 999.

Ph CH₃ CH₃ 1000.

Ph CH₃ CH₃ 1001. H Ph H H 1002. CH₃ Ph H CH₃ 1003. H Ph CH₃ H 1004. H PhH CH₃ 1005. CH₃ Ph CH₃ H 1006. CH₃ Ph H CH₃ 1007. H Ph CH₃ CH₃ 1008. CH₃Ph CH₃ CH₃ 1009. H Ph

H 1010. CH₃ Ph

H 1011. H Ph

H 1012. H Ph

CH₃ 1013. CH₃ Ph

H 1014. CH₃ Ph

CH₃ 1015. H Ph

CH₃ 1016. CH₃ Ph

CH₃ 1017. CH(CH₃)₂ Ph CH₂CH₃ H 1018. CH(CH₃)₂ Ph CH(CH₃)₂ H 1019.CH(CH₃)₂ Ph CH₂CH(CH₃)₂ H 1020. CH(CH₃)₂ Ph C(CH₃)₃ H 1021. CH(CH₃)₂ PhCH₂C(CH₃)₃ H 1022. CH(CH₃)₂ Ph

H 1023. CH(CH₃)₂ Ph

H 1024. CH(CH₃)₂ Ph

H 1025. CH(CH₃)₂ Ph

H 1026. CH(CH₃)₂ Ph

H 1027. CH(CH₃)₂ Ph

H 1028. C(CH₃)₃ Ph CH₂CH₃ H 1029. C(CH₃)₃ Ph CH(CH₃)₂ H 1030. C(CH₃)₃ PhCH₂CH(CH₃)₂ H 1031. C(CH₃)₃ Ph C(CH₃)₃ H 1032. C(CH₃)₃ Ph CH₂C(CH₃)₃ H1033. C(CH₃)₃ Ph

H 1034. C(CH₃)₃ Ph

H 1035. C(CH₃)₃ Ph

H 1036. C(CH₃)₃ Ph

H 1037. C(CH₃)₃ Ph

H 1038. C(CH₃)₃ Ph

H 1039. CH₂C(CH₃)₃ Ph CH₂CH₃ H 1040. CH₂C(CH₃)₃ Ph CH(CH₃)₂ H 1041.CH₂C(CH₃)₃ Ph CH₂CH(CH₃)₂ H 1042. CH₂C(CH₃)₃ Ph C(CH₃)₃ H 1043.CH₂C(CH₃)₃ Ph CH₂C(CH₃)₃ H 1044. CH₂C(CH₃)₃ Ph

H 1045. CH₂C(CH₃)₃ Ph

H 1046. CH₂C(CH₃)₃ Ph

H 1047. CH₂C(CH₃)₃ Ph

H 1048. CH₂C(CH₃)₃ Ph

H 1049. CH₂C(CH₃)₃ Ph

H 1050.

Ph CH₂CH₃ H 1051.

Ph CH(CH₃)₂ H 1052.

Ph CH₂CH(CH₃)₂ H 1053.

Ph C(CH₃)₃ H 1054.

Ph CH₂C(CH₃)₃ H 1055.

Ph

H 1056.

Ph

H 1057.

Ph

H 1058.

Ph

H 1059.

Ph

H 1060.

Ph

H 1061.

Ph CH₂CH₃ H 1062.

Ph CH(CH₃)₂ H 1063.

Ph CH₂CH(CH₃)₂ H 1064.

Ph C(CH₃)₃ H 1065.

Ph CH₂C(CH₃)₃ H 1066.

Ph

H 1067.

Ph

H 1068.

Ph

H 1069.

Ph

H 1070.

Ph

H 1071.

Ph

H 1072.

Ph CH₂CH(CH₃)₂ H 1073.

Ph C(CH₃)₃ H 1074.

Ph CH₂C(CH₃)₃ H 1075.

Ph

H 1076.

Ph

H 1077.

Ph

H 1078.

Ph

H 1079.

Ph

H 1080.

Ph

H 1081.

Ph CH₂CH(CH₃)₂ H 1082.

Ph C(CH₃)₃ H 1083.

Ph CH₂C(CH₃)₃ 1084.

Ph

H 1085.

Ph

H 1086.

Ph

H 1087.

Ph

H 1088.

Ph

H 1089.

Ph

H 1090.

Ph CH₂CH(CH₃)₂ H 1091.

Ph C(CH₃)₃ H 1092.

Ph CH₂C(CH₃)₃ H 1093.

Ph CH₂CH₂CF₃ H 1094.

Ph CH₂C(CH₃)₂CF₃ H 1095.

Ph

H 1096.

Ph

H 1097.

Ph

H 1098.

Ph

H 1099.

Ph

H 1100.

Ph

H 1101. H Ph H H 1102. CD₃ Ph H H 1103. H Ph H H 1104. H Ph CD₃ H 1105.CD₃ Ph H CD₃ 1106. CD₃ Ph CD₃ H 1107. CD₃ Ph H CD₃ 1108. H Ph CH₃ H1109. H Ph H CD₃ 1110. H Ph CD₃ CD₃ 1111. CD₃ Ph CD₃ H 1112. CD₃ Ph HCD₃ 1113. CD₃ Ph CD₃ CD₃ 1114. H Ph CD₃ CD₃ 1115. CD₃ Ph CD₃ CD₃ 1116.CD₂CH₃ Ph H H 1117. CD₂CH₃ Ph H CD₃ 1118. CD₂CH₃ Ph CD₃ H 1119. CD₂CH₃Ph H CD₃ 1120. CD₂CH₃ Ph CD₃ H 1121. CD₂CH₃ Ph H CD₃ 1122. CD₂CH₃ Ph CD₃CD₃ 1123. CD₂CH₃ Ph CD₃ CD₃ 1124. H Ph H H 1125. CH₃ Ph H CD₃ 1126. H PhCD₃ H 1127. H Ph H CD₃ 1128. CD₃ Ph CD₃ H 1129. CD₃ Ph H CD₃ 1130. H PhCD₃ CD₃ 1131. CD₃ Ph CD₃ CD₃ 1132. H Ph CD₂CH₃ H 1133. CD₃ Ph CD₂CH₃ H1134. H Ph CD₂CH₃ H 1135. H Ph CD₂CH₃ CD₃ 1136. CD₃ Ph CD₂CH₃ H 1137.CD₃ Ph CD₂CH₃ CD₃ 1138. H Ph CD₂CH₃ CD₃ 1139. CD₃ Ph CD₂CH₃ CD₃ 1140.CD(CH₃)₂ Ph H H 1141. CD(CH₃)₂ Ph H CD₃ 1142. CD(CH₃)₂ Ph CD₃ H 1143.CD(CH₃)₂ Ph H CD₃ 1144. CD(CH₃)₂ Ph CD₃ H 1145. CD(CH₃)₂ Ph H CD₃ 1146.CD(CH₃)₂ Ph CD₃ CD₃ 1147. CD(CH₃)₂ Ph CD₃ CD₃ 1148. H Ph H H 1149. CD₃Ph H CD₃ 1150. H Ph CD₃ H 1151. H Ph H CD₃ 1152. CD₃ Ph CD₃ H 1153. CD₃Ph H CD₃ 1154. H Ph CD₃ CD₃ 1155. CD₃ Ph CD₃ CD₃ 1156. H Ph CD(CH₃)₂ H1157. CD₃ Ph CD(CH₃)₂ H 1158. H Ph CD(CH₃)₂ H 1159. H Ph CD(CH₃)₂ CD₃1160. CD₃ Ph CD(CH₃)₂ H 1161. CD₃ Ph CD(CH₃)₂ CD₃ 1162. H Ph CD(CH₃)₂CD₃ 1163. CD₃ Ph CD(CH₃)₂ CD₃ 1164. CD(CD₃)₂ Ph H H 1165. CD(CD₃)₂ Ph HCD₃ 1166. CD(CD₃)₂ Ph CD₃ H 1167. CD(CD₃)₂ Ph H CD₃ 1168. CD(CD₃)₂ PhCD₃ H 1169. CD(CD₃)₂ Ph H CD₃ 1170. CD(CD₃)₂ Ph CD₃ CD₃ 1171. CD(CD₃)₂Ph CD₃ CD₃ 1172. H Ph H H 1173. CH₃ Ph H CD₃ 1174. H Ph CD₃ H 1175. H PhH CD₃ 1176. CD₃ Ph CD₃ H 1177. CD₃ Ph H CD₃ 1178. H Ph CD₃ CD₃ 1179. CD₃Ph CD₃ CD₃ 1180. H Ph CD(CD₃)₂ H 1181. CD₃ Ph CD(CD₃)₂ H 1182. H PhCD(CD₃)₂ H 1183. H Ph CD(CD₃)₂ CD₃ 1184. CD₃ Ph CD(CD₃)₂ H 1185. CD₃ PhCD(CD₃)₂ CD₃ 1186. H Ph CD(CD₃)₂ CD₃ 1187. CD₃ Ph CD(CD₃)₂ CD₃ 1188.CD₂CH(CH₃)₂ Ph H H 1189. CD₂CH(CH₃)₂ Ph H CD₃ 1190. CD₂CH(CH₃)₂ Ph CD₃ H1191. CD₂CH(CH₃)₂ Ph H CD₃ 1192. CD₂CH(CH₃)₂ Ph CD₃ H 1193. CD₂CH(CH₃)₂Ph H CD₃ 1194. CD₂CH(CH₃)₂ Ph C3 CD₃ 1195. CD₂CH(CH₃)₂ Ph CD₃ CD₃ 1196.H Ph H H 1197. CD₃ Ph H CD₃ 1198. H Ph CD₃ H 1199. H Ph H CD₃ 1200. CD₃Ph CD₃ H 1201. CD₃ Ph H CD₃ 1202. H Ph CD₃ CD₃ 1203. CD₃ Ph CD₃ CD₃1204. H Ph CD₂CH(CH₃)₂ H 1205. CD₃ Ph CD₂CH(CH₃)₂ H 1206. H PhCD₂CH(CH₃)₂ H 1207. H Ph CD₂CH(CH₃)₂ CD₃ 1208. CD₃ Ph CD₂CH(CH₃)₂ H1209. CD₃ Ph CD₂CH(CH₃)₂ CD₃ 1210. H Ph CD₂CH(CH₃)₂ CD₃ 1211. CD₃ PhCD₂CH(CH₃)₂ CD₃ 1212. CD₂C(CH₃)₃ Ph H H 1213. CD₂C(CH₃)₃ Ph H CD₃ 1214.CD₂C(CH₃)₃ Ph CD₃ H 1215. CD₂C(CH₃)₃ Ph H CD₃ 1216. CD₂C(CH₃)₃ Ph CD₃ H1217. CD₂C(CH₃)₃ Ph H CD₃ 1218. CD₂C(CH₃)₃ Ph CD₃ CD₃ 1219. CD₂C(CH₃)₃Ph CD₃ CD₃ 1220. H Ph H H 1221. CD₃ Ph H CD₃ 1222. H Ph C3 H 1223. H PhH CD₃ 1224. CD₃ Ph CD₃ H 1225. CD₃ Ph H CD₃ 1226. H Ph CD₃ CD₃ 1227. CD₃Ph CD₃ CD₃ 1228. H Ph CD₂C(CH₃)₃ H 1229. CD₃ Ph CD₂C(CH₃)₃ H 1230. H PhCD₂C(CH₃)₃ H 1231. H Ph CD₂C(CH₃)₃ CD₃ 1232. CD₃ Ph CD₂C(CH₃)₃ H 1233.CD₃ Ph CD₂C(CH₃)₃ CD₃ 1234. H Ph CD₂C(CH₃)₃ CD₃ 1235. CD₃ Ph CD₂C(CH₃)₃CD₃ 1236.

Ph H H 1237.

Ph H CD₃ 1238.

Ph CD₃ H 1239.

Ph H CD₃ 1240.

Ph CD₃ H 1241.

Ph H CD₃ 1242.

Ph CD₃ CD₃ 1243.

Ph CD₃ CD₃ 1244. H Ph H H 1245. CD₃ Ph H CD₃ 1246. H Ph CD₃ H 1247. H PhH CD₃ 1248. CD₃ Ph CD₃ H 1249. CD₃ Ph H CD₃ 1250. H Ph CD₃ CD₃ 1251. CD₃Ph CD₃ CD₃ 1252. H Ph

H 1253. CD₃ Ph

H 1254. H Ph

H 1255. H Ph

CD₃ 1256. CD₃ Ph

H 1257. CD₃ Ph

CD₃ 1258. H Ph

CD₃ 1259. CD₃ Ph

CD₃ 1260.

Ph H H 1261.

Ph H CD₃ 1262.

Ph CD₃ H 1263.

Ph H CD₃ 1264.

Ph CD₃ H 1265.

Ph H CD₃ 1266.

Ph CD₃ CD₃ 1267.

Ph CD₃ CD₃ 1268. H Ph H H 1269. CH₃ Ph H CD₃ 1270. H Ph CD₃ H 1271. H PhH CD₃ 1272. CD₃ Ph CD₃ H 1273. CD₃ Ph H CD₃ 1274. H Ph CD₃ CD₃ 1275. CH₃Ph CD₃ CD₃ 1276. H Ph

H 1277. CD₃ Ph

H 1278. H Ph

H 1279. H Ph

CD₃ 1280. CD₃ Ph

H 1281. CD₃ Ph

CD₃ 1282. H Ph

CD₃ 1283. CD₃ Ph

CD₃ 1284.

Ph H H 1285.

Ph H CD₃ 1286.

Ph CD₃ H 1287.

Ph H CD₃ 1288.

Ph CD₃ H 1289.

Ph H CD₃ 1290.

Ph CD₃ CD₃ 1291.

Ph CD₃ CD₃ 1292. H Ph H H 1293. CD₃ Ph H CD₃ 1294. H Ph CD₃ H 1295. H PhH CD₃ 1296. CD₃ Ph CD₃ H 1297. CD₃ Ph H CD₃ 1298. H Ph CD₃ CD₃ 1299. CD₃Ph CD₃ CD₃ 1300. H Ph

H 1301. CD₃ Ph

H 1302. H Ph

H 1303. H Ph

CD₃ 1304. CD₃ Ph

H 1305. CD₃ Ph

CD₃ 1306. H Ph

CD₃ 1307. CD₃ Ph

CD₃ 1308.

Ph H H 1309.

Ph H CD₃ 1310.

Ph CD₃ H 1311.

Ph H CD₃ 1312.

Ph CD₃ H 1313.

Ph H CD₃ 1314.

Ph CD₃ CD₃ 1315.

Ph CD₃ CD₃ 1316. H Ph H H 1317. CD₃ Ph H CD₃ 1318. H Ph CD₃ H 1319. H PhH CD₃ 1320. CD₃ Ph CD₃ H 1321. CD₃ Ph H CD₃ 1322. H Ph CD₃ CD₃ 1323. CD₃Ph CD₃ CD₃ 1324. H Ph

H 1325. CD₃ Ph

H 1326. H Ph

H 1327. H Ph

CD₃ 1328. CD₃ Ph

H 1329. CD₃ Ph

CD₃ 1330. H Ph

CD₃ 1331. CD₃ Ph

CD₃ 1332.

Ph H H 1333.

Ph H CD₃ 1334.

Ph CD₃ H 1335.

Ph H CD₃ 1336.

Ph CD₃ H 1337.

Ph H CD₃ 1338.

Ph CD₃ CD₃ 1339.

Ph CD₃ CD₃ 1340. H Ph H H 1341. CD₃ Ph H CD₃ 1342. H Ph CD₃ H 1343. H PhH CD₃ 1344. CD₃ Ph CD₃ H 1345. CD₃ Ph H CD₃ 1346. H Ph CD₃ CD₃ 1347. CD₃Ph CD₃ CD₃ 1348. H Ph

H 1349. CD₃ Ph

H 1350. H Ph

H 1351. H Ph

CD₃ 1352. CD₃ Ph

H 1353. CD₃ Ph

CD₃ 1354. H Ph

CD₃ 1355. CD₃ Ph

CD₃ 1356.

Ph H H 1357.

Ph H CD₃ 1358.

Ph CD₃ H 1359.

Ph H CD₃ 1360.

Ph CH₃ H 1361.

Ph H CD₃ 1362.

Ph CD₃ CD₃ 1363.

Ph CD₃ CD₃ 1364. H Ph H H 1365. CD₃ Ph H CD₃ 1366. H Ph CD₃ H 1367. H PhH CD₃ 1368. CD₃ Ph CD₃ H 1369. CD₃ Ph H CD₃ 1370. H Ph CD₃ CD₃ 1371. CD₃Ph CD₃ CD₃ 1372. H Ph

H 1373. CD₃ Ph

H 1374. H Ph

H 1375. H Ph

CH₃ 1376. CD₃ Ph

H 1377. CD₃ Ph

CD₃ 1378. H Ph

CD₃ 1379. CD₃ Ph

CD₃ 1380. CD(CH₃)₂ Ph CD₂CH₃ H 1381. CD(CH₃)₂ Ph CD(CH₃)₂ H 1382.CD(CH₃)₂ Ph CD₂CH(CH₃)₂ H 1383. CD(CH₃)₂ Ph C(CH₃)₃ H 1384. CD(CH₃)₂ PhCD₂C(CH₃)₃ H 1385. CD(CH₃)₂ Ph CD₂CH₂CF₃ H 1386. CD(CH₃)₂ PhCD₂C(CH₃)₂CF₃ H 1387. CD(CH₃)₂ Ph

H 1388. C(CH₃)₂ Ph

H 1389. CD(CH₃)₂ Ph

H 1390. CD(CH₃)₂ Ph

H 1391. CD(CH₃)₂ Ph

H 1392. CD(CH₃)₂ Ph

H 1393. C(CH₃)₃ Ph CD₂CH₃ H 1394. C(CH₃)₃ Ph CD(CH₃)₂ H 1395. C(CH₃)₃ PhCD₂CH(CH₃)₂ H 1396. C(CH₃)₃ Ph C(CH₃)₃ H 1397. C(CH₃)₃ Ph CD₂C(CH₃)₃ H1398. C(CH₃)₃ Ph

H 1399. C(CH₃)₃ Ph

1400. C(CH₃)₃ Ph

H 1401. C(CH₃)₃ Ph

H 1402. C(CH₃)₃ Ph

H 1403. C(CH₃)₃ Ph

H 1404. CD₂C(CH₃)₃ Ph CD₂CH₃ H 1405. CD₂C(CH₃)₃ Ph CD(CH₃)₂ H 1406.CD₂C(CH₃)₃ Ph CD₂CH(CH₃)₂ H 1407. CD₂C(CH₃)₃ Ph C(CH₃)₃ H 1408.CD₂C(CH₃)₃ Ph CD₂C(CH₃)₃ H 1409. CD₂C(CH₃)₃ Ph CD₂CH₂CF₃ H 1410.CD₂C(CH₃)₃ Ph CD₂C(CH₃)₂CF₃ H 1411. CD₂C(CH₃)₃ Ph

H 1412. CD₂C(CH₃)₃ Ph

H 1413. CD₂C(CH₃)₃ Ph

H 1414. CD₂C(CH₃)₃ Ph

H 1415. CD₂C(CH₃)₃ Ph

H 1416. CD₂C(CH₃)₃ Ph

H 1417.

Ph CD₂CH₃ H 1418.

Ph CD(CH₃)₂ H 1419.

Ph CD₂CH(CH₃)₂ H 1420.

Ph C(CH₃)₃ H 1421.

Ph CD₂C(CH₃)₃ H 1422.

Ph

H 1423.

Ph

H 1424.

Ph

H 1425.

Ph

H 1426.

Ph

H 1427.

Ph

H 1428.

Ph CD₂CH₃ H 1429.

Ph CD(CH₃)₂ H 1430.

Ph CD₂CH(CH₃)₂ H 1431.

Ph C(CH₃)₃ H 1432.

Ph CD₂C(CH₃)₃ H 1433.

Ph

H 1434.

Ph

H 1435.

Ph

H 1436.

Ph

H 1437.

Ph

H 1438.

Ph

H 1439.

Ph CD₂CH₃ H 1440.

Ph CD(CH₃)₂ H 1441.

Ph CD₂CH(CH₃)₂ H 1442.

Ph C(CH₃)₃ H 1443.

Ph CD₂C(CH₃)₃ H 1444.

Ph

H 1445.

Ph

H 1446.

Ph

H 1447.

Ph

H 1448.

Ph

H 1449.

Ph

H 1450.

Ph CD₂CH₃ H 1451.

Ph CD(CH₃)₂ H 1452.

Ph CD₂CH(CH₃)₂ H 1453.

Ph C(CH₃)₃ H 1454.

Ph CD₂C(CH₃)₃ H 1455.

Ph

H 1456.

Ph

H 1457.

Ph

H 1458.

Ph

H 1459.

Ph

H 1460.

Ph

H 1461.

Ph CD₂CH₃ H 1462.

Ph CD(CH₃)₂ H 1463.

Ph CD₂CH(CH₃)₂ H 1464.

Ph C(CH₃)₃ H 1465.

Ph CD₂C(CH₃)₃ H 1466.

Ph

H 1467.

Ph

H 1468.

Ph

H 1469.

Ph

H 1470.

Ph

H 1471.

Ph

H

In the embodiments of the compound where L_(B) is one of L_(B1) toL_(B1471) defined above, the compound is selected from the groupconsisting of Compound A-x having the formula Ir(L_(Ai))(L_(Bj))₂ orCompound B-x having the formula Ir(L_(Ai))₂(L_(Bj)); wherein x is aninteger defined by x=1471i+j−1471, wherein i is an integer from 1 to371, j is an integer from 1 to 1471, and wherein L_(A1) to L_(A371) havethe following formula:

wherein R, R¹, R², R³, R⁴, R⁵, and R⁶ are defined as provided below:

L_(Ai), where i is R¹ R R^(A) R^(B) R^(C) R^(D) R^(E) 1. H R^(A1 ) H H HH H 2. H R^(A2 ) H H H H H 3. H R^(A3 ) H H H H H 4. H R^(A4 ) H H H H H5. H R^(A5 ) H H H H H 6. H R^(A6 ) H H H H H 7. H R^(A7 ) H H H H H 8.H R^(A8 ) H H H H H 9. H R^(A9 ) H H H H H 10. H R^(A10) H H H H H 11. HR^(A11) H H H H H 12. H R^(A12) H H H H H 13. H R^(A13) H H H H H 14. HR^(A14) H H H H H 15. H R^(A15) H H H H H 16. H R^(A16) H H H H H 17. HR^(A17) H H H H H 18. H R^(A18) H H H H H 19. H R^(A19) H H H H H 20. HR^(A20) H H H H H 21. H R^(A21) H H H H H 22. H R^(A22) H H H H H 23. HR^(A23) H H H H H 24. H R^(A24) H H H H H 25. H R^(A25) H H H H H 26. HR^(A26) H H H H H 27. H R^(A27) H H H H H 28. H R^(A28) H H H H H 29. HR^(A29) H H H H H 30. H R^(A30) H H H H H 31. H R^(A31) H H H H H 32. HR^(A32) H H H H H 33. H R^(A33) H H H H H 34. H R^(A34) H H H H H 35. HR^(A35) H H H H H 36. H R^(A36) H H H H H 37. H R^(A37) H H H H H 38. HR^(A38) H H H H H 39. H R^(A39) H H H H H 40. H R^(A40) H H H H H 41. HR^(A41) H H H H H 42. H R^(A42) H H H H H 43. H R^(A43) H H H H H 44. HR^(A44) H H H H H 45. H R^(A45) H H H H H 46. H R^(A46) H H H H H 47. HR^(A47) H H H H H 48. H R^(A48) H H H H H 49. H R^(A49) H H H H H 50. HR^(A50) H H H H H 51. H R^(A51) H H H H H 52. H R^(A52) H H H H H 53. HR^(A53) H H H H H 54. H R^(A54) H H H H H 55. H R^(A55) H H H H H 56. HR^(A56) H H H H H 57. H R^(A57) H H H H H 58. H R^(A58) H H H H H 59. HR^(A59) H H H H H 60. H R^(A60) H H H H H 61. H R^(A61) H H H H H 62. HR^(A62) H H H H H 63. H R^(A63) H H H H H 64. H R^(A64) H H H H H 65. HR^(A65) H H H H H 66. H R^(A66) H H H H H 67. H R^(A67) H H H H H 68. HR^(A68) H H H H H 69. H R^(A69) H H H H H 70. H R^(A70) H H H H H 71. HR^(A71) H H H H H 72. H R^(A72) H H H H H 73. H R^(A73) H H H H H 74. HR^(A74) H H H H H 75. H R^(A75) H H H H H 76. H R^(A76) H H H H H 77. HR^(A77) H H H H H 78. H R^(A78) H H H H H 79. H R^(A79) H H H H H 80. HR^(A80) H H H H H 81. H R^(A81) H H H H H 82. H R^(A82) H H H H H 83. HR^(A83) H H H H H 84. H R^(A84) H H H H H 85. H R^(A85) H H H H H 86. HR^(A86) H H H H H 87. H R^(A87) H H H H H 88. H R^(A88) H H H H H 89. HR^(A89) H H H H H 90. H R^(A90) H H H H H 91. H R^(A91) H H H H H 92. HR^(A92) H H H H H 93. H R^(A93) H H H H H 94. CD₃ R^(A1 ) H H H H H 95.CD₃ R^(A2 ) H H H H H 96. CD₃ R^(A3 ) H H H H H 97. CD₃ R^(A4 ) H H H HH 98. CD₃ R^(A5 ) H H H H H 99. CD₃ R^(A6 ) H H H H H 100. CD₃ R^(A7 ) HH H H H 101. CD₃ R^(A8 ) H H H H H 102. CD₃ R^(A9 ) H H H H H 103. CD₃R^(A10) H H H H H 104. CD₃ R^(A11) H H H H H 105. CD₃ R^(A12) H H H H H106. CD₃ R^(A13) H H H H H 107. CD₃ R^(A14) H H H H H 108. CD₃ R^(A15) HH H H H 109. CD₃ R^(A16) H H H H H 110. CD₃ R^(A17) H H H H H 111. CD₃R^(A18) H H H H H 112. CD₃ R^(A19) H H H H H 113. CD₃ R^(A20) H H H H H114. CD₃ R^(A21) H H H H H 115. CD₃ R^(A22) H H H H H 116. CD₃ R^(A23) HH H H H 117. CD₃ R^(A24) H H H H H 118. CD₃ R^(A25) H H H H H 119. CD₃R^(A26) H H H H H 120. CD₃ R^(A27) H H H H H 121. CD₃ R^(A28) H H H H H122. CD₃ R^(A29) H H H H H 123. CD₃ R^(A30) H H H H H 124. CD₃ R^(A31) HH H H H 125. CD₃ R^(A32) H H H H H 126. CD₃ R^(A33) H H H H H 127. CD₃R^(A34) H H H H H 128. CD₃ R^(A35) H H H H H 129. CD₃ R^(A36) H H H H H130. CD₃ R^(A37) H H H H H 131. CD₃ R^(A38) H H H H H 132. CD₃ R^(A39) HH H H H 133. CD₃ R^(A40) H H H H H 134. CD₃ R^(A41) H H H H H 135. CD₃R^(A42) H H H H H 136. CD₃ R^(A43) H H H H H 137. CD₃ R^(A44) H H H H H138. CD₃ R^(A45) H H H H H 139. CD₃ R^(A46) H H H H H 140. CD₃ R^(A47) HH H H H 141. CD₃ R^(A48) H H H H H 142. CD₃ R^(A49) H H H H H 143. CD₃R^(A50) H H H H H 144. CD₃ R^(A51) H H H H H 145. CD₃ R^(A52) H H H H H146. CD₃ R^(A53) H H H H H 147. CD₃ R^(A54) H H H H H 148. CD₃ R^(A55) HH H H H 149. CD₃ R^(A56) H H H H H 150. CD₃ R^(A57) H H H H H 151. CD₃R^(A58) H H H H H 152. CD₃ R^(A59) H H H H H 153. CD₃ R^(A60) H H H H H154. CD₃ R^(A61) H H H H H 155. CD₃ R^(A62) H H H H H 156. CD₃ R^(A63) HH H H H 157. CD₃ R^(A64) H H H H H 158. CD₃ R^(A65) H H H H H 159. CD₃R^(A66) H H H H H 160. CD₃ R^(A67) H H H H H 161. CD₃ R^(A68) H H H H H162. CD₃ R^(A69) H H H H H 163. CD₃ R^(A70) H H H H H 164. CD₃ R^(A71) HH H H H 165. CD₃ R^(A72) H H H H H 166. CD₃ R^(A73) H H H H H 167. CD₃R^(A74) H H H H H 168. CD₃ R^(A75) H H H H H 169. CD₃ R^(A76) H H H H H170. CD₃ R^(A77) H H H H H 171. CD₃ R^(A78) H H H H H 172. CD₃ R^(A79) HH H H H 173. CD₃ R^(A80) H H H H H 174. CD₃ R^(A81) H H H H H 175. CD₃R^(A82) H H H H H 176. CD₃ R^(A83) H H H H H 177. CD₃ R^(A84) H H H H H178. CD₃ R^(A85) H H H H H 179. CD₃ R^(A86) H H H H H 180. CD₃ R^(A87) HH H H H 181. CD₃ R^(A88) H H H H H 182. CD₃ R^(A89) H H H H H 183. CD₃R^(A90) H H H H H 184. CD₃ R^(A91) H H H H H 185. CD₃ R^(A92) H H H H H186. CD₃ R^(A93) H H H H H 187. H R^(A1 ) H CD₃ H H H 188. H R^(A2 ) HCD₃ H H H 189. H R^(A3 ) H CD₃ H H H 190. H R^(A4 ) H CD₃ H H H 191. HR^(A5 ) H CD₃ H H H 192. H R^(A6 ) H CD₃ H H H 193. H R^(A7 ) H CD₃ H HH 194. H R^(A8 ) H CD₃ H H H 195. H R^(A10) H CD₃ H H H 196. H R^(A11) HCD₃ H H H 197. H R^(A12) H CD₃ H H H 198. H R^(A13) H CD₃ H H H 199. HR^(A14) H CD₃ H H H 200. H R^(A15) H CD₃ H H H 201. H R^(A16) H CD₃ H HH 202. H R^(A17) H CD₃ H H H 203. H R^(A18) H CD₃ H H H 204. H R^(A19) HCD₃ H H H 205. H R^(A20) H CD₃ H H H 206. H R^(A21) H CD₃ H H H 207. HR^(A22) H CD₃ H H H 208. H R^(A23) H CD₃ H H H 209. H R^(A24) H CD₃ H HH 210. H R^(A25) H CD₃ H H H 211. H R^(A26) H CD₃ H H H 212. H R^(A27) HCD₃ H H H 213. H R^(A28) H CD₃ H H H 214. H R^(A29) H CD₃ H H H 215. HR^(A30) H CD₃ H H H 216. H R^(A31) H CD₃ H H H 217. H R^(A32) H CD₃ H HH 218. H R^(A33) H CD₃ H H H 219. H R^(A34) H CD₃ H H H 220. H R^(A35) HCD₃ H H H 221. H R^(A36) H CD₃ H H H 222. H R^(A37) H CD₃ H H H 223. HR^(A38) H CD₃ H H H 224. H R^(A39) H CD₃ H H H 225. H R^(A40) H CD₃ H HH 226. H R^(A41) H CD₃ H H H 227. H R^(A42) H CD₃ H H H 228. H R^(A43) HCD₃ H H H 229. H R^(A44) H CD₃ H H H 230. H R^(A45) H CD₃ H H H 231. HR^(A46) H CD₃ H H H 232. H R^(A47) H CD₃ H H H 233. H R^(A48) H CD₃ H HH 234. H R^(A49) H CD₃ H H H 235. H R^(A50) H CD₃ H H H 236. H R^(A51) HCD₃ H H H 237. H R^(A52) H CD₃ H H H 238. H R^(A53) H CD₃ H H H 239. HR^(A54) H CD₃ H H H 240. H R^(A55) H CD₃ H H H 241. H R^(A56) H CD₃ H HH 242. H R^(A57) H CD₃ H H H 243. H R^(A58) H CD₃ H H H 244. H R^(A59) HCD₃ H H H 245. H R^(A60) H CD₃ H H H 246. H R^(A61) H CD₃ H H H 247. HR^(A62) H CD₃ H H H 248. H R^(A63) H CD₃ H H H 249. H R^(A64) H CD₃ H HH 250. H R^(A65) H CD₃ H H H 251. H R^(A66) H CD₃ H H H 252. H R^(A67) HCD₃ H H H 253. H R^(A68) H CD₃ H H H 254. H R^(A69) H CD₃ H H H 255. HR^(A70) H CD₃ H H H 256. H R^(A71) H CD₃ H H H 257. H R^(A72) H CD₃ H HH 258. H R^(A73) H CD₃ H H H 259. H R^(A74) H CD₃ H H H 260. H R^(A75) HCD₃ H H H 261. H R^(A76) H CD₃ H H H 262. H R^(A77) H CD₃ H H H 263. HR^(A78) H CD₃ H H H 264. H R^(A79) H CD₃ H H H 265. H R^(A80) H CD₃ H HH 266. H R^(A81) H CD₃ H H H 267. H R^(A82) H CD₃ H H H 268. H R^(A83) HCD₃ H H H 269. H R^(A84) H CD₃ H H H 270. H R^(A85) H CD₃ H H H 271. HR^(A86) H CD₃ H H H 272. H R^(A87) H CD₃ H H H 273. H R^(A88) H CD₃ H HH 274. H R^(A89) H CD₃ H H H 275. H R^(A90) H CD₃ H H H 276. H R^(A91) HCD₃ H H H 277. H R^(A92) H CD₃ H H H 278. H R^(A93) H CD₃ H H H 279. CD₃R^(A1 ) H CD₃ H H H 280. CD₃ R^(A2 ) H CD₃ H H H 281. CD₃ R^(A3 ) H CD₃H H H 282. CD₃ R^(A4 ) H CD₃ H H H 283. CD₃ R^(A5 ) H CD₃ H H H 284. CD₃R^(A6 ) H CD₃ H H H 285. CD₃ R^(A7 ) H CD₃ H H H 286. CD₃ R^(A8 ) H CD₃H H H 287. CD₃ R^(A9 ) H CD₃ H H H 288. CD₃ R^(A10) H CD₃ H H H 289. CD₃R^(A11) H CD₃ H H H 290. CD₃ R^(A12) H CD₃ H H H 291. CD₃ R^(A13) H CD₃H H H 292. CD₃ R^(A14) H CD₃ H H H 293. CD₃ R^(A15) H CD₃ H H H 294. CD₃R^(A16) H CD₃ H H H 295. CD₃ R^(A17) H CD₃ H H H 296. CD₃ R^(A18) H CD₃H H H 297. CD₃ R^(A19) H CD₃ H H H 298. CD₃ R^(A20) H CD₃ H H H 299. CD₃R^(A21) H CD₃ H H H 300. CD₃ R^(A22) H CD₃ H H H 301. CD₃ R^(A23) H CD₃H H H 302. CD₃ R^(A24) H CD₃ H H H 303. CD₃ R^(A25) H CD₃ H H H 304. CD₃R^(A26) H CD₃ H H H 305. CD₃ R^(A27) H CD₃ H H H 306. CD₃ R^(A28) H CD₃H H H 307. CD₃ R^(A29) H CD₃ H H H 308. CD₃ R^(A30) H CD₃ H H H 309. CD₃R^(A31) H CD₃ H H H 310. CD₃ R^(A32) H CD₃ H H H 311. CD₃ R^(A33) H CD₃H H H 312. CD₃ R^(A34) H CD₃ H H H 313. CD₃ R^(A35) H CD₃ H H H 314. CD₃R^(A36) H CD₃ H H H 315. CD₃ R^(A37) H CD₃ H H H 316. CD₃ R^(A38) H CD₃H H H 317. CD₃ R^(A39) H CD₃ H H H 318. CD₃ R^(A40) H CD₃ H H H 319. CD₃R^(A41) H CD₃ H H H 320. CD₃ R^(A42) H CD₃ H H H 321. CD₃ R^(A43) H CD₃H H H 322. CD₃ R^(A44) H CD₃ H H H 323. CD₃ R^(A45) H CD₃ H H H 324. CD₃R^(A46) H CD₃ H H H 325. CD₃ R^(A47) H CD₃ H H H 326. CD₃ R^(A48) H CD₃H H H 327. CD₃ R^(A49) H CD₃ H H H 328. CD₃ R^(A50) H CD₃ H H H 329. CD₃R^(A51) H CD₃ H H H 330. CD₃ R^(A52) H CD₃ H H H 331. CD₃ R^(A53) H CD₃H H H 332. CD₃ R^(A54) H CD₃ H H H 333. CD₃ R^(A55) H CD₃ H H H 334. CD₃R^(A56) H CD₃ H H H 335. CD₃ R^(A57) H CD₃ H H H 336. CD₃ R^(A58) H CD₃H H H 337. CD₃ R^(A59) H CD₃ H H H 338. CD₃ R^(A60) H CD₃ H H H 339. CD₃R^(A61) H CD₃ H H H 340. CD₃ R^(A62) H CD₃ H H H 341. CD₃ R^(A63) H CD₃H H H 342. CD₃ R^(A64) H CD₃ H H H 343. CD₃ R^(A65) H CD₃ H H H 344. CD₃R^(A66) H CD₃ H H H 345. CD₃ R^(A67) H CD₃ H H H 346. CD₃ R^(A68) H CD₃H H H 347. CD₃ R^(A69) H CD₃ H H H 348. CD₃ R^(A70) H CD₃ H H H 349. CD₃R^(A71) H CD₃ H H H 350. CD₃ R^(A72) H CD₃ H H H 351. CD₃ R^(A73) H CD₃H H H 352. CD₃ R^(A74) H CD₃ H H H 353. CD₃ R^(A75) H CD₃ H H H 354. CD₃R^(A76) H CD₃ H H H 355. CD₃ R^(A77) H CD₃ H H H 356. CD₃ R^(A78) H CD₃H H H 357. CD₃ R^(A79) H CD₃ H H H 358. CD₃ R^(A80) H CD₃ H H H 359. CD₃R^(A81) H CD₃ H H H 360. CD₃ R^(A82) H CD₃ H H H 361. CD₃ R^(A83) H CD₃H H H 362. CD₃ R^(A84) H CD₃ H H H 363. CD₃ R^(A85) H CD₃ H H H 364. CD₃R^(A86) H CD₃ H H H 365. CD₃ R^(A87) H CD₃ H H H 366. CD₃ R^(A88) H CD₃H H H 367. CD₃ R^(A89) H CD₃ H H H 368. CD₃ R^(A90) H CD₃ H H H 369. CD₃R^(A91) H CD₃ H H H 370. CD₃ R^(A92) H CD₃ H H H 371. CD₃ R^(A93) H CD₃H H H

An OLED is also disclosed, where the OLED comprises: an anode; acathode; and an organic layer, disposed between the anode and thecathode, comprising a compound having the formula:

In Formula I, R¹, R², R³, R⁴, and R⁵ each independently represents mono,to a maximum possible number of substitutions, or no substitution. X isselected from the group consisting of BR′, NR′, PR′, O, S, Se, C═O, S═O,SO₂, CR′R″, SiR′R″, and GeR′R″. Each of R′, R″, R¹, R², R³, R⁴, and R⁵is independently selected from the group consisting of hydrogen,deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy,aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl,aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile,isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinationsthereof. Any substitutions are optionally joined or fused into a ring. nis 1 or 2. R is selected from the group consisting of alkyl, cycloalkyl,heteroalkyl, heterocycloalkyl, partially or fully fluorinated variantsthereof, partially or fully deuterated variants thereof, and combinationthereof. R has at least five carbon atoms.

In some embodiments of the OLED, each of R′, R″, R¹, R², R³, R⁴, and R⁵is independently selected from the group consisting of hydrogen,deuterium, fluorine, alkyl, cycloalkyl, heteroalkyl, alkoxy, aryloxy,amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, aryl, heteroaryl,nitrile, isonitrile, and combinations thereof.

In some embodiments of the OLED, the organic layer further comprises ahost, wherein host comprises at least one chemical group selected fromthe group consisting of triphenylene, carbazole, dibenzothiphene,dibenzofuran, dibenzoselenophene, azatriphenylene, azacarbazole,aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene.

In some embodiments of the OLED, R in the compound has at least sixcarbon atoms. In some embodiments, R has at least seven carbon atoms.

A consumer product comprising the OLED is also disclosed. where the OLEDcomprises: an anode; a cathode; and an organic layer, disposed betweenthe anode and the cathode, comprising a compound having the formula:

In Formula I, R¹, R², R³, R⁴, and R⁵ each independently represents mono,to a maximum possible number of substitutions, or no substitution. X isselected from the group consisting of BR′, NR′, PR′, O, S, Se, C═O, S═O,SO₂, CR′R″, SiR′R″, and GeR′R″. R′, R″, R¹, R², R³, R⁴, and R⁵ areindependently selected from the group consisting of hydrogen, deuterium,halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy,amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl,heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile,isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinationsthereof. Any substitutions are optionally joined or fused into a ring. nis 1 or 2. R is selected from the group consisting of alkyl, cycloalkyl,heteroalkyl, heterocycloalkyl, partially or fully fluorinated variantsthereof, partially or fully deuterated variants thereof, and combinationthereof. R has at least five carbon atoms.

In some embodiments, the OLED has one or more characteristics selectedfrom the group consisting of being flexible, being rollable, beingfoldable, being stretchable, and being curved. In some embodiments, theOLED is transparent or semi-transparent. In some embodiments, the OLEDfurther comprises a layer comprising carbon nanotubes.

In some embodiments, the OLED further comprises a layer comprising adelayed fluorescent emitter. In some embodiments, the OLED comprises aRGB pixel arrangement or white plus color filter pixel arrangement. Insome embodiments, the OLED is a mobile device, a hand held device, or awearable device. In some embodiments, the OLED is a display panel havingless than 10 inch diagonal or 50 square inch area. In some embodiments,the OLED is a display panel having at least 10 inch diagonal or 50square inch area. In some embodiments, the OLED is a lighting panel.

An emissive region in an organic light emitting device, the emissiveregion comprising a compound having the formula:

In Formula I, R¹, R², R³, R⁴, and R⁵ each independently represents mono,to a maximum possible number of substitutions, or no substitution. X isselected from the group consisting of BR′, NR′, PR′, O, S, Se, C═O, S═O,SO₂, CR′R″, SiR′R″, and GeR′R″. R′, R″, R¹, R², R³, R⁴, and R⁵ areindependently selected from the group consisting of hydrogen, deuterium,halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy,amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl,heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile,isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinationsthereof. Any substitutions are optionally joined or fused into a ring. nis 1 or 2. R is selected from the group consisting of alkyl, cycloalkyl,heteroalkyl, heterocycloalkyl, partially or fully fluorinated variantsthereof, partially or fully deuterated variants thereof, and combinationthereof. R has at least five carbon atoms.

In some embodiments of the emissive region, the compound is an emissivedopant or a non-emissive dopant.

In some embodiments, the emissive region further comprises a host,wherein the host comprises at least one selected from the groupconsisting of metal complex, triphenylene, carbazole, dibenzothiophene,dibenzofuran, dibenzoselenophene, aza-triphenylene, aza-carbazole,aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene.

In some embodiments, the emissive region further comprises a host,wherein the host is selected from the group consisting of:

and combinations thereof.

In some embodiments, the compound can be an emissive dopant. In someembodiments, the compound can produce emissions via phosphorescence,fluorescence, thermally activated delayed fluorescence, i.e., TADF (alsoreferred to as E-type delayed fluorescence), triplet-tripletannihilation, or combinations of these processes.

According to another aspect, a formulation comprising the compounddescribed herein is also disclosed.

The OLED disclosed herein can be incorporated into one or more of aconsumer product, an electronic component module, and a lighting panel.The organic layer can be an emissive layer and the compound can be anemissive dopant in some embodiments, while the compound can be anon-emissive dopant in other embodiments.

The organic layer can also include a host. In some embodiments, two ormore hosts are preferred. In some embodiments, the hosts used may be a)bipolar, b) electron transporting, c) hole transporting or d) wide bandgap materials that play little role in charge transport. In someembodiments, the host can include a metal complex. The host can be atriphenylene containing benzo-fused thiophene or benzo-fused furan. Anysubstituent in the host can be an unfused substituent independentlyselected from the group consisting of C_(n)H_(2n+1), OC_(n)H_(2n+1),OAr₁, N(C_(n)H_(2n+1))₂, N(Ar₁)(Ar₂), CH═CH—C_(n)H_(2n+1),C≡C—C_(n)H_(2n+1), Ar₁, Ar₁—Ar₂, and C_(n)H_(2n)—Ar₁, or the host has nosubstitutions. In the preceding substituents n can range from 1 to 10;and Ar₁ and Ar₂ can be independently selected from the group consistingof benzene, biphenyl, naphthalene, triphenylene, carbazole, andheteroaromatic analogs thereof. The host can be an inorganic compound.For example a Zn containing inorganic material e.g. ZnS.

The host can be a compound comprising at least one chemical groupselected from the group consisting of triphenylene, carbazole,dibenzothiophene, dibenzofuran, dibenzoselenophene, azatriphenylene,azacarbazole, aza-dibenzothiophene, aza-dibenzofuran, andaza-dibenzoselenophene. The host can include a metal complex. The hostcan be, but is not limited to, a specific compound selected from thegroup consisting of:

and combinations thereof.Additional information on possible hosts is provided below.

In yet another aspect of the present disclosure, a formulation thatcomprises the novel compound disclosed herein is described. Theformulation can include one or more components selected from the groupconsisting of a solvent, a host, a hole injection material, holetransport material, and an electron transport layer material, disclosedherein.

Combination with Other Materials

The materials described herein as useful for a particular layer in anorganic light emitting device may be used in combination with a widevariety of other materials present in the device. For example, emissivedopants disclosed herein may be used in conjunction with a wide varietyof hosts, transport layers, blocking layers, injection layers,electrodes and other layers that may be present. The materials describedor referred to below are non-limiting examples of materials that may beuseful in combination with the compounds disclosed herein, and one ofskill in the art can readily consult the literature to identify othermaterials that may be useful in combination.

Conductivity Dopants:

A charge transport layer can be doped with conductivity dopants tosubstantially alter its density of charge carriers, which will in turnalter its conductivity. The conductivity is increased by generatingcharge carriers in the matrix material, and depending on the type ofdopant, a change in the Fermi level of the semiconductor may also beachieved. Hole-transporting layer can be doped by p-type conductivitydopants and n-type conductivity dopants are used in theelectron-transporting layer.

Non-limiting examples of the conductivity dopants that may be used in anOLED in combination with materials disclosed herein are exemplifiedbelow together with references that disclose those materials:EP01617493, EP01968131, EP2020694, EP2684932, US20050139810,US20070160905, US20090167167, US2010288362, WO06081780, WO2009003455,WO2009008277, WO2009011327, WO2014009310, US2007252140, US2015060804 andUS2012146012.

HIL/HTL:

A hole injecting/transporting material to be used in the presentinvention is not particularly limited, and any compound may be used aslong as the compound is typically used as a hole injecting/transportingmaterial. Examples of the material include, but are not limited to: aphthalocyanine or porphyrin derivative; an aromatic amine derivative; anindolocarbazole derivative; a polymer containing fluorohydrocarbon; apolymer with conductivity dopants; a conducting polymer, such asPEDOT/PSS; a self-assembly monomer derived from compounds such asphosphonic acid and silane derivatives; a metal oxide derivative, suchas MoO_(x); a p-type semiconducting organic compound, such as1,4,5,8,9,12-Hexaazatriphenylenehexacarbonitrile; a metal complex, and across-linkable compounds.

Examples of aromatic amine derivatives used in HIL or HTL include, butnot limit to the following general structures:

Each of Ar¹ to Ar⁹ is selected from the group consisting of aromatichydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl,triphenylene, naphthalene, anthracene, phenalene, phenanthrene,fluorene, pyrene, chrysene, perylene, and azulene; the group consistingof aromatic heterocyclic compounds such as dibenzothiophene,dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran,benzothiophene, benzoselenophene, carbazole, indolocarbazole,pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole,oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole,pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine,oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine,benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline,cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine,pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine,benzofuropyridine, furodipyridine, benzothienopyridine,thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine;and the group consisting of 2 to 10 cyclic structural units which aregroups of the same type or different types selected from the aromatichydrocarbon cyclic group and the aromatic heterocyclic group and arebonded to each other directly or via at least one of oxygen atom,nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom,chain structural unit and the aliphatic cyclic group. Each Ar may beunsubstituted or may be substituted by a substituent selected from thegroup consisting of deuterium, halide, alkyl, cycloalkyl, heteroalkyl,arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl,heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylicacids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl,phosphino, and combinations thereof.

In one aspect, Ar¹ to Ar⁹ is independently selected from the groupconsisting of:

wherein k is an integer from 1 to 20; X¹⁰¹ to X¹⁰⁸ is C (including CH)or N; Z¹⁰¹ is NAr¹, O, or S; Ar¹ has the same group defined above.

Examples of metal complexes used in HIL or HTL include, but are notlimited to the following general formula:

wherein Met is a metal, which can have an atomic weight greater than 40;(Y¹⁰¹-Y¹⁰²) is a bidentate ligand, Y¹⁰¹ and Y¹⁰² are independentlyselected from C, N, O, P, and S; L¹⁰¹ is an ancillary ligand; k′ is aninteger value from 1 to the maximum number of ligands that may beattached to the metal; and k′+k″ is the maximum number of ligands thatmay be attached to the metal.

In one aspect, (Y¹⁰¹-Y¹⁰²) is a 2-phenylpyridine derivative. In anotheraspect, (Y¹⁰¹-Y¹⁰²) is a carbene ligand. In another aspect, Met isselected from Ir, Pt, Os, and Zn. In a further aspect, the metal complexhas a smallest oxidation potential in solution vs. Fc⁺/Fc couple lessthan about 0.6 V.

Non-limiting examples of the HIL and HTL materials that may be used inan OLED in combination with materials disclosed herein are exemplifiedbelow together with references that disclose those materials:CN102702075, DE102012005215, EP01624500, EP01698613, EP01806334,EP01930964, EP01972613, EP01997799, EP02011790, EP02055700, EP02055701,EP1725079, EP2085382, EP2660300, EP650955, JP07-073529, JP2005112765,JP2007091719, JP2008021687, JP2014-009196, KR20110088898, KR20130077473,TW201139402, U.S. Ser. No. 06/517,957, US20020158242, US20030162053,US20050123751, US20060182993, US20060240279, US20070145888,US20070181874, US20070278938, US20080014464, US20080091025,US20080106190, US20080124572, US20080145707, US20080220265,US20080233434, US20080303417, US2008107919, US20090115320,US20090167161, US2009066235, US2011007385, US20110163302, US2011240968,US2011278551, US2012205642, US2013241401, US20140117329, US2014183517,U.S. Pat. Nos. 5,061,569, 5,639,914, WO05075451, WO07125714, WO08023550,WO08023759, WO2009145016, WO2010061824, WO2011075644, WO2012177006,WO2013018530, WO2013039073, WO2013087142, WO2013118812, WO2013120577,WO2013157367, WO2013175747, WO2014002873, WO2014015935, WO2014015937,WO2014030872, WO2014030921, WO2014034791, WO2014104514, WO2014157018.

EBL:

An electron blocking layer (EBL) may be used to reduce the number ofelectrons and/or excitons that leave the emissive layer. The presence ofsuch a blocking layer in a device may result in substantially higherefficiencies, and/or longer lifetime, as compared to a similar devicelacking a blocking layer. Also, a blocking layer may be used to confineemission to a desired region of an OLED. In some embodiments, the EBLmaterial has a higher LUMO (closer to the vacuum level) and/or highertriplet energy than the emitter closest to the EBL interface. In someembodiments, the EBL material has a higher LUMO (closer to the vacuumlevel) and/or higher triplet energy than one or more of the hostsclosest to the EBL interface. In one aspect, the compound used in EBLcontains the same molecule or the same functional groups used as one ofthe hosts described below.

Host:

The light emitting layer of the organic EL device of the presentinvention preferably contains at least a metal complex as light emittingmaterial, and may contain a host material using the metal complex as adopant material. Examples of the host material are not particularlylimited, and any metal complexes or organic compounds may be used aslong as the triplet energy of the host is larger than that of thedopant. Any host material may be used with any dopant so long as thetriplet criteria is satisfied.

Examples of metal complexes used as host are preferred to have thefollowing general formula:

wherein Met is a metal; (Y¹⁰³-Y¹⁰⁴) is a bidentate ligand, Y¹⁰³ and Y¹⁰⁴are independently selected from C, N, O, P, and S; L¹⁰¹ is an anotherligand; k′ is an integer value from 1 to the maximum number of ligandsthat may be attached to the metal; and k′+k″ is the maximum number ofligands that may be attached to the metal.

In one aspect, the metal complexes are:

wherein (O—N) is a bidentate ligand, having metal coordinated to atoms Oand N.

In another aspect, Met is selected from Ir and Pt. In a further aspect,(Y¹⁰³-Y¹⁰⁴) is a carbene ligand.

Examples of other organic compounds used as host are selected from thegroup consisting of aromatic hydrocarbon cyclic compounds such asbenzene, biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene,anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene,perylene, and azulene; the group consisting of aromatic heterocycliccompounds such as dibenzothiophene, dibenzofuran, dibenzoselenophene,furan, thiophene, benzofuran, benzothiophene, benzoselenophene,carbazole, indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole,imidazole, triazole, oxazole, thiazole, oxadiazole, oxatriazole,dioxazole, thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine,triazine, oxazine, oxathiazine, oxadiazine, indole, benzimidazole,indazole, indoxazine, benzoxazole, benzisoxazole, benzothiazole,quinoline, isoquinoline, cinnoline, quinazoline, quinoxaline,naphthyridine, phthalazine, pteridine, xanthene, acridine, phenazine,phenothiazine, phenoxazine, benzofuropyridine, furodipyridine,benzothienopyridine, thienodipyridine, benzoselenophenopyridine, andselenophenodipyridine; and the group consisting of 2 to 10 cyclicstructural units which are groups of the same type or different typesselected from the aromatic hydrocarbon cyclic group and the aromaticheterocyclic group and are bonded to each other directly or via at leastone of oxygen atom, nitrogen atom, sulfur atom, silicon atom, phosphorusatom, boron atom, chain structural unit and the aliphatic cyclic group.Each option within each group may be unsubstituted or may be substitutedby a substituent selected from the group consisting of deuterium,halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy,amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl,heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile,isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinationsthereof.

In one aspect, the host compound contains at least one of the followinggroups in the molecule:

wherein R¹⁰¹ is selected from the group consisting of hydrogen,deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy,aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl,aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile,isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinationsthereof, and when it is aryl or heteroaryl, it has the similardefinition as Ar's mentioned above. k is an integer from 0 to 20 or 1 to20. X¹⁰⁸ to X¹⁰⁸ are independently selected from C (including CH) or N.Z¹⁰¹ and Y¹⁰² are independently selected from N¹⁰¹, O, or S.

Non-limiting examples of the host materials that may be used in an OLEDin combination with materials disclosed herein are exemplified belowtogether with references that disclose those materials: EP2034538,EP2034538A, EP2757608, JP2007254297, KR20100079458, KR20120088644,KR20120129733, KR20130115564, TW201329200, US20030175553, US20050238919,US20060280965, US20090017330, US20090030202, US20090167162,US20090302743, US20090309488, US20100012931, US20100084966,US20100187984, US2010187984, US2012075273, US2012126221, US2013009543,US2013105787, US2013175519, US2014001446, US20140183503, US20140225088,US2014034914, U.S. Pat. No. 7,154,114, WO2001039234, WO2004093207,WO2005014551, WO2005089025, WO2006072002, WO2006114966, WO2007063754,WO2008056746, WO2009003898, WO2009021126, WO2009063833, WO2009066778,WO2009066779, WO2009086028, WO2010056066, WO2010107244, WO2011081423,WO2011081431, WO2011086863, WO2012128298, WO2012133644, WO2012133649,WO2013024872, WO2013035275, WO2013081315, WO2013191404, WO2014142472,

Additional Emitters:

One or more additional emitter dopants may be used in conjunction withthe compound of the present disclosure. Examples of the additionalemitter dopants are not particularly limited, and any compounds may beused as long as the compounds are typically used as emitter materials.Examples of suitable emitter materials include, but are not limited to,compounds which can produce emissions via phosphorescence, fluorescence,thermally activated delayed fluorescence, i.e., TADF (also referred toas E-type delayed fluorescence), triplet-triplet annihilation, orcombinations of these processes.

Non-limiting examples of the emitter materials that may be used in anOLED in combination with materials disclosed herein are exemplifiedbelow together with references that disclose those materials:CN103694277, CN1696137, EB01238981, EP01239526, EP01961743, EP1239526,EP1244155, EP1642951, EP1647554, EP1841834, EP1841834B, EP2062907,EP2730583, JP2012074444, JP2013110263, JP4478555, KR1020090133652,KR20120032054, KR20130043460, TW201332980, U.S. Ser. No. 06/699,599,U.S. Ser. No. 06/916,554, US20010019782, US20020034656, US20030068526,US20030072964, US20030138657, US20050123788, US20050244673,US2005123791, US2005260449, US20060008670, US20060065890, US20060127696,US20060134459, US20060134462, US20060202194, US20060251923,US20070034863, US20070087321, US20070103060, US20070111026,US20070190359, US20070231600, US2007034863, US2007104979, US2007104980,US2007138437, US2007224450, US2007278936, US20080020237, US20080233410,US20080261076, US20080297033, US200805851, US2008161567, US2008210930,US20090039776, US20090108737, US20090115322, US20090179555,US2009085476, US2009104472, US20100090591, US20100148663, US20100244004,US20100295032, US2010102716, US2010105902, US2010244004, US2010270916,US20110057559, US20110108822, US20110204333, US2011215710, US2011227049,US2011285275, US2012292601, US20130146848, US2013033172, US2013165653,US2013181190, US2013334521, US20140246656, US2014103305, U.S. Pat. Nos.6,303,238, 6,413,656, 6,653,654, 6,670,645, 6,687,266, 6,835,469,6,921,915, 7,279,704, 7,332,232, 7,378,162, 7,534,505, 7,675,228,7,728,137, 7,740,957, 7,759,489, 7,951,947, 8,067,099, 8,592,586,8,871,361, WO06081973, WO06121811, WO07018067, WO07108362, WO07115970,WO07115981, WO08035571, WO2002015645, WO2003040257, WO2005019373,WO2006056418, WO2008054584, WO2008078800, WO2008096609, WO2008101842,WO2009000673, WO2009050281, WO2009100991, WO2010028151, WO2010054731,WO2010086089, WO2010118029, WO2011044988, WO2011051404, WO2011107491,WO2012020327, WO2012163471, WO2013094620, WO2013107487, WO2013174471,WO2014007565, WO2014008982, WO2014023377, WO2014024131, WO2014031977,WO2014038456, WO2014112450.

HBL:

A hole blocking layer (HBL) may be used to reduce the number of holesand/or excitons that leave the emissive layer. The presence of such ablocking layer in a device may result in substantially higherefficiencies and/or longer lifetime as compared to a similar devicelacking a blocking layer. Also, a blocking layer may be used to confineemission to a desired region of an OLED. In some embodiments, the HBLmaterial has a lower HOMO (further from the vacuum level) and/or highertriplet energy than the emitter closest to the HBL interface. In someembodiments, the HBL material has a lower HOMO (further from the vacuumlevel) and/or higher triplet energy than one or more of the hostsclosest to the HBL interface.

In one aspect, compound used in HBL contains the same molecule or thesame functional groups used as host described above.

In another aspect, compound used in HBL contains at least one of thefollowing groups in the molecule:

wherein k is an integer from 1 to 20; L¹⁰¹ is an another ligand, k′ isan integer from 1 to 3.ETL:

Electron transport layer (ETL) may include a material capable oftransporting electrons. Electron transport layer may be intrinsic(undoped), or doped. Doping may be used to enhance conductivity.Examples of the ETL material are not particularly limited, and any metalcomplexes or organic compounds may be used as long as they are typicallyused to transport electrons.

In one aspect, compound used in ETL contains at least one of thefollowing groups in the molecule:

wherein R¹⁰¹ is selected from the group consisting of hydrogen,deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy,aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl,aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile,isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinationsthereof, when it is aryl or heteroaryl, it has the similar definition asAr's mentioned above. Ar¹ to Ar³ has the similar definition as Ar'smentioned above. k is an integer from 1 to 20. X¹⁰¹ to X¹⁰⁸ is selectedfrom C (including CH) or N.

In another aspect, the metal complexes used in ETL contains, but notlimit to the following general formula:

wherein (O—N) or (N—N) is a bidentate ligand, having metal coordinatedto atoms O, N or N, N; L¹⁰¹ is another ligand; k′ is an integer valuefrom 1 to the maximum number of ligands that may be attached to themetal.

Non-limiting examples of the ETL materials that may be used in an OLEDin combination with materials disclosed herein are exemplified belowtogether with references that disclose those materials: CN103508940,EP01602648, EP01734038, EP01956007, JP2004-022334, JP2005149918,JP2005-268199, KR0117693, KR20130108183, US20040036077, US20070104977,US2007018155, US20090101870, US20090115316, US20090140637,US20090179554, US2009218940, US2010108990, US2011156017, US2011210320,US2012193612, US2012214993, US2014014925, US2014014927, US20140284580,U.S. Pat. Nos. 6,656,612, 8,415,031, WO2003060956, WO2007111263,WO2009148269, WO2010067894, WO2010072300, WO2011074770, WO2011105373,WO2013079217, WO2013145667, WO2013180376, WO2014104499, WO2014104535.

Charge Generation Layer (CGL)

In tandem or stacked OLEDs, the CGL plays an essential role in theperformance, which is composed of an n-doped layer and a p-doped layerfor injection of electrons and holes, respectively. Electrons and holesare supplied from the CGL and electrodes. The consumed electrons andholes in the CGL are refilled by the electrons and holes injected fromthe cathode and anode, respectively; then, the bipolar currents reach asteady state gradually. Typical CGL materials include n and pconductivity dopants used in the transport layers.

In any above-mentioned compounds used in each layer of the OLED device,the hydrogen atoms can be partially or fully deuterated. Thus, anyspecifically listed substituent, such as, without limitation, methyl,phenyl, pyridyl, etc. may be undeuterated, partially deuterated, andfully deuterated versions thereof. Similarly, classes of substituentssuch as, without limitation, alkyl, aryl, cycloalkyl, heteroaryl, etc.also may be undeuterated, partially deuterated, and fully deuteratedversions thereof.

Experimental Synthesis of Compound Ir(L_(A96)L_(B370))

Step 1

One 1 L 3-neck flask was charged with 2,4-dichloro-5-methylpyridine(15.28 g, 94 mmol), dibenzo[b,d]furan-4-ylboronic acid (20.0 g, 94mmol), sodium carbonate (30.0 g, 283 mmol), DME (400 ml), water (40 ml)and tetrakis(triphenylphosphine)palladium(0) (2.180 g, 1.887 mmol). Thereaction mixture was heated to reflux for 16 hrs. The reaction was thendiluted with 150 ml water and extracted with 3×100 ml EtOAc. Theextracts were washed with 100 ml water, dried and evaporated to dryness.The residue was purified by column chromatography (SiO2) to yield thedesired product (19.8 g).

Step 2

One 500 ml 3-neck oven dried flask was charged with Pd2(dba)3 (0.411 g,0.449 mmol), X phos (0.857 g, 1.797 mmol),4-chloro-2-(dibenzo[b,d]furan-4-yl)-5-methylpyridine (4.4 g, 14.98mmol), THF (75 ml) and cyclohexylzinc(II) bromide (0.5M in THF) (44.9ml, 22.47 mmol). The reaction was heated to 65° C. for 24 hours. Thereaction was then diluted with 150 ml water and extracted with 3×100 mlEtOAc. The extracts were washed with 100 ml water, dried and evaporatedto dryness. The residue was purified by column chromatography (SiO2) toyield the desired product (9.3 g).

Step 3

One 200 ml flask was charged with4-cyclohexyl-2-(dibenzo[b,d]furan-4-yl)-5-methylpyridine (4.7 g, 13.76mmol), DMSO-d6 (38.5 ml, 551 mmol) and sodium 2-methylpropan-2-olate(0.661 g, 6.88 mmol). The reaction was heated to 60° C. for overnight.The reaction was then diluted with 150 ml water and extracted with 3×100ml EtOAc. The extracts were washed with 100 ml water, dried andevaporated to dryness. The residue was purified by column chromatography(SiO2) to yield the desired product (4.2 g).

Step 4

One 250 ml r.b. flask was charged with4-(cyclohexyl-1-d)-2-(dibenzo[b,d]furan-4-yl)-5-(methyl-d3)pyridine(1.76 g, 5.12 mmol), Iridium metal complexes (2.0 g, 2.56 mmol),Methanol (30 ml) and Ethanol (30.0 ml). The reaction was heated to 80°C. for 5 days. The solvent was evaporated to dryness. The residue waspurified by column chromatography (SiO2) to yield the desired product(0.55 g).

Device Examples

All example devices were fabricated by high vacuum (<10⁻⁷ Torr) thermalevaporation. The anode electrode was 800 Å of indium tin oxide (ITO).The cathode consisted of 10 Å of Liq (8-hydroxyquinoline lithium)followed by 1,000 Å of Al. All devices were encapsulated with a glasslid sealed with an epoxy resin in a nitrogen glove box (<1 ppm of H₂Oand 02) immediately after fabrication with a moisture getterincorporated inside the package. The organic stack of the deviceexamples consisted of sequentially, from the ITO Surface: 100 Å ofHAT-CN as the hole injection layer (HIL); 450 Å of HTM as a holetransporting layer (HTL); emissive layer (EML) with thickness 400 Å.Emissive layer containing H-host (H1): E-host (H2) in 6:4 ratio and 12weight % of green emitter; 350 Å of Liq (8-hydroxyquinoline lithium)doped with 40% of ETM as the ETL. The device structure is shown in Table1 below. Table 1 shows the schematic device structure. The chemicalstructures of the device materials are shown below.

Upon fabrication, electroluminance (EL) and currentdensity-voltage-luminance (J-V-L) of the devices were measured at DC 10mA/cm². Device performance is tabulated in Table 2 below.

TABLE 1 schematic device structure Layer Material Thickness [Å] AnodeITO 800 HIL HAT-CN 100 HTL HTM 450 Green H1:H2: example 400 EML dopantETL Liq:ETM 40% 350 EIL Liq 10 Cathode Al 1,000

TABLE 2 Device performance 1931 CIE At 10 mA/cm²* λ max FWHM Voltage LEEmitter 12% X Y [nm] [nm] [a.u.] [a.u.] EQE [a.u.] PE [a.u.]Ir(L_(A96)L_(B370)) 0.323 0.633 520 62 0.97 1.03 1.03 1.04 Comparative0.325 0.631 520 63 1.00 1.00 1.00 1.00 Example

-   -   Data are normalized to the comparative example.

Referring to Table 2, comparing Ir(L_(A96)L_(B370)) with the comparativeexample; the inventive compound has higher efficiency and lower voltagethan the comparative compound. Presumably, the alkyl substitution in theperipheral ring has better alignment with transition dipolar moment ofthe molecule. The concept is illustrated in the diagram shown in FIG. 3.

It is understood that the various embodiments described herein are byway of example only, and are not intended to limit the scope of theinvention. For example, many of the materials and structures describedherein may be substituted with other materials and structures withoutdeviating from the spirit of the invention. The present invention asclaimed may therefore include variations from the particular examplesand preferred embodiments described herein, as will be apparent to oneof skill in the art. It is understood that various theories as to whythe invention works are not intended to be limiting.

We claim:
 1. A compound having the formula [L_(A)]_(3-n)Ir[L_(B)]_(n),having the structure:

wherein R¹, R², R³, R⁴, and R⁵ each independently represents mono, to amaximum possible number of substitutions, or no substitution; wherein Xis selected from the group consisting of BR′, NR′, PR′, 0, S, Se, C═O,S═O, SO₂, CR′R″, SiR′R″, and GeR′R″; wherein R′, R″, R′, R², R³, R⁴, andR⁵ are independently selected from the group consisting of hydrogen,deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy,aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl,aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile,isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinationsthereof; wherein any substitutions are optionally joined or fused into aring; wherein n is 1 or 2; wherein R is selected from the groupconsisting of alkyl, and partially or fully deuterated variants thereof;and wherein R has at least five carbon atoms.
 2. The compound of claim1, wherein R has at least six carbon atoms.
 3. The compound of claim 1,wherein R has at least seven carbon atoms.
 4. The compound of claim 1,wherein n is
 2. 5. The compound of claim 1, wherein X is O.
 6. Thecompound of claim 1, wherein R¹, R², R³, R⁴, and R⁵ are eachindependently selected from the group consisting of hydrogen, deuterium,alkyl, cycloalkyl, aryl, and combinations thereof.
 7. The compound ofclaim 1, wherein the compound is selected from the group consisting of:

wherein R⁶ is selected from the group consisting of hydrogen, deuterium,halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy,amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl,heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile,isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinationsthereof.
 8. The compound of claim 1, wherein L_(B) is selected from thegroup consisting of L_(B1) to L_(B1471) having a structure according to

wherein R^(B1), R^(B2), R^(B3), and R^(B4) are defined as providedbelow: L_(Bi), where i is R^(B1) R^(B2) R^(B3) R^(B4)
 1. H H H H
 2. CH₃H H H
 3. H CH₃ H H
 4. H H CH₃ H
 5. CH₃ CH₃ H CH₃
 6. CH₃ H CH₃ H
 7. CH₃ HH CH₃
 8. H CH₃ CH₃ H
 9. H CH₃ H CH₃
 10. H H CH₃ CH₃
 11. CH₃ CH₃ CH₃ H12. CH₃ CH₃ H CH₃
 13. CH₃ H CH₃ CH₃
 14. H CH₃ CH₃ CH₃
 15. CH₃ CH₃ CH₃CH₃
 16. CH₂CH₃ H H H
 17. CH₂CH₃ CH₃ H CH₃
 18. CH₂CH₃ H CH₃ H
 19. CH₂CH₃H H CH₃
 20. CH₂CH₃ CH₃ CH₃ H
 21. CH₂CH₃ CH₃ H CH₃
 22. CH₂CH₃ H CH₃ CH₃23. CH₂CH₃ CH₃ CH₃ CH₃
 24. H CH₂CH₃ H H
 25. CH₃ CH₂CH₃ H CH₃
 26. HCH₂CH₃ CH₃ H
 27. H CH₂CH₃ H CH₃
 28. CH₃ CH₂CH₃ CH₃ H
 29. CH₃ CH₂CH₃ HCH₃
 30. H CH₂CH₃ CH₃ CH₃
 31. CH₃ CH₂CH₃ CH₃ CH₃
 32. H H CH₂CH₃ H
 33. CH₃H CH₂CH₃ H
 34. H CH₃ CH₂CH₃ H
 35. H H CH₂CH₃ CH₃
 36. CH₃ CH₃ CH₂CH₃ H37. CH₃ H CH₂CH₃ CH₃
 38. H CH₃ CH₂CH₃ CH₃
 39. CH₃ CH₃ CH₂CH₃ CH₃ 40.CH(CH₃)₂ H H H
 41. CH(CH₃)₂ CH₃ H CH₃
 42. CH(CH₃)₂ H CH₃ H
 43. CH(CH₃)₂H H CH₃
 44. CH(CH₃)₂ CH₃ CH₃ H
 45. CH(CH₃)₂ CH₃ H CH₃
 46. CH(CH₃)₂ H CH₃CH₃
 47. CH(CH₃)₂ CH₃ CH₃ CH₃
 48. H CH(CH₃)₂ H H
 49. CH₃ CH(CH₃)₂ H CH₃50. H CH(CH₃)₂ CH₃ H
 51. H CH(CH₃)₂ H CH₃
 52. CH₃ CH(CH₃)₂ CH₃ H
 53. CH₃CH(CH₃)₂ H CH₃
 54. H CH(CH₃)₂ CH₃ CH₃
 55. CH₃ CH(CH₃)₂ CH₃ CH₃
 56. H HCH(CH₃)₂ H
 57. CH₃ H CH(CH₃)₂ H
 58. H CH₃ CH(CH₃)₂ H
 59. H H CH(CH₃)₂CH₃
 60. CH₃ CH₃ CH(CH₃)₂ H
 61. CH₃ H CH(CH₃)₂ CH₃
 62. H CH₃ CH(CH₃)₂ CH₃63. CH₃ CH₃ CH(CH₃)₂ CH₃
 64. CH₂CH(CH₃)₂ H H H
 65. CH₂CH(CH₃)₂ CH₃ H CH₃66. CH₂CH(CH₃)₂ H CH₃ H
 67. CH₂CH(CH₃)₂ H H CH₃
 68. CH₂CH(CH₃)₂ CH₃ CH₃H
 69. CH₂CH(CH₃)₂ CH₃ H CH₃
 70. CH₂CH(CH₃)₂ H CH₃ CH₃
 71. CH₂CH(CH₃)₂CH₃ CH₃ CH₃
 72. H CH₂CH(CH₃)₂ H H
 73. CH₃ CH₂CH(CH₃)₂ H CH₃
 74. HCH₂CH(CH₃)₂ CH₃ H
 75. H CH₂CH(CH₃)₂ H CH₃
 76. CH₃ CH₂CH(CH₃)₂ CH₃ H 77.CH₃ CH₂CH(CH₃)₂ H CH₃
 78. H CH₂CH(CH₃)₂ CH₃ CH₃
 79. CH₃ CH₂CH(CH₃)₂ CH₃CH₃
 80. H H CH₂CH(CH₃)₂ H
 81. CH₃ H CH₂CH(CH₃)₂ H
 82. H CH₃ CH₂CH(CH₃)₂H
 83. H H CH₂CH(CH₃)₂ CH₃
 84. CH₃ CH₃ CH₂CH(CH₃)₂ H
 85. CH₃ HCH₂CH(CH₃)₂ CH₃
 86. H CH₃ CH₂CH(CH₃)₂ CH₃
 87. CH₃ CH₃ CH₂CH(CH₃)₂ CH₃88. C(CH₃)₃ H H H
 89. C(CH₃)₃ CH₃ H CH₃
 90. C(CH₃)₃ H CH₃ H
 91. C(CH₃)₃H H CH₃
 92. C(CH₃)₃ CH₃ CH₃ H
 93. C(CH₃)₃ CH₃ H CH₃
 94. C(CH₃)₃ H CH₃CH₃
 95. C(CH₃)₃ CH₃ CH₃ CH₃
 96. H C(CH₃)₃ H H
 97. CH₃ C(CH₃)₃ H CH₃ 98.H C(CH₃)₃ CH₃ H
 99. H C(CH₃)₃ H CH₃
 100. CH₃ C(CH₃)₃ CH₃ H
 101. CH₃C(CH₃)₃ H CH₃
 102. H C(CH₃)₃ CH₃ CH₃
 103. CH₃ C(CH₃)₃ CH₃ CH₃
 104. H HC(CH₃)₃ H
 105. CH₃ H C(CH₃)₃ H
 106. H CH₃ C(CH₃)₃ H
 107. H H C(CH₃)₃ CH₃108. CH₃ CH₃ C(CH₃)₃ H
 109. CH₃ H C(CH₃)₃ CH₃
 110. H CH₃ C(CH₃)₃ CH₃111. CH₃ CH₃ C(CH₃)₃ CH₃
 112. CH₂C(CH₃)₃ H H H
 113. CH₂C(CH₃)₃ CH₃ H CH₃114. CH₂C(CH₃)₃ H CH₃ H
 115. CH₂C(CH₃)₃ H H CH₃
 116. CH₂C(CH₃)₃ CH₃ CH₃H
 117. CH₂C(CH₃)₃ CH₃ H CH₃
 118. CH₂C(CH₃)₃ H CH₃ CH₃
 119. CH₂C(CH₃)₃CH₃ CH₃ CH₃
 120. H CH₂C(CH₃)₃ H H
 121. CH₃ CH₂C(CH₃)₃ H CH₃
 122. HCH₂C(CH₃)₃ CH₃ H
 123. H CH₂C(CH₃)₃ H CH₃
 124. CH₃ CH₂C(CH₃)₃ CH₃ H 125.CH₃ CH₂C(CH₃)₃ H CH₃
 126. H CH₂C(CH₃)₃ CH₃ CH₃
 127. CH₃ CH₂C(CH₃)₃ CH₃CH₃
 128. H H CH₂C(CH₃)₃ H
 129. CH₃ H CH₂C(CH₃)₃ H
 130. H CH₃ CH₂C(CH₃)₃H
 131. H H CH₂C(CH₃)₃ CH₃
 132. CH₃ CH₃ CH₂C(CH₃)₃ H
 133. CH₃ HCH₂C(CH₃)₃ CH₃
 134. H CH₃ CH₂C(CH₃)₃ CH₃
 135. CH₃ CH₃ CH₂C(CH₃)₃ CH₃136.

H H H
 137.

CH₃ H CH₃
 138.

H CH₃ H
 139.

H H CH₃
 140.

CH₃ CH₃ H
 141.

CH₃ H CH₃
 142.

H CH₃ CH₃
 143.

CH₃ CH₃ CH₃
 144. H

H H
 145. CH₃

H CH₃
 146. H

CH₃ H
 147. H

H CH₃
 148. CH₃

CH₃ H
 149. CH₃

H CH₃
 150. H

CH₃ CH₃
 151. CH₃

CH₃ CH₃
 152. H H

H
 153. CH₃ H

H
 154. H CH₃

H
 155. H H

CH₃
 156. CH₃ CH₃

H
 157. CH₃ H

CH₃
 158. H CH₃

CH₃
 159. CH₃ CH₃

CH₃
 160.

H H H
 161.

CH₃ H CH₃
 162.

H CH₃ H
 163.

H H CH₃
 164.

CH₃ CH₃ H
 165.

CH₃ H CH₃
 166.

H CH₃ CH₃
 167.

CH₃ CH₃ CH₃
 168. H

H H
 169. CH₃

H CH₃
 170. H

CH₃ H
 171. H

H CH₃
 172. CH₃

CH₃ H
 173. CH₃

H CH₃
 174. H

CH₃ CH₃
 175. CH₃

CH₃ CH₃
 176. H H

H
 177. CH₃ H

H
 178. H CH₃

H
 179. H H

CH₃
 180. CH₃ CH₃

H
 181. CH₃ H

CH₃
 182. H CH₃

CH₃
 183. CH₃ CH₃

CH₃
 184.

H H H
 185.

CH₃ H CH₃
 186.

H CH₃ H
 187.

H H CH₃
 188.

CH₃ CH₃ H
 189.

CH₃ H CH₃
 190.

H CH₃ CH₃
 191.

CH₃ CH₃ CH₃
 192. H

H H
 193. CH₃

H CH₃
 194. H

CH₃ H
 195. H

H CH₃
 196. CH₃

CH₃ H
 197. CH₃

H CH₃
 198. H

CH₃ CH₃
 199. CH₃

CH₃ CH₃
 200. H H

H
 201. CH₃ H

H
 202. H CH₃

H
 203. H H

CH₃
 204. CH₃ CH₃

H
 205. CH₃ H

CH₃
 206. H CH₃

CH₃
 207. CH₃ CH₃

CH₃
 208.

H H H
 209.

CH₃ H CH₃
 210.

H CH₃ H
 211.

H H CH₃
 212.

CH₃ CH₃ H
 213.

CH₃ H CH₃
 214.

H CH₃ CH₃
 215.

CH₃ CH₃ CH₃
 216. H

H H
 217. CH₃

H CH₃
 218. H

CH₃ H
 219. H

H CH₃
 220. CH₃

CH₃ H
 221. CH₃

H CH₃
 222. H

CH₃ CH₃
 223. CH₃

CH₃ CH₃
 224. H H

H
 225. CH₃ H

H
 226. H CH₃

H
 227. H H

CH₃
 228. CH₃ CH₃

H
 229. CH₃ H

CH₃
 230. H CH₃

CH₃
 231. CH₃ CH₃

CH₃
 232.

H H H
 233.

CH₃ H CH₃
 234.

CH₃ H
 235.

H H CH₃
 236.

CH₃ CH₃ H
 237.

CH₃ H CH₃
 238.

H CH₃ CH₃
 239.

CH₃ CH₃ CH₃
 240. H

H
 241. CH₃

CH₃
 242. H

CH₃ H
 243. H

CH₃
 244. CH₃

CH₃ H
 245. CH₃

CH₃
 246. H

CH₃ CH₃
 247. CH₃

CH₃ CH₃
 248. H H

H
 249. CH₃ H

H
 250. H CH₃

H
 251. H H

CH₃
 252. CH₃ CH₃

H
 253. CH₃ H

CH₃
 254. H CH₃

CH₃
 255. CH₃ CH₃

CH₃
 256.

H H H
 257.

CH₃ H CH₃
 258.

H CH₃ H
 259.

H H CH₃
 260.

CH₃ CH₃ H
 261.

CH₃ H CH₃
 262.

H CH₃ CH₃
 263.

CH₃ CH₃ CH₃
 264. H

H H
 265. CH₃

H CH₃
 266. H

CH₃ H
 267. H

H CH₃
 268. CH₃

CH₃ H
 269. CH₃

H CH₃
 270. H

CH₃ CH₃
 271. CH₃

CH₃ CH₃
 272. H H

H
 273. CH₃ H

H
 274. H CH₃

H
 275. H H

CH₃
 276. CH₃ CH₃

H
 277. CH₃ H

CH₃
 278. H CH₃

CH₃
 279. CH₃ CH₃

CH₃
 280. CH(CH₃)₂ H CH₂CH₃ H
 281. CH(CH₃)₂ H CH(CH₃)₂ H
 282. CH(CH₃)₂ HCH₂CH(CH₃)₂ H
 283. CH(CH₃)₂ H C(CH₃)₃ H
 284. CH(CH₃)₂ H CH₂C(CH₃)₃ H285. CH(CH₃)₂ H

H
 286. CH(CH₃)₂ H

H
 287. CH(CH₃)₂ H

H
 288. CH(CH₃)₂ H

H
 289. CH(CH₃)₂ H

H
 290. CH(CH₃)₂ H

H
 291. C(CH₃)₃ H CH₂CH₃ H
 292. C(CH₃)₃ H CH(CH₃)₂ H
 293. C(CH₃)₃ HCH₂CH(CH₃)₂ H
 294. C(CH₃)₃ H C(CH₃)₃ H
 295. C(CH₃)₃ H CH₂C(CH₃)₃ H 296.C(CH₃)₃ H

H
 297. C(CH₃)₃ H

H
 298. C(CH₃)₃ H

H
 299. C(CH₃)₃ H

H
 300. C(CH₃)₃ H

H
 301. C(CH₃)₃ H

H
 302. CH₂C(CH₃)₃ H CH₂CH₃ H
 303. CH₂C(CH₃)₃ H CH(CH₃)₂ H 304.CH₂C(CH₃)₃ H CH₂CH(CH₃)₂ H
 305. CH₂C(CH₃)₃ H C(CH₃)₃ H
 306. CH₂C(CH₃)₃ HCH₂C(CH₃)₃ H
 307. CH₂C(CH₃)₃ H

H
 308. CH₂C(CH₃)₃ H

H
 309. CH₂C(CH₃)₃ H

H
 310. CH₂C(CH₃)₃ H

H
 311. CH₂C(CH₃)₃ H

H
 312. CH₂C(CH₃)₃ H

H
 313.

H CH₂CH₃ H
 314.

H CH(CH₃)₂ H
 315.

H CH₂CH(CH₃)₂ H
 316.

H C(CH₃)₃ H
 317.

H CH₂C(CH₃)₃ H
 318.

H

H
 319.

H

H
 320.

H

H
 321.

H

H
 322.

H

H
 323.

H

H
 324.

H CH₂CH₃ H
 325.

H CH(CH₃)₂ H
 326.

H CH₂CH(CH₃)₂ H
 327.

H C(CH₃)₃ H
 328.

H CH₂C(CH₃)₃ H
 329.

H

H
 330.

H

H
 331.

H

H
 332.

H

H
 333.

H

H
 334.

H

H
 335.

H CH₂CH(CH₃)₂ H
 336.

H C(CH₃)₃ H
 337.

H CH₂C(CH₃)₃ H
 338.

H CH₂CH₂CF₃ H
 339.

H CH₂C(CH₃)₂CF₃ H
 340.

H

H
 341.

H

H
 342.

H

H
 343.

H

H
 344.

H

H
 345.

H

H
 346.

H CH₂CH(CH₃)₂ H
 347.

H C(CH₃)₃ H
 348.

H CH₂C(CH₃)₃ H
 349.

H

H
 350.

H

H
 351.

H

H
 352.

H

H
 353.

H

H
 354.

H

H
 355.

H CH₂CH(CH₃)₂ H
 356.

H C(CH₃)₃ H
 357.

H CH₂C(CH₃)₃ H
 358.

H

H
 359.

H

H
 360.

H

H
 361.

H

H
 362.

H

H
 363.

H

H
 364. H H H H
 365. CD₃ H H H
 366. H CD₃ H H
 367. H H CD₃ H
 368. CD₃ CD₃H CD₃
 369. CD₃ H CD₃ H
 370. CD₃ H H CD₃
 371. H CD₃ CH₃ H
 372. H CD₃ HCD₃
 373. H H CD₃ CD₃
 374. CD₃ CD₃ CD₃ H
 375. CD₃ CD₃ H CD₃
 376. CD₃ HCD₃ CD₃
 377. H CD₃ CD₃ CD₃
 378. CD₃ CD₃ CD₃ CD₃
 379. CD₂CH₃ H H H 380.CD₂CH₃ CD₃ H CD₃
 381. CD₂CH₃ H CD₃ H
 382. CD₂CH₃ H H CD₃
 383. CD₂CH₃ CD₃CD₃ H
 384. CD₂CH₃ CD₃ H CD₃
 385. CD₂CH₃ H CD₃ CD₃
 386. CD₂CH₃ CD₃ CD₃CD₃
 387. H CD₂CH₃ H H
 388. CH₃ CD₂CH₃ H CD₃
 389. H CD₂CH₃ CD₃ H
 390. HCD₂CH₃ H CD₃
 391. CD₃ CD₂CH₃ CD₃ H
 392. CD₃ CD₂CH₃ H CD₃
 393. H CD₂CH₃CD₃ CD₃
 394. CD₃ CD₂CH₃ CD₃ CD₃
 395. H H CD₂CH₃ H
 396. CD₃ H CD₂CH₃ H397. H CD₃ CD₂CH₃ H
 398. H H CD₂CH₃ CD₃
 399. CD₃ CD₃ CD₂CH₃ H
 400. CD₃ HCD₂CH₃ CD₃
 401. H CD₃ CD₂CH₃ CD₃
 402. CD₃ CD₃ CD₂CH₃ CD₃
 403. CD(CH₃)₂ HH H
 404. CD(CH₃)₂ CD₃ H CD₃
 405. CD(CH₃)₂ H CD₃ H
 406. CD(CH₃)₂ H H CD₃407. CD(CH₃)₂ CD₃ CD₃ H
 408. CD(CH₃)₂ CD₃ H CD₃
 409. CD(CH₃)₂ H CD₃ CD₃410. CD(CH₃)₂ CD₃ CD₃ CD₃
 411. H CD(CH₃)₂ H H
 412. CD₃ CD(CH₃)₂ H CD₃413. H CD(CH₃)₂ CD₃ H
 414. H CD(CH₃)₂ H CD₃
 415. CD₃ CD(CH₃)₂ CD₃ H 416.CD₃ CD(CH₃)₂ H CD₃
 417. H CD(CH₃)₂ CD₃ CD₃
 418. CD₃ CD(CH₃)₂ CD₃ CD₃419. H H CD(CH₃)₂ H
 420. CD₃ H CD(CH₃)₂ H
 421. H CD₃ CD(CH₃)₂ H
 422. H HCD(CH₃)₂ CD₃
 423. CD₃ CD₃ CD(CH₃)₂ H
 424. CD₃ H CD(CH₃)₂ CD₃
 425. H CD₃CD(CH₃)₂ CD₃
 426. CD₃ CD₃ CD(CH₃)₂ CD₃
 427. CD(CD₃)₂ H H H
 428. CD(CD₃)₂CD₃ H CD₃
 429. CD(CD₃)₂ H CD₃ H
 430. CD(CD₃)₂ H H CD₃
 431. CD(CD₃)₂ CD₃CD₃ H
 432. CD(CD₃)₂ CD₃ H CD₃
 433. CD(CD₃)₂ H CD₃ CD₃
 434. CD(CD₃)₂ CD₃CD₃ CD₃
 435. H CD(CD₃)₂ H H
 436. CH₃ CD(CD₃)₂ H CD₃
 437. H CD(CD₃)₂ CD₃H
 438. H CD(CD₃)₂ H CD₃
 439. CD₃ CD(CD₃)₂ CD₃ H
 440. CD₃ CD(CD₃)₂ H CD₃441. H CD(CD₃)₂ CD₃ CD₃
 442. CD₃ CD(CD₃)₂ CD₃ CD₃
 443. H H CD(CD₃)₂ H444. CD₃ H CD(CD₃)₂ H
 445. H CD₃ CD(CD₃)₂ H
 446. H H CD(CD₃)₂ CD₃ 447.CD₃ CD₃ CD(CD₃)₂ H
 448. CD₃ H CD(CD₃)₂ CD₃
 449. H CD₃ CD(CD₃)₂ CD₃ 450.CD₃ CD₃ CD(CD₃)₂ CD₃
 451. CD₂CH(CH₃)₂ H H H
 452. CD₂CH(CH₃)₂ CD₃ H CD₃453. CD₂CH(CH₃)₂ H CD₃ H
 454. CD₂CH(CH₃)₂ H H CD₃
 455. CD₂CH(CH₃)₂ CD₃CD₃ H
 456. CD₂CH(CH₃)₂ CD₃ H CD₃
 457. CD₂CH(CH₃)₂ H CD₃ CD₃ 458.CD₂CH(CH₃)₂ CD₃ CD₃ CD₃
 459. H CD₂CH(CH₃)₂ H H
 460. CD₃ CD₂CH(CH₃)₂ HCD₃
 461. H CD₂CH(CH₃)₂ CD₃ H
 462. H CD₂CH(CH₃)₂ H CD₃
 463. CD₃CD₂CH(CH₃)₂ CD₃ H
 464. CD₃ CD₂CH(CH₃)₂ H CD₃
 465. H CD₂CH(CH₃)₂ CD₃ CD₃466. CD₃ CD₂CH(CH₃)₂ CD₃ CD₃
 467. H H CD₂CH(CH₃)₂ H
 468. CD₃ HCD₂CH(CH₃)₂ H
 469. H CD₃ CD₂CH(CH₃)₂ H
 470. H H CD₂CH(CH₃)₂ CD₃
 471. CD₃CD₃ CD₂CH(CH₃)₂ H
 472. CD₃ H CD₂CH(CH₃)₂ CD₃
 473. H CD₃ CD₂CH(CH₃)₂ CD₃474. CD₃ CD₃ CD₂CH(CH₃)₂ CD₃
 475. CD₂C(CH₃)₃ H H H
 476. CD₂C(CH₃)₃ CD₃ HCD₃
 477. CD₂C(CH₃)₃ H CD₃ H
 478. CD₂C(CH₃)₃ H H CD₃
 479. CD₂C(CH₃)₃ CD₃CD₃ H
 480. CD₂C(CH₃)₃ CD₃ H CD₃
 481. CD₂C(CH₃)₃ H CD₃ CD₃ 482.CD₂C(CH₃)₃ CH₃ CD₃ CD₃
 483. H CD₂C(CH₃)₃ H H
 484. CD₃ CD₂C(CH₃)₃ H CD₃485. H CD₂C(CH₃)₃ CD₃ H
 486. H CD₂C(CH₃)₃ H CD₃
 487. CD₃ CD₂C(CH₃)₃ CD₃H
 488. CD₃ CD₂C(CH₃)₃ H CD₃
 489. H CD₂C(CH₃)₃ CD₃ CD₃
 490. CD₃CD₂C(CH₃)₃ CD₃ CD₃
 491. H H CD₂C(CH₃)₃ H
 492. CD₃ H CD₂C(CH₃)₃ H
 493. HCD₃ CD₂C(CH₃)₃ H
 494. H H CD₂C(CH₃)₃ CD₃
 495. CD₃ CD₃ CD₂C(CH₃)₃ H 496.CD₃ H CD₂C(CH₃)₃ CD₃
 497. H CD₃ CD₂C(CH₃)₃ CD₃
 498. CD₃ CD₃ CD₂C(CH₃)₃CD₃
 499.

H H H
 500.

CD₃ H CD₃
 501.

H CD₃ H
 502.

H H CD₃
 503.

CD₃ CD₃ H
 504.

CD₃ H CD₃
 505.

H CD₃ CD₃
 506.

CD₃ CD₃ CD₃
 507. H

H H
 508. CD₃

H CD₃
 509. H

CD₃ H
 510. H

H CD₃
 511. CD₃

CD₃ H
 512. CD₃

H CD₃
 513. H

CD₃ CD₃
 514. CD₃

CD₃ CD₃
 515. H H

H
 516. CD₃ H

H
 517. H CD₃

H
 518. H H

CD₃
 519. CD₃ CD₃

H
 520. CD₃ H

CD₃
 521. H CD₃

CD₃
 522. CD₃ CD₃

CD₃
 523.

H H H
 524.

CD₃ H CD₃
 525.

H CD₃ H
 526.

H H CD₃
 527.

CD₃ CD₃ H
 528.

CD₃ H CD₃
 529.

H CD₃ CD₃
 530.

CD₃ CD₃ CD₃
 531. H

H H
 532. CH₃

H CD₃
 533. H

CD₃ H
 534. H

H CD₃
 535. CD₃

CD₃ H
 536. CD₃

H CD₃
 537. H

CD₃ CD₃
 538. CH₃

CD₃ CD₃
 539. H H

H
 540. CD₃ H

H
 541. H CD₃

H
 542. H H

CD₃
 543. CD₃ CD₃

H
 544. CD₃ H

CD₃
 545. H CD₃

CD₃
 546. CD₃ CD₃

CD₃
 547.

H H H
 548.

CD₃ H CD₃
 549.

H CD₃ H
 550.

H H CD₃
 551.

CD₃ CD₃ H
 552.

CD₃ H CD₃
 553.

H CD₃ CD₃
 554.

CD₃ CD₃ CD₃
 555. H

H H
 556. CD₃

H CD₃
 557. H

CD₃ H
 558. H

H CD₃
 559. CD₃

CD₃ H
 560. CD₃

H CD₃
 561. H

CD₃ CD₃
 562. CD₃

CD₃ CD₃
 563. H H

H
 564. CD₃ H

H
 565. H CD₃

H
 566. H H

CD₃
 567. CD₃ CD₃

H
 568. CD₃ H

CD₃
 569. H CD₃

CD₃
 570. CD₃ CD₃

CD₃
 571.

H H H
 572.

CD₃ H CD₃
 573.

H CD₃ H
 574.

H H CD₃
 575.

CD₃ CD₃ H
 576.

CD₃ H CD₃
 577.

H CD₃ CD₃
 578.

CD₃ CD₃ CD₃
 579. H

H H
 580. CD₃

H CD₃
 581. H

CD₃ H
 582. H

H CD₃
 583. CD₃

CD₃ H
 584. CD₃

H CD₃
 585. H

CD₃ CD₃
 586. CD₃

CD₃ CD₃
 587. H H

H
 588. CD₃ H

H
 589. H CD₃

H
 590. H H

CD₃
 591. CD₃ CD₃

H
 592. CD₃ H

CD₃
 593. H CD₃

CD₃
 594. CD₃ CD₃

CD₃
 595.

H H H
 596.

CD₃ H CD₃
 597.

H CD₃ H
 598.

H H CD₃
 599.

CD₃ CD₃ H
 600.

CD₃ H CD₃
 601.

H CD₃ CD₃
 602.

CD₃ CD₃ CD₃
 603. H

H H
 604. CD₃

H CD₃
 605. H

CD₃ H
 606. H

H CD₃
 607. CD₃

CD₃ H
 608. CD₃

H CD₃
 609. H

CD₃ CD₃
 610. CD₃

CD₃ CD₃
 611. H H

H
 612. CD₃ H

H
 613. H CD₃

H
 614. H H

CD₃
 615. CD₃ CD₃

H
 616. CD₃ H

CD₃
 617. H CD₃

CD₃
 618. CD₃ CD₃

CD₃
 619.

H H H
 620.

CD₃ H CD₃
 621.

H CD₃ H
 622.

H H CD₃
 623.

CH₃ CH₃ H
 624.

CD₃ H CD₃
 625.

H CD₃ CD₃
 626.

CD₃ CD₃ CD₃
 627. H

H H
 628. CD₃

H CD₃
 629. H

CD₃ H
 630. H

H CD₃
 631. CD₃

CD₃ H
 632. CD₃

H CD₃
 633. H

CD₃ CD₃
 634. CD₃

CD₃ CD₃
 635. H H

H
 636. CD₃ H

H
 637. H CD₃

H
 638. H H

CH₃
 639. CD₃ CD₃

H
 640. CD₃ H

CD₃
 641. H CD₃

CD₃
 642. CD₃ CD₃

CD₃
 643. CD(CH₃)₂ H CD₂CH₃ H
 644. CD(CH₃)₂ H CD(CH₃)₂ H
 645. CD(CH₃)₂ HCD₂CH(CH₃)₂ H
 646. CD(CH₃)₂ H C(CH₃)₃ H
 647. CD(CH₃)₂ H CD₂C(CH₃)₃ H648. CD(CH₃)₂ H

H
 649. CD(CH₃)₂ H

H
 650. CD(CH₃)₂ H

H
 651. CD(CH₃)₂ H

H
 652. CD(CH₃)₂ H

H
 653. CD(CH₃)₂ H

H
 654. C(CH₃)₃ H CD₂CH₃ H
 655. C(CH₃)₃ H CD(CH₃)₂ H
 656. C(CH₃)₃ HCD₂CH(CH₃)₂ H
 657. C(CH₃)₃ H C(CH₃)₃ H
 658. C(CH₃)₃ H CD₂C(CH₃)₃ H 659.C(CH₃)₃ H

H
 660. C(CH₃)₃ H

H
 661. C(CH₃)₃ H

H
 662. C(CH₃)₃ H

H
 663. C(CH₃)₃ H

H
 664. C(CH₃)₃ H

H
 665. CD₂C(CH₃)₃ H CD₂CH₃ H
 666. CD₂C(CH₃)₃ H CD(CH₃)₂ H 667.CD₂C(CH₃)₃ H CD₂CH(CH₃)₂ H
 668. CD₂C(CH₃)₃ H C(CH₃)₃ H
 669. CD₂C(CH₃)₃ HCD₂C(CH₃)₃ H
 670. CD₂C(CH₃)₃ H

H
 671. CD₂C(CH₃)₃ H

H
 672. CD₂C(CH₃)₃ H

H
 673. CD₂C(CH₃)₃ H

H
 674. CD₂C(CH₃)₃ H

H
 675. CD₂C(CH₃)₃ H

H
 676.

H CD₂CH₃ H
 677.

H CD(CH₃)₂ H
 678.

H CD₂CH(CH₃)₂ H
 679.

H C(CH₃)₃ H
 680.

H CD₂C(CH₃)₃ H
 681.

H

H
 682.

H

H
 683.

H

H
 684.

H

H
 685.

H

H
 686.

H

H
 687.

H CD₂CH₃ H
 688.

H CD(CH₃)₂ H
 689.

H CD₂CH(CH₃)₂ H
 690.

H C(CH₃)₃ H
 691.

H CD₂C(CH₃)₃ H
 692.

H CD₂CH₂CF₃ H
 693.

H CD₂C(CH₃)₂CF₃ H
 694.

H

H
 695.

H

H
 696.

H

H
 697.

H

H
 698.

H

H
 699.

H

H
 700.

H CD₂CH₃ H
 701.

H CD(CH₃)₂ H
 702.

H CD₂CH(CH₃)₂ H
 703.

H C(CH₃)₃ H
 704.

H CD₂C(CH₃)₃ H
 705.

H CD₂CH₂CF₃ H
 706.

H CD₂C(CH₃)₂CF₃ H
 707.

H

H
 708.

H

H
 709.

H

H
 710.

H

H
 711.

H

H
 712.

H

H
 713.

H CD₂CH₃ H
 714.

H CD(CH₃)₂ H
 715.

H CD₂CH(CH₃)₂ H
 716.

H C(CH₃)₃ H
 717.

H CD₂C(CH₃)₃ H
 718.

H CD₂CH₂CF₃ H
 719.

H CD₂C(CH₃)₂CF₃ H
 720.

H

H
 721.

H

H
 722.

H

H
 723.

H

H
 724.

H

H
 725.

H

H
 726.

H CD₂CH₃ H
 727.

H CD(CH₃)₂ H
 728.

H CD₂CH(CH₃)₂ H
 729.

H C(CH₃)₃ H
 730.

H CD₂C(CH₃)₃ H
 731.

H CD₂CH₂CF₃ H
 732.

H CD₂C(CH₃)₂CF₃ H
 733.

H

H
 734.

H

H
 735.

H

H
 736.

H

H
 737.

H

H
 738. H H H H
 739. CH₃ Ph H H
 740. H Ph H H
 741. H Ph CH₃ H
 742. CH₃ PhH CH₃
 743. CH₃ Ph CH₃ H
 744. CH₃ Ph H CH₃
 745. H Ph CH₃ H
 746. H Ph HCH₃
 747. H Ph CH₃ CH₃
 748. CH₃ Ph CH₃ H
 749. CH₃ Ph H CH₃
 750. CH₃ PhCH₃ CH₃
 751. H Ph CH₃ CH₃
 752. CH₃ Ph CH₃ CH₃
 753. CH₂CH₃ Ph H H 754.CH₂CH₃ Ph H CH₃
 755. CH₂CH₃ Ph CH₃ H
 756. CH₂CH₃ Ph H CH₃
 757. CH₂CH₃ PhCH₃ H
 758. CH₂CH₃ Ph H CH₃
 759. CH₂CH₃ Ph CH₃ CH₃
 760. CH₂CH₃ Ph CH₃ CH₃761. H Ph H H
 762. CH₃ Ph H CH₃
 763. H Ph CH₃ H
 764. H Ph H CH₃
 765. CH₃Ph CH₃ H
 766. CH₃ Ph H CH₃
 767. H Ph CH₃ CH₃
 768. CH₃ Ph CH₃ CH₃
 769. HPh CH₂CH₃ H
 770. CH₃ Ph CH₂CH₃ H
 771. H Ph CH₂CH₃ H
 772. H Ph CH₂CH₃ CH₃773. CH₃ Ph CH₂CH₃ H
 774. CH₃ Ph CH₂CH₃ CH₃
 775. H Ph CH₂CH₃ CH₃ 776.CH₃ Ph CH₂CH₃ CH₃
 777. CH(CH₃)₂ Ph H H
 778. CH(CH₃)₂ Ph H CH₃ 779.CH(CH₃)₂ Ph CH₃ H
 780. CH(CH₃)₂ Ph H CH₃
 781. CH(CH₃)₂ Ph CH₃ H 782.CH(CH₃)₂ Ph H CH₃
 783. CH(CH₃)₂ Ph CH₃ CH₃
 784. CH(CH₃)₂ Ph CH₃ CH₃ 785.H Ph H H
 786. CH₃ Ph H CH₃
 787. H Ph CH₃ H
 788. H Ph H CH₃
 789. CH₃ PhCH₃ H
 790. CH₃ Ph H CH₃
 791. H Ph CH₃ CH₃
 792. CH₃ Ph CH₃ CH₃
 793. H PhCH(CH₃)₂ H
 794. CH₃ Ph CH(CH₃)₂ H
 795. H Ph CH(CH₃)₂ H
 796. H PhCH(CH₃)₂ CH₃
 797. CH₃ Ph CH(CH₃)₂ H
 798. CH₃ Ph CH(CH₃)₂ CH₃
 799. H PhCH(CH₃)₂ CH₃
 800. CH₃ Ph CH(CH₃)₂ CH₃
 801. CH₂CH(CH₃)₂ Ph H H 802.CH₂CH(CH₃)₂ Ph H CH₃
 803. CH₂CH(CH₃)₂ Ph CH₃ H
 804. CH₂CH(CH₃)₂ Ph H CH₃805. CH₂CH(CH₃)₂ Ph CH₃ H
 806. CH₂CH(CH₃)₂ Ph H CH₃
 807. CH₂CH(CH₃)₂ PhCH₃ CH₃
 808. CH₂CH(CH₃)₂ Ph CH₃ CH₃
 809. H Ph H H
 810. CH₃ Ph H CH₃ 811.H Ph CH₃ H
 812. H Ph H CH₃
 813. CH₃ Ph CH₃ H
 814. CH₃ Ph H CH₃
 815. H PhCH₃ CH₃
 816. CH₃ Ph CH₃ CH₃
 817. H Ph CH₂CH(CH₃)₂ H
 818. CH₃ PhCH₂CH(CH₃)₂ H
 819. H Ph CH₂CH(CH₃)₂ H
 820. H Ph CH₂CH(CH₃)₂ CH₃
 821. CH₃Ph CH₂CH(CH₃)₂ H
 822. CH₃ Ph CH₂CH(CH₃)₂ CH₃
 823. H Ph CH₂CH(CH₃)₂ CH₃824. CH₃ Ph CH₂CH(CH₃)₂ CH₃
 825. C(CH₃)₃ Ph H H
 826. C(CH₃)₃ Ph H CH₃827. C(CH₃)₃ Ph CH₃ H
 828. C(CH₃)₃ Ph H CH₃
 829. C(CH₃)₃ Ph CH₃ H 830.C(CH₃)₃ Ph H CH₃
 831. C(CH₃)₃ Ph CH₃ CH₃
 832. C(CH₃)₃ Ph CH₃ CH₃
 833. HPh H H
 834. CH₃ Ph H CH₃
 835. H Ph CH₃ H
 836. H Ph H CH₃
 837. CH₃ Ph CH₃H
 838. CH₃ Ph H CH₃
 839. H Ph CH₃ CH₃
 840. CH₃ Ph CH₃ CH₃
 841. H PhC(CH₃)₃ H
 842. CH₃ Ph C(CH₃)₃ H
 843. H Ph C(CH₃)₃ H
 844. H Ph C(CH₃)₃CH₃
 845. CH₃ Ph C(CH₃)₃ H
 846. CH₃ Ph C(CH₃)₃ CH₃
 847. H Ph C(CH₃)₃ CH₃848. CH₃ Ph C(CH₃)₃ CH₃
 849. CH₂C(CH₃)₃ Ph H H
 850. CH₂C(CH₃)₃ Ph H CH₃851. CH₂C(CH₃)₃ Ph CH₃ H
 852. CH₂C(CH₃)₃ Ph H CH₃
 853. CH₂C(CH₃)₃ Ph CH₃H
 854. CH₂C(CH₃)₃ Ph H CH₃
 855. CH₂C(CH₃)₃ Ph CH₃ CH₃
 856. CH₂C(CH₃)₃ PhCH₃ CH₃
 857. H Ph H H
 858. CH₃ Ph H CH₃
 859. H Ph CH₃ H
 860. H Ph H CH₃861. CH₃ Ph CH₃ H
 862. CH₃ Ph H CH₃
 863. H Ph CH₃ CH₃
 864. CH₃ Ph CH₃CH₃
 865. H Ph CH₂C(CH₃)₃ H
 866. CH₃ Ph CH₂C(CH₃)₃ H
 867. H Ph CH₂C(CH₃)₃H
 868. H Ph CH₂C(CH₃)₃ CH₃
 869. CH₃ Ph CH₂C(CH₃)₃ H
 870. CH₃ PhCH₂C(CH₃)₃ CH₃
 871. H Ph CH₂C(CH₃)₃ CH₃
 872. CH₃ Ph CH₂C(CH₃)₃ CH₃
 873.

Ph H H
 874.

Ph H CH₃
 875.

Ph CH₃ H
 876.

Ph H CH₃
 877.

Ph CH₃ H
 878.

Ph H CH₃
 879.

Ph CH₃ CH₃
 880.

Ph CH₃ CH₃
 881. H Ph H H
 882. CH₃ Ph H CH₃
 883. H Ph CH₃ H
 884. H Ph HCH₃
 885. CH₃ Ph CH₃ H
 886. CH₃ Ph H CH₃
 887. H Ph CH₃ CH₃
 888. CH₃ PhCH₃ CH₃
 889. H Ph

H
 890. CH₃ Ph

H
 891. H Ph

H
 892. H Ph

CH₃
 893. CH₃ Ph

H
 894. CH₃ Ph

CH₃
 895. H Ph

CH₃
 896. CH₃ Ph

CH₃
 897.

Ph H H
 898.

Ph H CH₃
 899.

Ph CH₃ H
 900.

Ph H CH₃
 901.

Ph CH₃ H
 902.

Ph H CH₃
 903.

Ph CH₃ CH₃
 904.

Ph CH₃ CH₃
 905. H Ph H H
 906. CH₃ Ph H CH₃
 907. H Ph CH₃ H
 908. H Ph HCH₃
 909. CH₃ Ph CH₃ H
 910. CH₃ Ph H CH₃
 911. H Ph CH₃ CH₃
 912. CH₃ PhCH₃ CH₃
 913. H Ph

H
 914. CH₃ Ph

H
 915. H Ph

H
 916. H Ph

CH₃
 917. CH₃ Ph

H
 918. CH₃ Ph

CH3
 919. H Ph

CH₃
 920. CH₃ Ph

CH₃
 921.

Ph H H
 922.

Ph H CH₃
 923.

Ph CH₃ H
 924.

Ph H CH₃
 925.

Ph CH₃ H
 926.

Ph H CH₃
 927.

Ph CH₃ CH₃
 928.

Ph CH₃ CH₃
 929. H Ph H H
 930. CH₃ Ph H CH₃
 931. H Ph CH₃ H
 932. H Ph HCH₃
 933. CH₃ Ph CH₃ H
 934. CH₃ Ph H CH₃
 935. H Ph CH₃ CH₃
 936. CH₃ PhCH₃ CH₃
 937. H Ph

H
 938. CH₃ Ph

H
 939. H Ph

H
 940. H Ph

CH₃
 941. CH₃ Ph

H
 942. CH₃ Ph

CH₃
 943. H Ph

CH₃
 944. CH₃ Ph

CH₃
 945.

Ph H H
 946.

Ph H CH₃
 947.

Ph CH₃ H
 948.

Ph H CH₃
 949.

Ph CH₃ H
 950.

Ph H CH₃
 951.

Ph CH₃ CH₃
 952.

Ph CH₃ CH₃
 953. H Ph H H
 954. CH₃ Ph H CH₃
 955. H Ph CH₃ H
 956. H Ph HCH₃
 957. CH₃ Ph CH₃ H
 958. CH₃ Ph H CH₃
 959. H Ph CH₃ CH₃
 960. CH₃ PhCH₃ CH₃
 961. H Ph

H
 962. CH₃ Ph

H
 963. H Ph

H
 964. H Ph

CH₃
 965. CH₃ Ph

H
 966. CH₃ Ph

CH₃
 967. H Ph

CH₃
 968. CH₃ Ph

CH₃
 969.

Ph H H
 970.

Ph H CH₃
 971.

Ph CH₃ H
 972.

Ph H CH₃
 973.

Ph CH₃ H
 974.

Ph H CH₃
 975.

Ph CH₃ CH₃
 976.

Ph CH₃ CH₃
 977. H Ph H H
 978. CH₃ Ph H CH₃
 979. H Ph CH₃ H
 980. H Ph HCH₃
 981. CH₃ Ph CH₃ H
 982. CH₃ Ph H CH₃
 983. H Ph CH₃ CH₃
 984. CH₃ PhCH₃ CH₃
 985. H Ph

H
 986. CH₃ Ph

H
 987. H Ph

H
 988. H Ph

CH₃
 989. CH₃ Ph

H
 990. CH₃ Ph

CH₃
 991. H Ph

CH₃
 992. CH₃ Ph

CH₃
 993.

Ph H H
 994.

Ph H CH₃
 995.

Ph CH₃ H
 996.

Ph H CH₃
 997.

Ph CH₃ H
 998.

Ph H CH₃
 999.

Ph CH₃ CH₃
 1000.

Ph CH₃ CH₃
 1001. H Ph H H
 1002. CH₃ Ph H CH₃
 1003. H Ph CH₃ H
 1004. H PhH CH₃
 1005. CH₃ Ph CH₃ H
 1006. CH₃ Ph H CH₃
 1007. H Ph CH₃ CH₃
 1008. CH₃Ph CH₃ CH₃
 1009. H Ph

H
 1010. CH₃ Ph

H
 1011. H Ph

H
 1012. H Ph

CH₃
 1013. CH₃ Ph

H
 1014. CH₃ Ph

CH₃
 1015. H Ph

CH₃
 1016. CH₃ Ph

CH₃
 1017. CH(CH₃)₂ Ph CH₂CH₃ H
 1018. CH(CH₃)₂ Ph CH(CH₃)₂ H 1019.CH(CH₃)₂ Ph CH₂CH(CH₃)₂ H
 1020. CH(CH₃)₂ Ph C(CH₃)₃ H
 1021. CH(CH₃)₂ PhCH₂C(CH₃)₃ H
 1022. CH(CH₃)₂ Ph

H
 1023. CH(CH₃)₂ Ph

H
 1024. CH(CH₃)₂ Ph

H
 1025. CH(CH₃)₂ Ph

H
 1026. CH(CH₃)₂ Ph

H
 1027. CH(CH₃)₂ Ph

H
 1028. C(CH₃)₃ Ph CH₂CH₃ H
 1029. C(CH₃)₃ Ph CH(CH₃)₂ H
 1030. C(CH₃)₃ PhCH₂CH(CH₃)₂ H
 1031. C(CH₃)₃ Ph C(CH₃)₃ H
 1032. C(CH₃)₃ Ph CH₂C(CH₃)₃ H1033. C(CH₃)₃ Ph

H
 1034. C(CH₃)₃ Ph

H
 1035. C(CH₃)₃ Ph

H
 1036. C(CH₃)₃ Ph

H
 1037. C(CH₃)₃ Ph

H
 1038. C(CH₃)₃ Ph

H
 1039. CH₂C(CH₃)₃ Ph CH₂CH₃ H
 1040. CH₂C(CH₃)₃ Ph CH(CH₃)₂ H 1041.CH₂C(CH₃)₃ Ph CH₂CH(CH₃)₂ H
 1042. CH₂C(CH₃)₃ Ph C(CH₃)₃ H 1043.CH₂C(CH₃)₃ Ph CH₂C(CH₃)₃ H
 1044. CH₂C(CH₃)₃ Ph

H
 1045. CH₂C(CH₃)₃ Ph

H
 1046. CH₂C(CH₃)₃ Ph

H
 1047. CH₂C(CH₃)₃ Ph

H
 1048. CH₂C(CH₃)₃ Ph

H
 1049. CH₂C(CH₃)₃ Ph

H
 1050.

Ph CH₂CH₃ H
 1051.

Ph CH(CH₃)₂ H
 1052.

Ph CH₂CH(CH₃)₂ H
 1053.

Ph C(CH₃)₃ H
 1054.

Ph CH₂C(CH₃)₃ H
 1055.

Ph

H
 1056.

Ph

H
 1057.

Ph

H
 1058.

Ph

H
 1059.

Ph

H
 1060.

Ph

H
 1061.

Ph CH₂CH₃ H
 1062.

Ph CH(CH₃)₂ H
 1063.

Ph CH₂CH(CH₃)₂ H
 1064.

Ph C(CH₃)₃ H
 1065.

Ph CH₂C(CH₃)₃ H
 1066.

Ph

H
 1067.

Ph

H
 1068.

Ph

H
 1069.

Ph

H
 1070.

Ph

H
 1071.

Ph

H
 1072.

Ph CH₂CH(CH₃)₂ H
 1073.

Ph C(CH₃)₃ H
 1074.

Ph CH₂C(CH₃)₃ H
 1075.

Ph

H
 1076.

Ph

H
 1077.

Ph

H
 1078.

Ph

H
 1079.

Ph

H
 1080.

Ph

H
 1081.

Ph CH₂CH(CH₃)₂ H
 1082.

Ph C(CH₃)₃ H
 1083.

Ph CH₂C(CH₃)₃ H
 1084.

Ph

H
 1085.

Ph

H
 1086.

Ph

H
 1087.

Ph

H
 1088.

Ph

H
 1089.

Ph

H
 1090.

Ph CH₂CH(CH₃)₂ H
 1091.

Ph C(CH₃)₃ H
 1092.

Ph CH₂C(CH₃)₃ H
 1093.

Ph CH₂CH₂CF₃ H
 1094.

Ph CH₂C(CH₃)₂CF₃ H
 1095.

Ph

H
 1096.

Ph

H
 1097.

Ph

H
 1098.

Ph

H
 1099.

Ph

H
 1100.

Ph

H
 1101. H Ph H H
 1102. CD₃ Ph H H
 1103. H Ph H H
 1104. H Ph CD₃ H 1105.CD₃ Ph H CD₃
 1106. CD₃ Ph CD₃ H
 1107. CD₃ Ph H CD₃
 1108. H Ph CH₃ H1109. H Ph H CD₃
 1110. H Ph CD₃ CD₃
 1111. CD₃ Ph CD₃ H
 1112. CD₃ Ph HCD₃
 1113. CD₃ Ph CD₃ CD₃
 1114. H Ph CD₃ CD₃
 1115. CD₃ Ph CD₃ CD₃ 1116.CD₂CH₃ Ph H H
 1117. CD₂CH₃ Ph H CD₃
 1118. CD₂CH₃ Ph CD₃ H
 1119. CD₂CH₃Ph H CD₃
 1120. CD₂CH₃ Ph CD₃ H
 1121. CD₂CH₃ Ph H CD₃
 1122. CD₂CH₃ Ph CD₃CD₃
 1123. CD₂CH₃ Ph CD₃ CD₃
 1124. H Ph H H
 1125. CH₃ Ph H CD₃
 1126. H PhCD₃ H
 1127. H Ph H CD₃
 1128. CD₃ Ph CD₃ H
 1129. CD₃ Ph H CD₃
 1130. H PhCD₃ CD₃
 1131. CD₃ Ph CD₃ CD₃
 1132. H Ph CD₂CH₃ H
 1133. CD₃ Ph CD₂CH₃ H1134. H Ph CD₂CH₃ H
 1135. H Ph CD₂CH₃ CD₃
 1136. CD₃ Ph CD₂CH₃ H 1137.CD₃ Ph CD₂CH₃ CD₃
 1138. H Ph CD₂CH₃ CD₃
 1139. CD₃ Ph CD₂CH₃ CD₃ 1140.CD(CH₃)₂ Ph H H
 1141. CD(CH₃)₂ Ph H CD₃
 1142. CD(CH₃)₂ Ph CD₃ H 1143.CD(CH₃)₂ Ph H CD₃
 1144. CD(CH₃)₂ Ph CD₃ H
 1145. CD(CH₃)₂ Ph H CD₃ 1146.CD(CH₃)₂ Ph CD₃ CD₃
 1147. CD(CH₃)₂ Ph CD₃ CD₃
 1148. H Ph H H
 1149. CD₃Ph H CD₃
 1150. H Ph CD₃ H
 1151. H Ph H CD₃
 1152. CD₃ Ph CD₃ H
 1153. CD₃Ph H CD₃
 1154. H Ph CD₃ CD₃
 1155. CD₃ Ph CD₃ CD₃
 1156. H Ph CD(CH₃)₂ H1157. CD₃ Ph CD(CH₃)₂ H
 1158. H Ph CD(CH₃)₂ H
 1159. H Ph CD(CH₃)₂ CD₃1160. CD₃ Ph CD(CH₃)₂ H
 1161. CD₃ Ph CD(CH₃)₂ CD₃
 1162. H Ph CD(CH₃)₂CD₃
 1163. CD₃ Ph CD(CH₃)₂ CD₃
 1164. CD(CD₃)₂ Ph H H
 1165. CD(CD₃)₂ Ph HCD₃
 1166. CD(CD₃)₂ Ph CD₃ H
 1167. CD(CD₃)₂ Ph H CD₃
 1168. CD(CD₃)₂ PhCD₃ H
 1169. CD(CD₃)₂ Ph H CD₃
 1170. CD(CD₃)₂ Ph CD₃ CD₃
 1171. CD(CD₃)₂Ph CD₃ CD₃
 1172. H Ph H H
 1173. CH₃ Ph H CD₃
 1174. H Ph CD₃ H
 1175. H PhH CD₃
 1176. CD₃ Ph CD₃ H
 1177. CD₃ Ph H CD₃
 1178. H Ph CD₃ CD₃
 1179. CD₃Ph CD₃ CD₃
 1180. H Ph CD(CD₃)₂ H
 1181. CD₃ Ph CD(CD₃)₂ H
 1182. H PhCD(CD₃)₂ H
 1183. H Ph CD(CD₃)₂ CD₃
 1184. CD₃ Ph CD(CD₃)₂ H
 1185. CD₃ PhCD(CD₃)₂ CD₃
 1186. H Ph CD(CD₃)₂ CD₃
 1187. CD₃ Ph CD(CD₃)₂ CD₃ 1188.CD₂CH(CH₃)₂ Ph H H
 1189. CD₂CH(CH₃)₂ Ph H CD₃
 1190. CD₂CH(CH₃)₂ Ph CD₃ H1191. CD₂CH(CH₃)₂ Ph H CD₃
 1192. CD₂CH(CH₃)₂ Ph CD₃ H
 1193. CD₂CH(CH₃)₂Ph H CD₃
 1194. CD₂CH(CH₃)₂ Ph CD₃ CD₃
 1195. CD₂CH(CH₃)₂ Ph CD₃ CD₃ 1196.H Ph H H
 1197. CD₃ Ph H CD₃
 1198. H Ph CD₃ H
 1199. H Ph H CD₃
 1200. CD₃Ph CD₃ H
 1201. CD₃ Ph H CD₃
 1202. H Ph CD₃ CD₃
 1203. CD₃ Ph CD₃ CD₃1204. H Ph CD₂CH(CH₃)₂ H
 1205. CD₃ Ph CD₂CH(CH₃)₂ H
 1206. H PhCD₂CH(CH₃)₂ H
 1207. H Ph CD₂CH(CH₃)₂ CD₃
 1208. CD₃ Ph CD₂CH(CH₃)₂ H1209. CD₃ Ph CD₂CH(CH₃)₂ CD₃
 1210. H Ph CD₂CH(CH₃)₂ CD₃
 1211. CD₃ PhCD₂CH(CH₃)₂ CD₃
 1212. CD₂C(CH₃)₃ Ph H H
 1213. CD₂C(CH₃)₃ Ph H CD₃ 1214.CD₂C(CH₃)₃ Ph CD₃ H
 1215. CD₂C(CH₃)₃ Ph H CD₃
 1216. CD₂C(CH₃)₃ Ph CD₃ H1217. CD₂C(CH₃)₃ Ph H CD₃
 1218. CD₂C(CH₃)₃ Ph CD₃ CD₃
 1219. CD₂C(CH₃)₃Ph CD₃ CD₃
 1220. H Ph H H
 1221. CD₃ Ph H CD₃
 1222. H Ph CD₃ H
 1223. H PhH CD₃
 1224. CD₃ Ph CD₃ H
 1225. CD₃ Ph H CD₃
 1226. H Ph CD₃ CD₃
 1227. CD₃Ph CD₃ CD₃
 1228. H Ph CD₂C(CH₃)₃ H
 1229. CD₃ Ph CD₂C(CH₃)₃ H
 1230. H PhCD₂C(CH₃)₃ H
 1231. H Ph CD₂C(CH₃)₃ CD₃
 1232. CD₃ Ph CD₂C(CH₃)₃ H 1233.CD₃ Ph CD₂C(CH₃)₃ CD₃
 1234. H Ph CD₂C(CH₃)₃ CD₃
 1235. CD₃ Ph CD₂C(CH₃)₃CD₃
 1236.

Ph H H
 1237.

Ph H CD₃
 1238.

Ph CD₃ H
 1239.

Ph H CD₃
 1240.

Ph CD₃ H
 1241.

Ph H CD₃
 1242.

Ph CD₃ CD₃
 1243.

Ph CD₃ CD₃
 1244. H Ph H H
 1245. CD₃ Ph H CD₃
 1246. H Ph CD₃ H
 1247. H PhH CD₃
 1248. CD₃ Ph CD₃ H
 1249. CD₃ Ph H CD₃
 1250. H Ph CD₃ CD₃
 1251. CD₃Ph CD₃ CD₃
 1252. H Ph

H
 1253. CD₃ Ph

H
 1254. H Ph

H
 1255. H Ph

CD₃
 1256. CD₃ Ph

H
 1257. CD₃ Ph

CD₃
 1258. H Ph

CD₃
 1259. CD₃ Ph

CD₃
 1260.

Ph H H
 1261.

Ph H CD₃
 1262.

Ph CD₃ H
 1263.

Ph H CD₃
 1264.

Ph CD₃ H
 1265.

Ph H CD₃
 1266.

Ph CD₃ CD₃
 1267.

Ph CD₃ CD₃
 1268. H Ph H H
 1269. CH₃ Ph H CD₃
 1270. H Ph CD₃ H
 1271. H PhH CD₃
 1272. CD₃ Ph CD₃ H
 1273. CD₃ Ph H CD₃
 1274. H Ph CD₃ CD₃
 1275. CH₃Ph CD₃ CD₃
 1276. H Ph

H
 1277. CD₃ Ph

H
 1278. H Ph

H
 1279. H Ph

CD₃
 1280. CD₃ Ph

H
 1281. CD₃ Ph

CD₃
 1282. H Ph

CD₃
 1283. CD₃ Ph

CD₃
 1284.

Ph H H
 1285.

Ph H CD₃
 1286.

Ph CD₃ H
 1287.

Ph H CD₃
 1288.

Ph CD₃ H
 1289.

Ph H CD₃
 1290.

Ph CD₃ CD₃
 1291.

Ph CD₃ CD₃
 1292. H Ph H H
 1293. CD₃ Ph H CD₃
 1294. H Ph CD₃ H
 1295. H PhH CD₃
 1296. CD₃ Ph CD₃ H
 1297. CD₃ Ph H CD₃
 1298. H Ph CD₃ CD₃
 1299. CD₃Ph CD₃ CD₃
 1300. H Ph

H
 1301. CD₃ Ph

H
 1302. H Ph

H
 1303. H Ph

CD₃
 1304. CD₃ Ph

H
 1305. CD₃ Ph

CD₃
 1306. H Ph

CD₃
 1307. CD₃ Ph

CD₃
 1308.

Ph H H
 1309.

Ph H CD₃
 1310.

Ph CD₃ H
 1311.

Ph H CD₃
 1312.

Ph CD₃ H
 1313.

Ph H CD₃
 1314.

Ph CD₃ CD₃
 1315.

Ph CD₃ CD₃
 1316. H Ph H H
 1317. CD₃ Ph H CD₃
 1318. H Ph CD₃ H
 1319. H PhH CD₃
 1320. CD₃ Ph CD₃ H
 1321. CD₃ Ph H CD₃
 1322. H Ph CD₃ CD₃
 1323. CD₃Ph CD₃ CD₃
 1324. H Ph

H
 1325. CD₃ Ph

H
 1326. H Ph

H
 1327. H Ph

CD₃
 1328. CD₃ Ph

H
 1329. CD₃ Ph

CD₃
 1330. H Ph

CD₃
 1331. CD₃ Ph

CD₃
 1332.

Ph H H
 1333.

Ph H CD₃
 1334.

Ph CD₃ H
 1335.

Ph H CD₃
 1336.

Ph CD₃ H
 1337.

Ph H CD₃
 1338.

Ph CD₃ CD₃
 1339.

Ph CD₃ CD₃
 1340. H Ph H H
 1341. CD₃ Ph H CD₃
 1342. H Ph CD₃ H
 1343. H PhH CD₃
 1344. CD₃ Ph CD₃ H
 1345. CD₃ Ph H CD₃
 1346. H Ph CD₃ CD₃
 1347. CD₃Ph CD₃ CD₃
 1348. H Ph

H
 1349. CD₃ Ph

H
 1350. H Ph

H
 1351. H Ph

CD₃
 1352. CD₃ Ph

H
 1353. CD₃ Ph

CD₃
 1354. H Ph

CD₃
 1355. CD₃ Ph

CD₃
 1356.

Ph H H
 1357.

Ph H CD₃
 1358.

Ph CD₃ H
 1359.

Ph H CD₃
 1360.

Ph CH₃ H
 1361.

Ph H CD₃
 1362.

Ph CD₃ CD₃
 1363.

Ph CD₃ CD₃
 1364. H Ph H H
 1365. CD₃ Ph H CD₃
 1366. H Ph CD₃ H
 1367. H PhH CD₃
 1368. CD₃ Ph CD₃ H
 1369. CD₃ Ph H CD₃
 1370. H Ph CD₃ CD₃
 1371. CD₃Ph CD₃ CD₃
 1372. H Ph

H
 1373. CD₃ Ph

H
 1374. H Ph

H
 1375. H Ph

CH₃
 1376. CD₃ Ph

H
 1377. CD₃ Ph

CD₃
 1378. H Ph

CD₃
 1379. CD₃ Ph

CD₃
 1380. CD(CH₃)₂ Ph CD₂CH₃ H
 1381. CD(CH₃)₂ Ph CD(CH₃)₂ H 1382.CD(CH₃)₂ Ph CD₂CH(CH₃)₂ H
 1383. CD(CH₃)₂ Ph C(CH₃)₃ H
 1384. CD(CH₃)₂ PhCD₂C(CH₃)₃ H
 1385. CD(CH₃)₂ Ph CD₂CH₂CF₃ H
 1386. CD(CH₃)₂ PhCD₂C(CH₃)₂CF₃ H
 1387. CD(CH₃)₂ Ph

H
 1388. CD(CH₃)₂ Ph

H
 1389. CD(CH₃)₂ Ph

H
 1390. CD(CH₃)₂ Ph

H
 1391. CD(CH₃)₂ Ph

H
 1392. CD(CH₃)₂ Ph

H
 1393. C(CH₃)₃ Ph CD₂CH₃ H
 1394. C(CH₃)₃ Ph CD(CH₃)₂ H
 1395. C(CH₃)₃ PhCD₂CH(CH₃)₂ H
 1396. C(CH₃)₃ Ph C(CH₃)₃ H
 1397. C(CH₃)₃ Ph CD₂C(CH₃)₃ H1398. C(CH₃)₃ Ph

H
 1399. C(CH₃)₃ Ph

H
 1400. C(CH₃)₃ Ph

H
 1401. C(CH₃)₃ Ph

H
 1402. C(CH₃)₃ Ph

H
 1403. C(CH₃)₃ Ph

H
 1404. CD₂C(CH₃)₃ Ph CD₂CH₃ H
 1405. CD₂C(CH₃)₃ Ph CD(CH₃)₂ H 1406.CD₂C(CH₃)₃ Ph CD₂CH(CH₃)₂ H
 1407. CD₂C(CH₃)₃ Ph C(CH₃)₃ H 1408.CD₂C(CH₃)₃ Ph CD₂C(CH₃)₃ H
 1409. CD₂C(CH₃)₃ Ph CD₂CH₂CF₃ H 1410.CD₂C(CH₃)₃ Ph CD₂C(CH₃)₂CF₃ H
 1411. CD₂C(CH₃)₃ Ph

H
 1412. CD₂C(CH₃)₃ Ph

H
 1413. CD₂C(CH₃)₃ Ph

H
 1414. CD₂C(CH₃)₃ Ph

H
 1415. CD₂C(CH₃)₃ Ph

H
 1416. CD₂C(CH₃)₃ Ph

H
 1417.

Ph CD₂CH₃ H
 1418.

Ph CD(CH₃)₂ H
 1419.

Ph CD₂CH(CH₃)₂ H
 1420.

Ph C(CH₃)₃ H
 1421.

Ph CD₂C(CH₃)₃ H
 1422.

Ph

H
 1423.

Ph

H
 1424.

Ph

H
 1425.

Ph

H
 1426.

Ph

H
 1427.

Ph

H
 1428.

Ph CD₂CH₃ H
 1429.

Ph CD(CH₃)₂ H
 1430.

Ph CD₂CH(CH₃)₂ H
 1431.

Ph C(CH₃)₃ H
 1432.

Ph CD₂C(CH₃)₃ H
 1433.

Ph

H
 1434.

Ph

H
 1435.

Ph

H
 1436.

Ph

H
 1437.

Ph

H
 1438.

Ph

H
 1439.

Ph CD₂CH₃ H
 1440.

Ph CD(CH₃)₂ H
 1441.

Ph CD₂CH(CH₃)₂ H
 1442.

Ph C(CH₃)₃ H
 1443.

Ph CD₂C(CH₃)₃ H
 1444.

Ph

H
 1445.

Ph

H
 1446.

Ph

H
 1447.

Ph

H
 1448.

Ph

H
 1449.

Ph

H
 1450.

Ph CD₂CH₃ H
 1451.

Ph CD(CH₃)₂ H
 1452.

Ph CD₂CH(CH₃)₂ H
 1453.

Ph C(CH₃)₃ H
 1454.

Ph CD₂C(CH₃)₃ H
 1455.

Ph

H
 1456.

Ph

H
 1457.

Ph

H
 1458.

Ph

H
 1459.

Ph

H
 1460.

Ph

H
 1461.

Ph CD₂CH₃ H
 1462.

Ph CD(CH₃)₂ H
 1463.

Ph CD₂CH(CH₃)₂ H
 1464.

Ph C(CH₃)₃ H
 1465.

Ph CD₂C(CH₃)₃ H
 1466.

Ph

H
 1467.

Ph

H
 1468.

Ph

H
 1469.

Ph

H
 1470.

Ph

H
 1471.

Ph

H.


9. The compound of claim 1, wherein R has five carbon atoms.
 10. Anorganic light emitting device (OLED) comprising: an anode; a cathode;and an organic layer, disposed between the anode and the cathode,comprising a compound having the formula:

wherein R¹, R², R³, R⁴, and R⁵ each independently represents mono, to amaximum possible number of substitutions, or no substitution; wherein Xis selected from the group consisting of BR′, NR′, PR′, 0, S, Se, C═O,S═O, SO₂, CR′R″, SiR′R″, and GeR′R″; wherein R′, R″, R¹, R², R³, R⁴, andR⁵ are independently selected from the group consisting of hydrogen,deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy,aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl,aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile,isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinationsthereof; wherein any substitutions are optionally joined or fused into aring; wherein n is 1 or 2; wherein R is selected from the groupconsisting of alkyl, and partially or fully deuterated variants thereof;and wherein R has at least five carbon atoms.
 11. The OLED of claim 10,wherein R has at least six carbon atoms.
 12. The OLED of claim 10,wherein R has at least seven carbon atoms.
 13. The OLED of claim 10,wherein the organic layer further comprises a host, wherein hostcomprises at least one chemical group selected from the group consistingof triphenylene, carbazole, dibenzothiphene, dibenzofuran,dibenzoselenophene, azatriphenylene, azacarbazole, aza-dibenzothiophene,aza-dibenzofuran, and aza-dibenzoselenophene.
 14. The OLED of claim 10,wherein the organic layer further comprises a host, wherein the host isselected from the group consisting of:

and combinations thereof.
 15. The OLED of claim 10, wherein the organiclayer further comprises a host, wherein the host comprises a metalcomplex.
 16. The OLED of claim 10, wherein R has five carbon atoms. 17.A consumer product comprising an organic light-emitting device (OLED)comprising: an anode; a cathode; and an organic layer, disposed betweenthe anode and the cathode, comprising a compound having the formula:

wherein R¹, R², R³, R⁴, and R⁵ each independently represents mono, to amaximum possible number of substitutions, or no substitution; wherein Xis selected from the group consisting of BR′, NR′, PR′, 0, S, Se, C═O,S═O, SO₂, CR′R″, SiR′R″, and GeR′R″; wherein R′, R″, R¹, R², R³, R⁴, andR⁵ are independently selected from the group consisting of hydrogen,deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy,aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl,aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile,isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinationsthereof; wherein any substitutions are optionally joined or fused into aring; wherein n is 1 or 2; wherein R is selected from the groupconsisting of alkyl, and partially or fully deuterated variants thereof;and wherein R has at least five carbon atoms.
 18. The consumer productof claim 17, wherein the consumer product is one of a flat paneldisplay, a curved display, a computer monitor, a medical monitor, OLEDsused in photodynamic therapy, near IR (NIR) OLEDs, a television, abillboard, a light for interior or exterior illumination and/orsignaling, a heads-up display, a fully or partially transparent display,a flexible display, a rollable display, a foldable display, astretchable display, a laser printer, a telephone, a cell phone, tablet,a phablet, a personal digital assistant (PDA), a wearable device, alaptop computer, a digital camera, a camcorder, a viewfinder, amicro-display that is less than 2 inches diagonal, a 3-D display, avirtual reality or augmented reality display, a vehicle, a video wallcomprising multiple displays tiled together, a theater or stadiumscreen, or a sign.
 19. The consumer product of claim 17, wherein R hasfive carbon atoms.